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11. 发明授权

US5478384A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5478384A
公开(公告)日：1995-12-26
申请号：US238734
申请日：1994-05-05
申请人： Hiroshi Takimoto , Tomio Yoneyama , Hideo Sano , Yukichi Murata , Masahiro Yamada
发明人： Hiroshi Takimoto , Tomio Yoneyama , Hideo Sano , Yukichi Murata , Masahiro Yamada
IPC分类号： C09B31/08 , C09B31/18 , C09D11/00 , C09D11/02
CPC分类号： C09D11/32 , C09B31/08 , C09B31/18 , C09D11/328
摘要： A recording liquid excellent in print quality, light resistance, and water resistance which is characterized in that it contains an aqueous medium and at least one dye selected from the dyes represented by general formulae [I] to [V]: ##STR1## (wherein R.sub.1 and R.sub.2 each represents H, CH.sub.3, or OCH.sub.3 ; R.sub.3 represents H, Cl,CH.sub.3, or OCH.sub.3 ; R.sub.4 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, a tolyl group, or an anisyl group; R.sub.5 represents H, a phenyl group which may be substituted with a COOM group, or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; R.sub.6 represents H or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; X represents SO.sub.3 M or COOM; Y represents --CO-- or --SO.sub.2 --; m represents 1 or 2; n represents 0 or 1; A represents a phenylene group which may have one or more members selected from the group consisting of an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, an amino group, a --COOM group, a hydroxyl group, an --SO.sub.3 M group, and a halogen atom; and M represents an alkali metal, an ammonium group, or an organic amine salt.)
摘要翻译：印刷质量，耐光性和耐水性优异的记录液，其特征在于，其含有水性介质和选自通式[I]〜[V]表示的染料中的至少一种染料：（IV）其中R 1和R 2各自表示H，CH 3或OCH 3; R 3表示H，Cl，CH 3或 OCH 3; R 4表示碳原子数1〜6的烷基，苯基，甲苯基或茴香基; R 5表示H，可以被COOM基取代的苯基或具有1〜被COOM基团取代的3个碳原子; R6表示H或被COOM基团取代的具有1至3个碳原子的烷基; X表示SO 3 M或COOM; Y表示-CO-或-SO 2 - ; m表示 1或2; n表示0或1; A表示可以具有一个或多个选自具有1至4个碳的烷基的一个或多个的亚苯基具有1至4个碳原子的烷氧基，氨基，-COOM基，羟基，-SO 3 M基和卤素原子; M表示碱金属，铵基或有机胺盐。

12. 发明授权

US5599386A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5599386A
公开(公告)日：1997-02-04
申请号：US445797
申请日：1995-05-04
申请人： Hideo Sano , Yukichi Murata , Hiroshi Takimoto
发明人： Hideo Sano , Yukichi Murata , Hiroshi Takimoto
IPC分类号： C09B29/30 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , C09B29/30
摘要： A recording liquid comprising an aqueous medium and at least one selected from the compounds whose free acid form is represented by the formula {1}: ##STR1## wherein, R.sup.1, R.sup.2 and R.sup.3 each independently represent a substituted or unsubstituted C.sub.1-9 alkyl group, a C.sub.1-9 alkoxy group, a halogen, hydrogen, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a C.sub.1-9 alkyl- or C.sub.6-15 aryl-sulfonyl group, a COOH group or a carboxylic ester group;m is a number of 0, 1 or 2; andR.sup.4, R.sup.5 and R.sup.6 each independently represent hydrogen, a C.sub.1-18 alkyl group, a C.sub.2-18 alkenyl group, an aryl group, an aralkyl group, an alicyclic group or a heterocyclic group, any of which groups except hydrogen may have a substituent.
摘要翻译：包含水性介质和选自游离酸形式的由式{1}表示的化合物中的至少一种的记录液体：其代表取代或未取代的C1-9烷基，C1-9烷氧基，卤素，氢，羟基，取代或未取代的氨基甲酰基，取代或未取代的氨磺酰基，取代或未取代的氨基，硝基，磺酸酯基，C1-9烷基或C6-15芳基 - 磺酰基，COOH基或羧酸酯基; m是0，1或2的数字; R 4，R 5和R 6各自独立地表示氢，C 1-18烷基，C 2-18烯基，芳基，芳烷基，脂环族基或杂环基，除氢以外的基团可以具有取代基。

