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11. 发明申请

US20110236793A1 Highly Stable Fuel Cell Membranes and Methods of Making Them 有权
标题翻译：高度稳定的燃料电池膜及其制备方法
公开(公告)号：US20110236793A1
公开(公告)日：2011-09-29
申请号：US13154695
申请日：2011-06-07
申请人： Vincent A. Durante , William E. Delaney
发明人： Vincent A. Durante , William E. Delaney
IPC分类号： H01M8/10
CPC分类号： H01M8/106 , C08J5/2281 , C08J2327/00 , H01M8/1004 , H01M8/1023 , H01M8/1051 , Y02P70/56
摘要： A solid polymer electrolyte membrane having (a) an ion exchange material and (b) dispersed in said ion exchange material, a hydrogen peroxide decomposition catalyst bound to a carbon particle support, wherein the hydrogen peroxide decomposition catalyst comprises (i) polyvinylphosphonic acid and (ii) cerium.
摘要翻译：一种固体高分子电解质膜，其具有（a）离子交换材料和（b）分散在所述离子交换材料中，与碳粒子载体结合的过氧化氢分解催化剂，其中所述过氧化氢分解催化剂包含（i）聚乙烯基膦酸和（ ii）铈。

12. 发明授权

US5733518A Process and catalyst for dehydrogenation of organic compounds 失效
标题翻译：有机化合物脱氢的工艺和催化剂
公开(公告)号：US5733518A
公开(公告)日：1998-03-31
申请号：US678016
申请日：1996-07-10
申请人： Vincent A. Durante , Daniel E. Resasco , Darrell W. Walker , Gary L. Haller , Eugene L. Coggins
发明人： Vincent A. Durante , Daniel E. Resasco , Darrell W. Walker , Gary L. Haller , Eugene L. Coggins
IPC分类号： B01J8/04 , B01J27/18 , C01B3/00
CPC分类号： B01J8/0453 , B01J27/1813 , B01J27/1815 , B01J2208/00274
摘要： The invention comprises a process for selectively oxidizing hydrogen in a mixture with other gaseous materials by contacting the hydrogen containing gas under oxidation conditions with a catalyst comprising a phosphate of a metal wherein the metal is selected from the group consisting of germanium, tin, lead, arsenic, antimony and bismuth.
摘要翻译：本发明包括通过在氧化条件下使含氢气体与包含金属磷酸盐的催化剂接触来选择性地氧化与其它气态物质的混合物中的氢的方法，其中金属选自锗，锡，铅，砷，锑和铋。

13. 发明申请

US20120006196A1 Capture of mercury from a gaseous mixture containing mercury 有权
公开(公告)号：US20120006196A1
公开(公告)日：2012-01-12
申请号：US13199666
申请日：2011-09-06
申请人： Vincent A. Durante , Zhengtian Xu , Glenn S. Shealy
发明人： Vincent A. Durante , Zhengtian Xu , Glenn S. Shealy
IPC分类号： B01D53/64 , B01J20/32 , B01D53/02
CPC分类号： B01D53/64 , B01D2253/102 , B01D2253/25 , B01D2257/602 , B01J20/20
摘要： Compositions are provided, derived from chemical treatment of carbonaceous fiber felt forms or other carbonaceous substrates, that exhibit both high efficiency and capacity for mercury capture from flue gases and the like. These compositions are superior to known compositions, particularly with regard to their performance under severely deactivating conditions. The compositions result from the pyrolysis of certain specific sulfur bearing compounds while in contact with activated carbon powders, activated carbon fibers, or with other carbonized forms. Precursor compounds to these novel mercury-binding compositions contain structural moieties that may be represented as: where X, Y are individual atoms or are functional groups consisting of several atoms, such that the atom bonding to sulfur is not hydrogen. X and Y can be linked in cyclic structures, either directly or through other atoms.

