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    • 11. 发明申请
    • CROSSLINKED OLEFIN POLYMERS AND PROCESS FOR PRODUCTION THEREOF
    • 交联烯烃聚合物及其生产方法
    • US20090018288A1
    • 2009-01-15
    • US11718834
    • 2005-11-07
    • Ryo AburataniYutaka ObataTomoaki TakebeMasanori SeraYutaka Minami
    • Ryo AburataniYutaka ObataTomoaki TakebeMasanori SeraYutaka Minami
    • C08F10/14C08F8/00
    • C08F10/14C08F4/65908C08F4/65912C08F4/65927C08F8/00C08F110/14C08F210/14C08F2500/20C08F2500/04C08F2500/03
    • Crosslinked olefin polymers which are reduced in stickiness and improved in rigidity, heat resistance, light resistance, and water resistance while retaining the molding properties such as injection moldability, spinnability, film-forming properties and the physical properties such as toughness (including elongation and break strength) and tackiness; and a process for the production thereof. Crosslinked olefin polymers which are obtained by reacting an α-olefin polymer produced by polymerization of at least one α-olefin having 6 or more carbon atoms or polymerization of at least one α-olefin having 6 or more carbon atoms with at least one other α-olefin with a crosslinking agent and which satisfy the following requirements: (1) the content of units of α-olefins having 6 or more carbon atoms is 50 mol % or more, (2) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC) is 7.0 or more in terms of polystyrene, (3) the content of components having weight-average molecular weights (Mw) of 106 or more is 5% by mass or more as determined by GPC, and (4) the stereoregularity indication M4 is 75 mol % or less; and a process for the production of the polymers.
    • 在保持成型性,如注塑成型性,纺丝性,成膜性以及韧性(包括伸长率和断裂性等)的物理性能的同时,粘合性降低,刚性,耐热性,耐光性和耐水性降低的交联烯烃聚合物 强度)和粘性; 及其生产方法。 通过使至少一种具有6个或更多个碳原子的至少一种α-烯烃聚合而产生的α-烯烃聚合物或至少一种具有6个或更多个碳原子的至少一个碳原子的α-烯烃与至少一种其它的α-烯烃反应而获得的交联烯烃聚合物 (1)具有6个或更多个碳原子的α-烯烃的单元含量为50摩尔%以上,(2)分子量分布(Mw / Mn)为 通过凝胶渗透色谱法(GPC)测定的聚苯乙烯换算为7.0以上,(3)通过GPC测定,重均分子量(Mw)为106以上的成分的含量为5质量%以上, (4)立构规整性指示M4为75摩尔%以下; 以及聚合物的制造方法。
    • 12. 发明申请
    • RESIN FOR OPTICAL COMPONENT, RAW MATERIAL COMPOSITION USED FOR RESIN FOR OPTICAL COMPONENT, AND OPTICAL COMPONENT
    • 光学元件用树脂,用于光学元件的树脂的原料组合物和光学组分
    • US20100324246A1
    • 2010-12-23
    • US12667166
    • 2008-06-30
    • Yutaka ObataTakeshi IwasakiTomoaki Takebe
    • Yutaka ObataTakeshi IwasakiTomoaki Takebe
    • C08F120/18C08F230/08
    • C08F220/68C08F222/1006G02B1/04C08L33/10C08L33/08C08L67/00
    • Provided are a resin for an optical component, which has heat resistance, does not suffer from yellowing because of its stability against heat, and is excellent in transparency and workability; a raw material composition used for the resin for an optical component; and an optical component. Specifically, provided is a resin for an optical component containing a (meth)acrylate compound unit (A1), in which a hydrocarbon group containing an adamantane structure is ester-bonded, and a (meth)acrylate compound unit (B1) having a polyfunctional group, which is other than the unit (A1). Also, provided is a raw material composition used for a resin for an optical component, which contains a (meth)acrylate compound (A2) in which a hydrocarbon group containing an adamantane structure is ester-bonded, and a (meth)acrylate compound (B2) having a polyfunctional group, which is other than the compound (A2). Further, provided is an optical component which is obtained by polymerizing and molding the raw material composition.
