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    • 18. 发明授权
    • Chemical treatment of semiconductor substrates
    • 半导体衬底的化学处理
    • US07314837B2
    • 2008-01-01
    • US11333629
    • 2005-12-29
    • Li LiWeimin Li
    • Li LiWeimin Li
    • H01L21/31
    • H01L21/316H01L21/76232H01L21/76826H01L21/76828H01L21/76837Y10S438/902
    • A method is disclosed for removing liquids from a semiconductor substrate by contacting the liquid on the substrate with a liquid which attracts the liquid on the substrate, separating the liquids from the substrate, and inducing a phase transition in a layer on the substrate. In particular, the method is applicable to removing water from a water-containing layer on the substrate by contacting the layer with a hygroscopic liquid. Trenches on a substrate can be isolated by filling the trenches with a water-containing gel formed by reacting silane and hydrogen peroxide. The gel is contacted with sulfuric acid to remove a portion of the water from the gel before annealing to form silica in the trenches. Unlike filled trenches formed by conventional technology, there are no voids in the bottom of the trenches. The method is also applicable to forming dielectric layers which cover metal lines, low-dielectric layers, and interlayer dielectric layers. The liquid may be applied to the substrate by chemical vapor deposition or by spin-applying.
    • 公开了一种通过使衬底上的液体接触吸附衬底上的液体的液体,将液体与衬底分离并引起衬底上的层中的相变来从半导体衬底去除液体的方法。 特别地,该方法适用于通过使该层与吸湿性液体接触来从基底上的含水层除去水分。 通过用硅烷和过氧化氢反应形成的含水凝胶填充沟槽可以分离衬底上的沟槽。 将凝胶与硫酸接触以在退火之前从凝胶中除去一部分水以在沟槽中形成二氧化硅。 与常规技术形成的填充沟槽不同,沟槽底部没有空隙。 该方法也适用于形成覆盖金属线,低电介质层和层间电介质层的电介质层。 液体可以通过化学气相沉积或通过旋涂施加到基底上。
    • 19. 发明授权
    • Atomic layer deposition methods of forming silicon dioxide comprising layers
    • 形成二氧化硅层的原子层沉积方法
    • US07018469B2
    • 2006-03-28
    • US10669667
    • 2003-09-23
    • Li LiWeimin LiGurtej S. Sandhu
    • Li LiWeimin LiGurtej S. Sandhu
    • C30B25/14
    • C23C16/45527C23C16/402
    • A substrate is positioned within a deposition chamber. Trimethylsilane is flowed to the chamber and a first inert gas is flowed to the chamber under conditions effective to chemisorb a first species monolayer comprising silicon onto the substrate. The first inert gas is flowed at a first rate. After forming the first species monolayer, an oxidant is flowed to the chamber and a second inert gas is flowed to the chamber under conditions effective to react the oxidant with the chemisorbed first species and form a monolayer comprising silicon dioxide on the substrate. The second inert gas flowing is at a second rate which is less than the first rate. The a) trimethylsilane and first inert gas flowing and the b) oxidant and second inert gas flowing are successively repeated effective to form a silicon dioxide comprising layer on the substrate. Other implementations and aspects are contemplated.
    • 衬底位于沉积室内。 三甲基硅烷流到室中,并且第一惰性气体在有效地化学吸附包含硅的第一物质单层到衬底上的条件下流到室中。 第一惰性气体以第一速率流动。 在形成第一物质单层之后,将氧化剂流到室,并且在有效使氧化剂与化学吸附的第一种类反应的条件下将第二惰性气体流入室,并在衬底上形成包含二氧化硅的单层。 第二惰性气体流动的速度小于第一速率。 a)三甲基硅烷和第一惰性气体流动,b)氧化剂和第二惰性气体流动相继重复有效地在基底上形成含二氧化硅的层。 考虑其他实现和方面。