13. 发明授权

US5437716A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5437716A
公开(公告)日：1995-08-01
申请号：US242627
申请日：1994-05-13
申请人： Hideo Sano , Tomio Yoneyama , Yukichi Murata , Masahiro Yamada
发明人： Hideo Sano , Tomio Yoneyama , Yukichi Murata , Masahiro Yamada
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： A recording liquid comprising an aqueous medium and at least one dye selected from dyes, free acid forms of which are represented by formulae (I) and (II): ##STR1## The symbols in formulae (I) and (II) are defined in the specification.
摘要翻译：一种包含水性介质和至少一种选自染料（其游离酸形式由式（I）和（II）表示）的染料的记录液：（I）式（I） I）和（II）在本说明书中定义。

14. 发明授权

US4816435A Transfer sheet for thermal transfer recording 失效
标题翻译：热转印记录转印纸
公开(公告)号：US4816435A
公开(公告)日：1989-03-28
申请号：US54606
申请日：1987-05-27
申请人： Yukichi Murata , Shuichi Maeda
发明人： Yukichi Murata , Shuichi Maeda
IPC分类号： B41M5/035 , B41M5/26 , B41M5/385 , B41M5/39
CPC分类号： B41M5/3858 , B41M5/3854 , B41M5/39 , Y10S428/913 , Y10S428/914 , Y10T428/24975 , Y10T428/264 , Y10T428/265 , Y10T428/31721 , Y10T428/31786
摘要： A transfer sheet for thermal transfer recording system having a color material layer containing sublimable dyes on one surface of a base film, and said color material layer is a black color material layer containing sublimable dyes represented by following formulae (I), (II) and (III); ##STR1## in the above formulae, X and Y represent a hydrogen atom or a methyl group; --A-- represents --CO--, --COO--, or --SO.sub.2 --; and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, and R.sup.7 represent a hydrogen atom or a substituted or unsubstituted alkyl group.
摘要翻译：一种用于热转印记录系统的转印片，其具有在基膜的一个表面上含有可升华的染料的着色材料层，并且所述着色层是含有下式（I），（II）和（三）; （I）（II）在上式中，X和Y表示氢原子或甲基; -A-表示-CO-，-COO-或-SO 2 - ; 并且R 1，R 2，R 3，R 4，R 5，R 6和R 7表示氢原子或取代或未取代的烷基。

15. 发明授权

US5139995A Image receiving sheet for thermal transfer recording and thermal transfer recording method 失效
标题翻译：用于热转印记录和热转印记录方法的图像接收片
公开(公告)号：US5139995A
公开(公告)日：1992-08-18
申请号：US561329
申请日：1990-08-01
申请人： Tsutomu Taki , Yukichi Murata , Katsuhiko Kuroda
发明人： Tsutomu Taki , Yukichi Murata , Katsuhiko Kuroda
IPC分类号： B41M5/52
CPC分类号： B41M5/5254 , Y10S428/913 , Y10S428/914 , Y10T428/265 , Y10T428/31786 , Y10T428/31855
摘要： An image receiving sheet for thermal transfer recording, which comprises a substrate and an image receiving layer formed on the substrate, wherein the image receiving layer comprises, as the main component, a polyvinyl acetal resin of the following formula (I): ##STR1## wherein k, l, m and n represent percentages of the respective structural units in the formula within ranges of 50