    • 提供一种光学部件用树脂,其具有耐热性,耐热稳定性不会发黄,并且透明性和加工性优异; 用于光学部件的树脂的原料组合物; 和光学部件。 具体地说,提供了含有(甲基)丙烯酸酯化合物单元(A1)的含有金刚烷结构的烃基酯键合的光学部件用树脂和具有多官能团的(甲基)丙烯酸酯化合物单元(B1) 组(A1)。 另外,作为光学部件用树脂,使用含有金刚烷结构的烃基进行酯键合的(甲基)丙烯酸酯化合物(A2)和(甲基)丙烯酸酯化合物( B2)具有不同于化合物(A2)的多官能团。 此外,提供了通过聚合和成型原料组合物而获得的光学部件。
    • 14. 发明授权
    • Crystalline polypropylene and its moldings and films
    • 结晶聚丙烯及其模制品和薄膜
    • US06639038B2
    • 2003-10-28
    • US09963591
    • 2001-09-27
    • Itaru KuramotoYutaka ObataTsuyoshi OtaToshio IsozakiJunichi AmanoTakashi Sumitomo
    • Itaru KuramotoYutaka ObataTsuyoshi OtaToshio IsozakiJunichi AmanoTakashi Sumitomo
    • C08F11006
    • C08F110/06C08F2500/17C08F2500/03C08F2500/26
    • A first crystalline polypropylene of the present invention satisfies the relationships of the following formulae (1) and (2): &agr;≦−0.42×ln(Mp)+7.3  (1),and Tm>1.85×ln(Mp)+144.5  (2), wherein &agr; is a 0° C. soluble content (% by weight) as measured through programmed-temperature fractionation, Mp is a peak molecular weight in a molecular weight distribution curve as measured through gel permeation chromatography, and Tm is a melting point (° C.) as measured through differential scanning calorimetry. A second crystalline polypropylene of the present invention satisfies the relationship given in the following formula (3): &agr;≦1.11[&eegr;]−0.42+1.40  (3) wherein &agr; is the same as above and [&eegr;] an intrinsic viscosity (dl/g) as measured in a tetralin solvent at 135° C. Moldings and films made of the first or second crystalline polypropylene are highly rigid and have good heat resistance and good scratch resistance.
    • 本发明的第一结晶聚丙烯满足下式(1)和(2)的关系:其中α为通过程序温度分馏法测定的0℃可溶成分(重量%),Mp为峰 通过凝胶渗透色谱法测定的分子量分布曲线中的分子量,Tm是通过差示扫描量热法测定的熔点(℃)。 本发明的第二结晶聚丙烯满足下式(3)中给出的关系:其中α与上述相同,η在135℃下在四氢化萘溶剂中测得的特性粘度(dl / g) 由第一或第二结晶聚丙烯制成的模制品和薄膜是高度刚性的并且具有良好的耐热性和良好的耐擦伤性。
    • 15. 发明授权
    • Process for preparing polybutadiene having a 1,2-configuration content
of 5-40% and a cis-1,4-configuration content of 60% or more
    • 制备1,2-构型含量为5-40%,顺式-1,4-构型含量为60%以上的聚丁二烯的方法
    • US4340685A
    • 1982-07-20
    • US228625
    • 1981-01-26
    • Yasumasa TakeuchiYutaka ObataNoboru OhshimaTooru ShibataKaoru Nakako
    • Yasumasa TakeuchiYutaka ObataNoboru OhshimaTooru ShibataKaoru Nakako
    • C08F2/00C08F2/04C08F2/06C08F2/44C08F4/00C08F4/26C08F4/60C08F4/70C08F36/00C08F36/06C08F136/06
    • C08F136/06
    • A process for preparing polybutadiene having a 1,2-configuration content of 5-40% and a cis-1,4-configuration content of 60% or more, which comprises polymerizing 1,3-butadiene in the presence of a catalyst consisting of:(A) a cobalt compound,(B) at least one member selected from the group consisting of:(i) a trialkylaluminum,(ii) a reaction product of a trialkylaluminum and an alcohol or water,(iii) a mixture of a trialkylaluminum and a dialkylaluminum halide,(iv) a dialkylaluminum hydride, and(v) an organolithium compound, and(C) at least one compound selected from the group consisting of phenyl isothiocyanate and carbon disulfide, in a hydrocarbon or halogenated hydrocarbon solution of a high cis-1,4-polybutadiene obtained by polymerizing 1,3-butadiene with a catalyst consisting of:(D) at least one compound selected from the group consisting of the organocarboxylates of nickel and organic complex compounds of nickel,(E) at least one compound selected from the group consisting of boron trifluoride, boron trifluoride complex compounds and hydrogen fluoride, and(F) at least one compound selected from the group consisting of the organometallic compounds of the alkali metals of the Group II or III metals of the Periodic Table. The polybutadiene produced by this process has an improved tear strength and improved flexural fatigue properties.
