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11. 发明授权

US5264601A N,O-bis(trimethylsilyl) acetamide stabilization 失效
标题翻译： N，O-双（三甲基甲硅烷基）乙酰胺稳定化
公开(公告)号：US5264601A
公开(公告)日：1993-11-23
申请号：US921250
申请日：1992-07-29
申请人： Toshio Shinohara , Muneo Kudo , Susumu Ueno , Masao Maruyama
发明人： Toshio Shinohara , Muneo Kudo , Susumu Ueno , Masao Maruyama
IPC分类号： C07D277/72 , C07D277/74 , C07D277/76 , C07F7/18 , C07F7/10
CPC分类号： C07F7/1852
摘要： N,O-bis(trimethylsilyl)acetamide is improved in thermal stability by adding about 0.01 to 5 mol % of a 2-mercaptobenzothiazole or a salt thereof thereto.

12. 发明申请

US20060240268A1 Protective coat-forming coating composition, coated article, and multilayer laminate 审中-公开
标题翻译：保护涂层形成涂料组合物，涂覆制品和多层层压材料
公开(公告)号：US20060240268A1
公开(公告)日：2006-10-26
申请号：US11454979
申请日：2006-06-19
申请人： Masaaki Yamaya , Kazuharu Sato , Muneo Kudo
发明人： Masaaki Yamaya , Kazuharu Sato , Muneo Kudo
IPC分类号： B32B17/10 , B32B27/06 , B32B9/04
CPC分类号： C09D183/14 , C09D4/00 , Y10T428/3154 , Y10T428/31612 , Y10T428/31663 , C08G77/24
摘要： A coating composition primarily comprising a disilane compound of the formula (A): XmR13-mSi—Y—SiR13-mXm (A) wherein R1 is a monovalent hydrocarbon group, Y is a divalent fluorinated organo group, X is a hydrolyzable group, and m is 1, 2 or 3, or a (partial) hydrolyzate thereof is applied and cured to form a protective coat having excellent chemical resistance and antireflection.
摘要翻译：主要包含式（A）的乙硅烷化合物的涂料组合物：<？in-line-formula description =“In-line formula”end =“lead”？> X＆lt; （A）3-m Si-Y-SiR 1 - 3-m X（A）其中R 1是一价烃基，Y是二价氟化有机基团，X是可水解的基团，m为1,2或3，或其（部分）水解产物被施加和固化以形成具有优异的耐化学性和抗反射性的保护涂层。

13. 发明授权

US06656598B2 Aqueous coating composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US06656598B2
公开(公告)日：2003-12-02
申请号：US09973768
申请日：2001-10-11
申请人： Muneo Kudo , Masaaki Yamaya
发明人： Muneo Kudo , Masaaki Yamaya
IPC分类号： B32B904
CPC分类号： C09D183/08 , C08K5/06 , Y10T428/31663 , C08L83/08 , C08L2666/34 , C08L2666/14
摘要： An aqueous coating composition including (A) an amino group-containing organopolysiloxane, (B) water and (C) at least one of a surface-active agent represented by the general formula (I): wherein R1 to R4are a C1-C8 alkyl group, R5 and R6 are a C1-C6 alkylene group, R7 and R8 are selected from a hydrogen atom, a C1-C6 alkyl group and a C2-C6 acyl group, and m and n are an integer of 0 to 40, provided that m and n are not 0 at the same time and that of m+n ranges from 1 to 40 on the average; and a nonionic surface-active agent containing a perfluoroalkyl group and an alkylene oxide group. In the composition, (C) is present in a content of 0.01% to 5% by weight based on the total of (A), (B) and (C), and an alcohol is present in an amount not more than 10% by weight of the composition. The aqueous coating composition has superior uniform-coating properties and storage stability.
摘要翻译：一种水性涂料组合物，其包含（A）含氨基的有机聚硅氧烷，（B）水和（C）由通式（I）表示的表面活性剂中的至少一种：其中R 1至R 4 >是C 1 -C 8烷基，R 5和R 6是C 1 -C 6亚烷基，R 7和R 8选自氢原子，C 1 -C 6烷基和 C2-C6酰基，m和n为0〜40的整数，条件是m和n不同时为0，m + n的平均值为1〜40; 和含有全氟烷基和环氧烷基的非离子表面活性剂。在组合物中，（C）的含量相对于（A），（B）和（C）的总量为0.01〜5重量％，醇的含量不超过10重量％的组合物。水性涂料组合物具有优异的均匀涂布性能和储存稳定性。