16. 发明授权

US5859092A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5859092A
公开(公告)日：1999-01-12
申请号：US840451
申请日：1997-04-18
申请人： Takashi Hirasa , Hiroshi Takimoto , Yukichi Murata , Hiroshi Mikami , Shoji Toki
发明人： Takashi Hirasa , Hiroshi Takimoto , Yukichi Murata , Hiroshi Mikami , Shoji Toki
IPC分类号： C09D11/00 , C09D11/023 , C09D11/037 , C09D11/10 , C09D11/106 , C09D11/107 , C09D11/108 , C09D11/16 , C09D11/17 , C09D11/322 , C09D11/324
CPC分类号： C09D11/326 , C09D11/16 , Y10S260/38
摘要： A recording liquid containing an aqueous medium, a pigment and a polymer, wherein the polymer comprises at least one polymer containing a repeating unit A having at least one of a carboxyl group and an acid anhydride group and an allylether unit B of the formula (I), ##STR1## wherein R.sub.1 and R.sub.2 are a hydrogen atom or a substituted or unsubstituted C.sub.1 -C.sub.5 alkyl group, R.sub.3 is a hydrogen atom, an alkyl group, an alkylcarbonyl group, an alkenyl group, an alkenylcarbonyl group, an aryl group, an arylcarbonyl group, an aralkyl group, an aralkylcarbonyl group, a cycloalkyl group, a cycloalkylcarbonyl group, a heterocyclic group or a carbonyl group having a heterocyclic group, and these groups other than a hydrogen atom may have a substituent, and n is from 1 to 50.
摘要翻译：含有水性介质，颜料和聚合物的记录液体，其中所述聚合物包含至少一种含有具有羧基和酸酐基团中的至少一个的重复单元A的聚合物和式（I）的烯丙基醚单元B ），其中R 1和R 2是氢原子或取代或未取代的C 1 -C 5烷基，R 3是氢原子，烷基，烷基羰基，烯基，链烯基羰基，芳基，芳基羰基，芳烷基，芳烷基羰基，环烷基，环烷基羰基，杂环基或具有杂环基的羰基，这些除氢原子以外的基团可以具有取代基，n 从1到50。

17. 再颁专利

USRE34737E Dye transfer sheet for sublimation heat-sensitive transfer recording 失效
标题翻译：用于升华热敏转印记录的染料转印片
公开(公告)号：USRE34737E
公开(公告)日：1994-09-20
申请号：US696929
申请日：1991-05-08
申请人： Toshio Niwa , Yukichi Murata , Shuichi Maeda
发明人： Toshio Niwa , Yukichi Murata , Shuichi Maeda
IPC分类号： B41M5/39 , C09B53/02 , B41M5/035 , B41M5/38
CPC分类号： B41M5/39 , C09B53/02 , Y10T428/24934 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786
摘要： A dye transfer sheet for heat-sensitive transfer recording which has an ink layer containing a sublimable dye formed on a base film, said sublimable dye being of the formula: ##STR1## wherein --B represents ##STR2## --Z.sup.1 and --Z.sup.2 each represents hydrogen, alkyl optionally substituted by fluorine, alkoxy, halogen or --NHB, K represents ##STR3## --R.sup.1, --R.sup.2, --R.sup.6 and --R.sup.7 each represents hydrogen, C.sub.1 -C.sub.8 substituted or unsubstituted alkyl, substituted or unsubstituted vinyl, allyl or aryl, --R.sup.3, --R.sup.4 and --R.sup.5 each represents hydrogen or methyl, --X represents hydrogen, alkyl optionally substituted by fluorine, alkoxy, formylamino, alkylcarbonylamino optionally substituted by fluorine, arylcarbonylamino or halogen, and --Y represents hydrogen, alkyl optionally substituted by fluorine, alkoxy or halogen.
摘要翻译：一种用于热敏转印记录的染料转印片，其具有含有形成在基膜上的可升华染料的油墨层，所述升华染料具有下式：其中-B表示 - Z1和-Z2各自表示氢，任选被氟取代的烷基，烷氧基，卤素或-NHB，K表示各自的R 1，-R 2，-R 6和-R 7 代表氢，C1-C8取代或未取代的烷基，取代或未取代的乙烯基，烯丙基或芳基，-R3，-R4和-R5各自表示氢或甲基，-X表示氢，任选被氟取代的烷基，烷氧基，甲酰氨基，烷基羰基氨基任选被氟，芳基羰基氨基或卤素取代，-Y表示氢，任选被氟，烷氧基或卤素取代的烷基。