    • 一种制备1,2-构型含量为5-40%,顺式-1,4-构型含量为60%以上的聚丁二烯的方法,其包括在催化剂存在下将1,3-丁二烯聚合,所述催化剂由 :(A)钴化合物,(B)选自由以下组成的组中的至少一种:(i)三烷基铝,(ii)三烷基铝与醇或水的反应产物,(iii) 三烷基铝和二烷基卤化铝,(iv)氢化二烷基铝,和(v)有机锂化合物,和(C)至少一种选自异硫氰酸苯酯和二硫化碳的化合物在烃或卤代烃溶液中 通过由以下组成的催化剂聚合1,3-丁二烯获得的高顺式-1,4-聚丁二烯:(D)至少一种选自镍的有机羧酸盐和镍的有机络合物的化合物,(E)在 选自组中的至少一种化合物 三氟化硼配位化合物和氟化氢,和(F)选自元素周期表第二或第三族金属的碱金属的有机金属化合物中的至少一种化合物。 通过该方法制备的聚丁二烯具有改进的撕裂强度和改善的弯曲疲劳性能。
    • 18. 发明授权
    • Air conditioner system for an automotive vehicle having main and
auxiliary cooling unit
    • 具有主和辅助冷却单元的机动车辆的空调系统
    • US4470270A
    • 1984-09-11
    • US356450
    • 1982-03-09
    • Yutaka TakadaYutaka Obata
    • Yutaka TakadaYutaka Obata
    • B60H1/00B60H1/32F24F11/02F25B5/02G05D23/19B60H3/04
    • B60H1/323F25B5/02G05D23/1919
    • An air conditioner system for an automotive vehicle is provided with a main and an auxiliary cooling unit for discharging cooling air to respective front and rear portions of the vehicle compartment. The main and auxiliary cooling units operate to control air flow amounts independently of each other. A main control switch for controlling the amount of cooling air from the main cooling unit cooperates with a pair of auxiliary cooling unit switches to control the auxiliary cooling unit. One member of the pair of auxiliary cooling unit switches is provided adjacent the driver's seat and the other adjacent the rear seat for turning the auxiliary cooling unit on and off. The auxiliary cooling unit can be controlled by either one of the pair of switches as long as the main control switch is on.
    • 一种用于机动车辆的空调系统设置有用于将冷却空气排放到车厢的相应前部和后部的主冷却单元和辅助冷却单元。 主和辅助冷却单元操作以彼此独立地控制空气流量。 用于控制来自主冷却单元的冷却空气量的主控制开关与一对辅助冷却单元开关配合以控制辅助冷却单元。 一对辅助冷却单元开关中的一个构件设置在驾驶员座位附近,而另一个辅助冷却单元开关设置在后座上,用于打开和关闭辅助冷却单元。 只要主控开关打开,辅助冷却单元可以由一对开关中的任一个控制。
    • 20. 发明授权
    • Propylene resin composition and process for producing the same
    • 丙烯树脂组合物及其制备方法
    • US06407168B1
    • 2002-06-18
    • US09674524
    • 2000-11-21
    • Yasuhisa SugitaTakashi SaekiHiroki NakashimaMasaru NakagawaKenichi MitsuhashiYutaka Obata
    • Yasuhisa SugitaTakashi SaekiHiroki NakashimaMasaru NakagawaKenichi MitsuhashiYutaka Obata
    • C08L2312
    • C08J3/005B29C47/0011B29C47/50C08F297/083C08J2323/12C08L23/10C08L23/12C08L23/16C08L53/00C08L2205/02C08L2666/04C08L2666/24
    • Provided are a propylene resin composition comprising 100 parts byweight in total of two different types of propylene polymers each having specific properties, from 0 to 50 parts by weight of a specific elastomer, and from 0 to 50 parts by weight of an inorganic filler; and a method for producing it. The production method comprises melting and kneading two polymer groups each comprising one or more propylene polymers. The resin composition in which the viscosity difference between the propylene homopolymer segments to form the base polymer and the amorphous propylene segments to form the disperse phase is small is produced by first melting and kneading one polymer group, then immediately adding the other polymer group thereto, and further kneading and melting the two. For the composition in which the viscosity difference therebetween is large, the polymer groups are separately kneaded in melt, and the resulting melts are further kneaded. The propylene resin composition has high stiffness, high impact resistance and high fluidity, and its moldings have good appearances.
    • 提供一种丙烯树脂组合物,其包含100重量份的总共两种不同类型的具有特定性质的丙烯聚合物,0至50重量份的特定弹性体和0至50重量份的无机填料; 及其制造方法。 该制备方法包括熔融和捏合两种各自包含一种或多种丙烯聚合物的聚合物基团。 通过首先熔融和捏合一个聚合物基团,然后立即向其中加入另一个聚合物基团,产生其中形成基础聚合物的丙烯均聚物链段和形成分散相的无定形丙烯链段之间的粘度差小的树脂组合物, 并进一步捏合和熔融两者。 对于其间的粘度差较大的组合物,将聚合物基团分别捏合在熔体中,并将​​所得熔体进一步捏合。 丙烯树脂组合物具有高刚度,高抗冲击性和高流动性,并且其模制品具有良好的外观。