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    • 13. 发明授权
    • Polyester containing benzylidene having reduced fluorescence
    • 含有亚苄基的聚酯具有降低的荧光
    • US6001952A
    • 1999-12-14
    • US095036
    • 1998-06-10
    • Karen Lynn CarmanMartin Emerson RogersAllan Scott JonesMax Allen Weaver
    • Karen Lynn CarmanMartin Emerson RogersAllan Scott JonesMax Allen Weaver
    • C08G63/685C08K5/00C08K5/315C08L67/02C08G63/00
    • C08K5/0008C08G63/6854C08K5/315C08L67/02
    • A polymer composition having naphthalenedicarboxylic residue includes a fluorescence quenching benzylidene compound capable of absorbing ultraviolet light radiation. In a preferred embodiment, the composition includes at least a 0.1 mole percent of naphthalene-2,6-dicarboxylate and about 0.01 mole percent to about 5 mole percent of a benzylidene compound having the following structure: ##STR1## wherein R is selected from the group consisting of hydrogen, C.sub.1 -C.sub.8 alkyl, substituted C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 alkenyl, C.sub.3 -C.sub.8 alkynyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.8 cycloalkenyl and --R.sub.2 --X, wherein R.sub.2 is selected from the group consisting of C.sub.1 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene-O--C.sub.2 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene-S--C.sub.1 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene-S--C.sub.2 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene-N(SO.sub.2 C.sub.1-C.sub.8 alkyl)-C.sub.2 -C.sub.8 alkylene and X is selected from the group consisting of hydroxy, carboxy, carboalkoxy and acyloxy; R.sub.1 is hydrogen or has 1-3 groups independently selected from the group consisting of hydroxy, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy and halogen; Y is selected from the group consisting of carbalkoxy, cyano, carbamoyl, substituted carbamoyl, aryl, aroyl, C.sub.1 -C.sub.8 alkylsulfonyl and arylsulfonyl.
    • 具有萘二羧酸残基的聚合物组合物包括能够吸收紫外光辐射的荧光淬灭亚苄基化合物。 在优选的实施方案中,组合物包含至少0.1摩尔%的2,6-二甲酸萘酯和约0.01摩尔%至约5摩尔%的具有以下结构的亚苄基化合物:其中R选自 氢,C1-C8烷基,取代的C1-C8烷基,C3-C8烯基,C3-C8炔基,C3-C8环烷基,C3-C8环烯基和-R2-X,其中R2选自C1-C8 亚烷基,C2-C8亚烷基-O-C2-C8亚烷基,C2-C8亚烷基-S-C1-C8亚烷基,C2-C8亚烷基,C2-C8亚烷基-S-C2-C8亚烷基,C2-C8亚烷基-N( SO 2 C 1 -C 8烷基)-C 2 -C 8亚烷基,X选自羟基,羧基,烷氧羰基和酰氧基; R 1是氢或具有1-3个独立地选自羟基,C 1 -C 8烷基,C 1 -C 8烷氧基和卤素的基团; Y选自烷氧基,氰基,氨基甲酰基,取代的氨基甲酰基,芳基,芳酰基,C 1 -C 8烷基磺酰基和芳基磺酰基。