14. 发明授权

US08034741B2 Capture of mercury from a gaseous mixture containing mercury 有权
标题翻译：从含有汞的气态混合物中捕获汞
公开(公告)号：US08034741B2
公开(公告)日：2011-10-11
申请号：US11270116
申请日：2005-11-09
申请人： Vincent A. Durante , Zhengtian Xu , Glenn S. Shealy
发明人： Vincent A. Durante , Zhengtian Xu , Glenn S. Shealy
IPC分类号： C01B31/08
CPC分类号： B01D53/64 , B01D2253/102 , B01D2253/25 , B01D2257/602 , B01J20/20
摘要： Compositions are provided, derived from chemical treatment of carbonaceous fiber felt forms or other carbonaceous substrates, that exhibit both high efficiency and capacity for mercury capture from flue gases and the like. These compositions are superior to known compositions, particularly with regard to their performance under severely deactivating conditions. The compositions result from the pyrolysis of certain specific sulfur bearing compounds while in contact with activated carbon powders, activated carbon fibers, or with other carbonized forms. Precursor compounds to these novel mercury-binding compositions contain structural moieties that may be represented as: where X, Y are individual atoms or are functional groups consisting of several atoms, such that the atom bonding to sulfur is not hydrogen. X and Y can be linked in cyclic structures, either directly or through other atoms.
摘要翻译：提供了组合物，其衍生自含碳纤维毡形式或其它含碳底物的化学处理，其表现出从烟道气等捕获汞的高效率和高容量。这些组合物优于已知的组合物，特别是关于它们在严重失活条件下的性能。组合物是由与特定含硫化合物热解而与活性炭粉，活性碳纤维或其他碳化形式接触而产生的。这些新型汞结合组合物的前体化合物含有可以表示为：其中X，Y是单个原子或由几个原子组成的官能团，使得与硫结合的原子不是氢的结构部分。 X和Y可以直接或通过其他原子连接在环状结构中。

15. 发明授权

US07989115B2 Highly stable fuel cell membranes and methods of making them 有权
标题翻译：高度稳定的燃料电池膜及其制备方法
公开(公告)号：US07989115B2
公开(公告)日：2011-08-02
申请号：US11956819
申请日：2007-12-14
申请人： Vincent A. Durante , William E. Delaney
发明人： Vincent A. Durante , William E. Delaney
IPC分类号： H01M8/10 , B01D71/36 , B01D69/14 , C08J5/22 , C25B13/08
CPC分类号： H01M8/106 , C08J5/2281 , C08J2327/00 , H01M8/1004 , H01M8/1023 , H01M8/1051 , Y02P70/56
摘要： A solid polymer electrolyte membrane having (a) an ion exchange material and (b) dispersed in said ion exchange material, a hydrogen peroxide decomposition catalyst bound to a carbon particle support, wherein the hydrogen peroxide decomposition catalyst comprises (i) polyvinylphosphonic acid and (ii) cerium.
摘要翻译：一种固体高分子电解质膜，其具有（a）离子交换材料和（b）分散在所述离子交换材料中，与碳粒子载体结合的过氧化氢分解催化剂，其中所述过氧化氢分解催化剂包含（i）聚乙烯基膦酸和（ ii）铈。

16. 发明授权

US5540833A Sulfur tolerant bimetallic zeolitic reforming catalysts 失效
标题翻译：耐硫双金属沸石重整催化剂
公开(公告)号：US5540833A
公开(公告)日：1996-07-30
申请号：US189268
申请日：1994-01-31
申请人： Gustavo Larsen , Gary L. Haller , Daniel E. Resasco , Vincent A. Durante
发明人： Gustavo Larsen , Gary L. Haller , Daniel E. Resasco , Vincent A. Durante
IPC分类号： C07B61/00 , B01J29/62 , B01J29/63 , B01J29/72 , C10G35/09 , C10G35/095 , C10G45/64 , C10G45/70 , B01J29/068
CPC分类号： C10G35/095 , B01J29/62 , B01J29/63
摘要： New compositions of matter comprise a metal from the group consisting of platinum, rhodium and palladium, a metal from the first row of Group VIII of the Periodic Table and a nonacidic L-zeolite. A preferred composition is Pt--Ni/KL-zeolite. Such catalysts are prepared by coimpregnation of the zeolite with the metals. Methods of using the catalysts in reforming, aromatization or dehydrogenation are provided.
摘要翻译：新的物质组合物包括来自铂，铑和钯的金属，来自元素周期表第Ⅷ族的第一排的金属和非酸的L-沸石。优选的组合物是Pt-Ni / KL-沸石。这样的催化剂是通过将沸石与金属共浸渍来制备的。提供了在重整，芳构化或脱氢中使用催化剂的方法。