14. 发明申请

US20100022705A1 PREPARATION OF HYDROLYZABLE GROUP-CONTAINING ORGANOHYDROGENPOLYSILOXANE AND ORGANOPOLYSILOXANE DERIVED THEREFROM 有权
标题翻译：含有可氢化基团的组氨酸聚氧乙烯醚和衍生自其的有机聚硅氧烷的制备
公开(公告)号：US20100022705A1
公开(公告)日：2010-01-28
申请号：US12504019
申请日：2009-07-16
申请人： Masahiro Amemiya , Hitoshi Uehara , Muneo Kudo , Mitsuo Asai
发明人： Masahiro Amemiya , Hitoshi Uehara , Muneo Kudo , Mitsuo Asai
IPC分类号： C08L83/04
CPC分类号： C08G77/12 , C08G77/08 , C08G77/34 , C08G77/38
摘要： A hydrolyzable group-containing organohydrogenpolysiloxane is prepared by (A) reacting (a) an organosiloxane with (b) an organosilane or organosiloxane containing a hydrolyzable group, at least one of components (a) and (b) containing hydrosilyl, in the presence of a superstrong acid catalyst, (B) adding an inorganic basic neutralizing agent and/or an adsorbent to the resulting reaction solution, and (C) removing the neutralized and/or adsorbed form of the superstrong acid catalyst. The process proceeds in an essentially non-aqueous system, and the organohydrogenpolysiloxane free of residual acidic catalyst is obtainable at low cost.
摘要翻译：通过（A）使（a）有机硅氧烷与（b）含有可水解基团的有机硅烷或有机硅氧烷，含有氢化甲硅烷基的组分（a）和（b）中的至少一种在有机硅氧烷存在下反应制备可水解基团的有机氢聚硅氧烷）超强酸催化剂，（B）向所得反应溶液中添加无机碱性中和剂和/或吸附剂，（C）除去超强酸催化剂的中和和/或吸附形式。该方法在基本上非水系统中进行，并且以低成本获得不含残留酸性催化剂的有机氢聚硅氧烷。

15. 发明授权

US06316155B1 External additive for electrostatically charged latent image developing toner 有权
标题翻译：用于静电充电潜像显影调色剂的外用添加剂
公开(公告)号：US06316155B1
公开(公告)日：2001-11-13
申请号：US09524907
申请日：2000-03-13
申请人： Muneo Kudo , Masaki Tanaka , Yoshiteru Sakatsume , Shoji Ichinohe , Mitsuo Asai
发明人： Muneo Kudo , Masaki Tanaka , Yoshiteru Sakatsume , Shoji Ichinohe , Mitsuo Asai
IPC分类号： G03G908
CPC分类号： C09C1/3081 , C01P2004/32 , C01P2004/62 , G03G9/09725
摘要： An external additive for electrostatically charged latent image developing toner is provied. The additive includes spherical hydrophobic fine silica particles having primary particles having a particle diameter of from 0.01 to 5 &mgr;m, which fine silica particles fulfill the following conditions (i) and (ii): (i) when an organic compound which is liquid at room temperature and has a dielectric constant of from 1 to 40 F/m and fine silica particles are mixed in a weight ratio of 5:1 and shaken, the fine silica particles disperse uniformly in the organic compound; and (ii) the quantity of primary particles remaining as primary particles when methanol is evaporated under heating by means of an evaporator from a dispersion prepared by dispersing the fine silica particles in methanol and thereafter the particles are held at a temperature of 100° C. for 2 hours, represents at least 20% of the quantity of primary particles originally present. The external additive does not react or has no interaction with an organic photoreceptor and therefore change in quality does not occur or the photoreceptor is not scraped. Furthermore, it has a good flowability and therefore adhesion of a toner to the photoreceptor does not occur.
摘要翻译：证明了静电充电潜像显影调色剂的外用添加剂。添加剂包括具有粒径为0.01〜5μm的一次粒子的球状疏水性细二氧化硅粒子，二氧化硅微粒满足以下条件（i）和（ii）：（i）当室内为液体的有机化合物时介电常数为1〜40F / m，二氧化硅微粒以5:1的重量比混合并摇动，二氧化硅微粒分散在有机化合物中; 和（ii）当通过蒸发器在加热下从通过将二氧化硅微粒分散在甲醇中制备的分散体蒸发而蒸发甲醇时的初级颗粒的量，然后将颗粒保持在100℃的温度。 2小时，表示原始存在的初级粒子的量的至少20％。外部添加剂不与有机感光体反应或没有相互作用，因此不会发生质量变化或感光体不被刮擦。此外，它具有良好的流动性，因此不会发生调色剂对感光体的粘附。