18. 发明授权

US4981748A Heat transfer recording sheet 失效
标题翻译：热转印记录纸
公开(公告)号：US4981748A
公开(公告)日：1991-01-01
申请号：US310587
申请日：1989-02-15
申请人： Yutaka Kawai , Yukio Tsuge , Yukichi Murata , Masahiro Yamamoto
发明人： Yutaka Kawai , Yukio Tsuge , Yukichi Murata , Masahiro Yamamoto
IPC分类号： B41M5/382 , B41M5/40
CPC分类号： B41M5/405 , Y10S428/913 , Y10S428/914 , Y10T428/25 , Y10T428/265 , Y10T428/266 , Y10T428/31786 , Y10T428/31855
摘要： A heat transfer recording sheet comprising a base film, a layer of heat transferable coloring material on one side of the base film and a heat resistant layer on the other side of the base film, wherein said heat resistant layer is formed by curing a mixture comprising a compound of the formula: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is an acryloyl group or a methacryloyl group, and R.sup.6 is an acryloyl group, a methacryloyl group, an alkyloyl group or a hydrogen atom, and a compound of the formula: ##STR2## wherein each of R.sup.7 and R.sup.8 is an acryloyl group or a methacryloyl group, each of R.sup.9 and R.sup.10 is a hydrogen atom, an alkyl group or an aryl group, and each of rings A and B is a benzene ring which may have a lower alkyl group and/or a halogen atom as a substituent, and n is an integer of from 1 to 9, and/or a compound of the formula: ##STR3## wherein each of R.sup.11, R.sup.12 and R.sup.13 is an acryloyl group or a methacryloyl group, and m is an integer of from 0 to 5.

19. 发明授权

US4820685A Transfer sheets for thermal transfer recording 失效
标题翻译：用于热转印记录的转印纸
公开(公告)号：US4820685A
公开(公告)日：1989-04-11
申请号：US146420
申请日：1988-01-21
申请人： Yukichi Murata
发明人： Yukichi Murata
IPC分类号： B41M5/035 , B41M5/26 , B41M5/385 , B41M5/39 , C08L1/08 , C08L3/00 , C08L25/04 , C08L29/14 , C08L33/06 , C08L55/02 , C08L67/00 , C08L69/00 , C08L71/00 , C08L81/06 , C09B25/00 , C09D11/02 , D06P5/13
CPC分类号： B41M5/385 , Y10S428/913 , Y10S428/914 , Y10T428/24975 , Y10T428/31786
摘要： A transfer sheet having on a base film a color material layer containing a quinophthalone series dye of formula (I) and/or a quinophthalone series dye of formula (II), which is used for a sublimation type thermal transfer system: ##STR1## wherein X represents a hydrogen atom or a halogen atom; R.sup.0 represents an alkyl group, an alkoxyalkyl group which may be substituted, an aralkyloxyalkyl group which may be substituted, an allyloxyalkyl group which may be substituted, an aryloxyalkyl group, a tetrahydrofurfuryl group, a furfuryl group, a cycloalkyl group, an allyl group, or an aralkyl group; Y represents a hydrogen atom or a halogen atom; and R.sup.1 and R.sup.2 represent a hydrogen atom, an alkyl group, an alkoxyalkyl group, a cycloalkyl group, an allyl group, an aryl group which may be substituted, an aryl group, an aralkyl group, a furfuryl group, a tetrahydrofurfuryl group, or a hydroxyalkyl group.
摘要翻译：一种转印片，其在基底膜上具有含有式（I）的喹酞酮系列染料和/或式（II）的喹啉酮系列染料的着色材料层，其用于升华型热转印系统：图像>其中X表示氢原子或卤素原子; R 0表示烷基，可被取代的烷氧基烷基，可被取代的芳烷氧基烷基，可被取代的烯丙氧基烷基，芳氧基烷基，四氢糠基，糠基，环烷基，烯丙基，或芳烷基; Y表示氢原子或卤素原子; R 1和R 2表示氢原子，烷基，烷氧基烷基，环烷基，烯丙基，可被取代的芳基，芳基，芳烷基，糠基，四氢糠基或羟基烷基。