17. 发明授权

US5439859A Process and catalyst for dehydrogenation of organic compounds 失效
标题翻译：有机化合物脱氢的工艺和催化剂
公开(公告)号：US5439859A
公开(公告)日：1995-08-08
申请号：US874499
申请日：1992-04-27
申请人： Vincent A. Durante , Daniel E. Resasco , Darrell W. Walker , Gary L. Haller , Eugene L. Coggins
发明人： Vincent A. Durante , Daniel E. Resasco , Darrell W. Walker , Gary L. Haller , Eugene L. Coggins
IPC分类号： B01J8/04 , B01J23/755 , B01J27/18 , C07B35/04 , C07C5/333 , B01J29/064 , B01J29/072
CPC分类号： B01J37/0207 , B01J23/755 , B01J23/866 , B01J27/1813 , B01J27/1815 , B01J29/24 , B01J29/63 , B01J8/0453 , C07B35/04 , C07C5/3335 , B01J2208/00274 , Y02P20/128
摘要： Alkanes are dehydrogenated by passage through alternating dehydrogenation zones and selective oxidation zone(s), in which latter zone(s) hydrogen produced in the preceding endothermic dehydrogenation reaction is selectively oxidized to generate heat for the succeeding dehydrogenation reaction. New catalyst compositions are prepared comprising reduced and sulfided nickel crystallites on siliceous supports which have been treated with chromium compounds and oxidized to provide surface-anchored chromyl species. Also new catalyst compositions are prepared by sulfiding nickel-containing compositions with carbonaceous sulfur compounds such as dialkylsulfoxides. Another embodiment of the invention is catalyst and dehydrogenation therewith, in which pores having radius of 50 to 200 Angstroms occupy pore volume from 0.30 to 1.50 ml per gram of the support, and pores having radius of 20 to 50 Angstroms occupy pore volume less than 0.1 ml per gram of the support. In another embodiment, alkanes are dehydrogenated using as catalyst a metal or metal compound having dehydrogenating activity supported on alkali-treated alumina.
摘要翻译：烷烃通过通过交替脱氢区和选择性氧化区脱氢，其中在先前吸热脱氢反应中产生的后一个区域被选择性氧化以产生用于随后的脱氢反应的热。制备新的催化剂组合物，其包含已经用铬化合物处理并被氧化以提供表面锚定的染色体物质的硅质载体上的还原和硫化的镍微晶。还通过用含碳硫化合物如二烷基亚砜将含硫组合物硫化来制备新的催化剂组合物。本发明的另一个实施方案是催化剂和其脱氢，其中具有50至200埃半径的孔占每克载体的0.30至1.50ml的孔体积，并且半径为20至50埃的孔隙占孔体积小于0.1 ml每克支持。在另一个实施方案中，使用负载在碱处理的氧化铝上的具有脱氢活性的金属或金属化合物作为催化剂使烷烃脱氢。

18. 发明申请

US20090155662A1 Highly Stable Fuel Cell Membranes and Methods of Making Them 有权
标题翻译：高度稳定的燃料电池膜及其制备方法
公开(公告)号：US20090155662A1
公开(公告)日：2009-06-18
申请号：US11956819
申请日：2007-12-14
申请人： Vincent A. Durante , William E. Delaney
发明人： Vincent A. Durante , William E. Delaney
IPC分类号： H01M8/10 , C08L85/02 , C08G79/04
CPC分类号： H01M8/106 , C08J5/2281 , C08J2327/00 , H01M8/1004 , H01M8/1023 , H01M8/1051 , Y02P70/56
摘要： A solid polymer electrolyte membrane having (a) an ion exchange material and (b) dispersed in said ion exchange material, a hydrogen peroxide decomposition catalyst bound to a carbon particle support, wherein the hydrogen peroxide decomposition catalyst comprises (i) polyvinylphosphonic acid and (ii) cerium.
摘要翻译：一种固体高分子电解质膜，其具有（a）离子交换材料和（b）分散在所述离子交换材料中，与碳粒子载体结合的过氧化氢分解催化剂，其中所述过氧化氢分解催化剂包含（i）聚乙烯基膦酸和（ ii）铈。

19. 发明授权

US06872364B2 Apparatus for endothermic reactions of organic compounds 失效
标题翻译：有机化合物吸热反应装置
公开(公告)号：US06872364B2
公开(公告)日：2005-03-29
申请号：US10331367
申请日：2002-12-30
申请人： Thomas W. Bierl , Vincent A. Durante , Lawrence H. Finkel , Daniel E. Resasco
发明人： Thomas W. Bierl , Vincent A. Durante , Lawrence H. Finkel , Daniel E. Resasco
IPC分类号： B01J8/04 , B01J23/755 , B01J27/18 , C07B35/04 , C07C5/333 , F27B15/14 , C07C5/393
CPC分类号： B01J8/0453 , B01J23/755 , B01J23/866 , B01J27/1813 , B01J27/1815 , B01J29/24 , B01J29/63 , B01J37/0207 , B01J2208/00274 , C07B35/04 , C07C5/3335 , Y02P20/584 , C07C11/08
摘要： An apparatus for conducting an endothermic reaction of an organic' compound in the presence of molecular hydrogen and of multicomponent solids is described. The process of operating the apparatus comprises contacting the compound with a solid catalyst for the endothermic reaction and a hydrogen oxidizing solid reagent intermixed with the solid catalyst. Organic products of the endothermic reaction are produced, with evolution of molecular hydrogen. The solid catalyst becomes gradually deactivated by formation of carbonaceous deposits thereon. The evolved hydrogen undergoes an exothermic reaction with the hydrogen oxidizing solid reagent to form a reduction product which comprises deactivated hydrogen oxidizing solid reagent. The deactivated solid catalyst is reactivated by combustion of carbonaceous deposits thereon and the deactivated hydrogen oxidizing solid reagent is reactivated by contacting the reagent with an oxidizing agent in the absence of substantial quantities of hydrogen and in the absence of substantial quantities of organic compounds other than those on the surface of the reagent. The apparatus provides an endothermic reaction which is carried out in the presence of a fluidized bed of catalyst and in the presence of particles of granular hydrogen oxidizing solid reagent which move downwardly through the fluidized catalyst bed, and in which the solid catalyst and solid reagent are separated prior to reactivation thereof in separate reactivation zones.
摘要翻译：描述了在分子氢和多组分固体存在下进行有机化合物的吸热反应的装置。操作该装置的过程包括使化合物与用于吸热反应的固体催化剂和与固体催化剂混合的氢氧化固体试剂接触。随着分子氢的发展，产生吸热反应的有机产物。固体催化剂通过在其上形成碳质沉积物而逐渐失活。放出的氢气经历与氢氧化固体试剂的放热反应，形成还原产物，其包含失活的氢氧化固体试剂。失活的固体催化剂通过其上的碳质沉积物的燃烧而再活化，并且通过在不存在大量氢气的情况下将试剂与氧化剂接触并且在不存在大量的除了那些之外的大量有机化合物的情况下，使失活的氢氧化固体试剂再活化在试剂的表面。该装置提供吸热反应，其在催化剂的流化床存在下和在向下移动通过流化催化剂床的颗粒氢氧化固体试剂存在下进行，其中固体催化剂和固体试剂为在分离的再活化区域中再分离。

20. 发明授权

US5962752A Leached alumina vanadyl catalysts for hydroxylation of aromatics using molecular oxygen as the terminal oxidant without coreductant 失效
标题翻译：使用分子氧作为末端氧化剂而不含助催化剂的沥青氧化铝氧钒催化剂用于芳族化合物的羟基化
公开(公告)号：US5962752A
公开(公告)日：1999-10-05
申请号：US903824
申请日：1997-07-31
申请人： Vincent A. Durante , Tilak P. Wijesekera , Swati Karmakar
发明人： Vincent A. Durante , Tilak P. Wijesekera , Swati Karmakar
IPC分类号： C07B41/02 , C07C37/58 , C07C37/00
CPC分类号： C07B41/02 , B01J23/22 , B01J37/0207 , C07C37/58 , B01J37/0009 , B01J37/06 , Y02P20/52
摘要： A process is disclosed for the catalytic hydroxylation of aromatic hydrocarbons which comprises contacting aromatic feedstock with oxidant comprising molecular oxygen, under suitable reaction conditions, in the presence of a catalyst comprising vanadyl (V.sup.IV) on an alumina support, preferably on leached alumina. The process is particularly suited, for example, to the one-step conversion of benzene to phenol.
摘要翻译：公开了用于芳烃的催化羟基化的方法，其包括在合适的反应条件下，在氧化铝载体上，优选在浸提的氧化铝上的包含氧钒（VIV）的催化剂存在下使芳族原料与包含分子氧的氧化剂接触。该方法特别适用于例如苯到苯的一步转化。

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