20. 发明授权

US4777159A Dye transfer type thermal printing sheets and method for printing 失效
标题翻译：染色转印型热敏打印纸和印刷方法
公开(公告)号：US4777159A
公开(公告)日：1988-10-11
申请号：US729038
申请日：1985-04-30
申请人： Nobuyoshi Taguchi , Akihiro Imai , Toshio Niwa , Yukichi Murata
发明人： Nobuyoshi Taguchi , Akihiro Imai , Toshio Niwa , Yukichi Murata
IPC分类号： B41M5/382 , B41J31/00 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/392 , B41M5/395 , B41M5/40 , B41M5/42 , B41M5/44
CPC分类号： B41M5/42 , B41M5/385 , B41M5/392 , B41M5/395 , B41M5/443 , B41M5/3852 , B41M5/3854 , B41M5/3858 , Y10S428/913 , Y10S428/914 , Y10S430/146 , Y10T428/2438 , Y10T428/25
摘要： The dye transfer type thermal printing sheet and method for printing of this invention are a printing sheet comprising a transfer sheet in which a smooth heat-resistant layer composed of fine particles, a liquid lubricating material and a polymer is formed on one side of a substrate, and on the other side is formed a coloring material layer containing at least one sublimable dye, non-sublimable particles and a binder, a part of said non-sublimable particles jutting out from the reference surface of the sublimable dye layer; and an image-receiving sheet having, on a substrate for image-receiving sheet, a development layer composed of, at least, inorganic fine particles; a binder having dye-affinity and another binder immiscible with said binder; and a dye transfer type thermal method for printing which comprises placing the aforesaid coloring material layer and development layer of the above-mentioned printing sheet face to face with each other, heating the printing sheet selectively from the smooth heat-resistant layer side of the transfer sheet, and thereby forming an image on the image-receiving sheet. By the above-mentioned sheet and method, there can given stable running of transfer sheet and a printed image which is reduced in dropout and noise, has a good depth of color and a good quality of image, and is excellent in storage stability. Further, a full-color image also can be obtained by using three kinds of transfer sheets which develop a cyan color, a magenta color or a yellow color, respectively.
摘要翻译：本发明的染料转印型热敏打印纸和印刷方法是一种印刷纸，其包括转印纸，其中在基材的一侧上形成由细颗粒，液体润滑材料和聚合物构成的光滑耐热层并且另一方面形成着色材料层，其含有至少一种可升华染料，不可升华的颗粒和粘合剂，所述不可升华的颗粒的一部分从升华染料层的参考表面突出出来; 以及图像接收片，其在用于图像接收片的衬底上具有由至少无机细颗粒构成的显影层; 具有染料亲和性的粘合剂和与所述粘合剂不混溶的另一种粘合剂; 以及用于印刷的染料转移型热敏方法，其包括将上述印刷片的上述着色材料层和显影层彼此面对放置，从转印的平滑耐热层侧选择性地加热印刷片从而在图像接收片上形成图像。通过上述片材和方法，可以使转印片材的稳定运行和降低了脱落和噪音的印刷图像，具有良好的颜色深度和良好的图像质量，并且具有优异的储存稳定性。此外，也可以通过使用分别形成青色，品红色或黄色的三种转印片来获得全色图像。

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