16. 发明授权

US07226982B2 Protective coat-forming coating composition, coated article, and multilayer laminate 有权
标题翻译：保护涂层形成涂料组合物，涂覆制品和多层层压材料
公开(公告)号：US07226982B2
公开(公告)日：2007-06-05
申请号：US10824393
申请日：2004-04-15
申请人： Masaaki Yamaya , Kazuharu Sato , Muneo Kudo
发明人： Masaaki Yamaya , Kazuharu Sato , Muneo Kudo
IPC分类号： C08G77/24
CPC分类号： C09D183/14 , C09D4/00 , Y10T428/3154 , Y10T428/31612 , Y10T428/31663 , C08G77/24
摘要： A coating composition primarily comprising a disilane compound of the formula (A): XmR13−mSi—Y—SiR13−mXm (A) wherein R1 is a monovalent hydrocarbon group, Y is a divalent fluorinated organo group, X is a hydrolyzable group, and m is 1, 2 or 3, or a (partial) hydrolyzate thereof is applied and cured to form a protective coat having excellent chemical resistance and antireflection.
摘要翻译：主要包含式（A）的乙硅烷化合物的涂料组合物：<？in-line-formula description =“In-line formula”end =“lead”？> X＆lt; （A）3-m Si-Y-SiR 1 - 3-m X（A）其中R 1是一价烃基，Y是二价氟化有机基团，X是可水解的基团，m为1,2或3，或其（部分）水解产物被施加和固化以形成具有优异的耐化学性和抗反射性的保护涂层。

17. 发明授权

US06699956B2 Highly dielectric addition type curable compositions 有权
标题翻译：高介电加成型可固化组合物
公开(公告)号：US06699956B2
公开(公告)日：2004-03-02
申请号：US10096590
申请日：2002-03-14
申请人： Muneo Kudo , Masaaki Yamaya
发明人： Muneo Kudo , Masaaki Yamaya
IPC分类号： C08G7708
CPC分类号： C08F8/42 , C08L83/08 , C08L83/00
摘要： A highly dielectric addition type curable composition is provided comprising (A) an organopolysiloxane containing a cyanoalkyl group and a monovalent hydrocarbon group having an aliphatic unsaturated bond, (B) an organohydrogenpolysiloxane containing a cyanoalkyl group, and (C) a platinum group metal catalyst. The composition is easy to handle because of liquid despite solvent-free, less hygroscopic and effectively curable, and has a film-forming ability. The cured composition has excellent dielectric properties as demonstrated by a large dielectric constant and a low dielectric loss.
摘要翻译：提供一种高介电性添加型固化性组合物，其包含（A）含有氰基烷基和具有脂肪族不饱和键的一价烃基的有机聚硅氧烷，（B）含有氰基烷基的有机氢聚硅氧烷，（C）铂族金属催化剂。该组合物尽管无溶剂，较少的吸湿性和有效固化性，但易于处理，且具有成膜性。固化的组合物具有优异的介电性能，如介电常数大和介电损耗低的证明。

18. 发明授权

US06335037B1 Cosmetic comprising spherical hydrophobic fine silica particles 有权
标题翻译：化妆品包括球形疏水性细二氧化硅颗粒
公开(公告)号：US06335037B1
公开(公告)日：2002-01-01
申请号：US09526063
申请日：2000-03-15
申请人： Shoji Ichinohe , Muneo Kudo , Akira Yamamoto
发明人： Shoji Ichinohe , Muneo Kudo , Akira Yamamoto
IPC分类号： A61K916
CPC分类号： A61Q15/00 , A61K8/025 , A61K8/25 , A61K9/167 , A61K2800/412 , A61K2800/612 , A61Q1/00 , A61Q1/02 , A61Q1/10 , A61Q19/10
摘要： A cosmetic containing spherical hydrophobic fine silica particles having an average particle diameter of from 0.01 to 5 &mgr;m, having been made more highly hydrophobic, is provided. The spherical hydrophobic fine silica particles have been made hydrophobic on their surfaces by introducing an R2SiO3/2 unit (wherein R2 represents a monovalent hydrocarbon group having 1 to 20 carbon atoms) to the surfaces of hydrophilic fine silica particles having an SiO2 unit, and further have been made more highly hydrophobic on their surfaces by introducing to the surfaces of the hydrophobic fine silica particles first treated an R13SiO1/2 unit (wherein R1's may be the same or different and each represent a monovalent hydrocarbon group having 1 to 6 carbon atoms). The cosmetic containing spherical hydrophobic fine silica particles is a product improved in spreadability and inunctionability.
摘要翻译：提供了具有更高疏水性的平均粒径为0.01〜5μm的球状疏水性二氧化硅微粒的化妆品。通过将R2SiO3 / 2单元（其中R2表示碳原子数1〜20的一价烃基）引入具有SiO 2单元的亲水性二氧化硅微粒的表面，使球形疏水性二氧化硅微粒表面疏水化，通过向首先处理的R 13 SiO 1/2单元（其中R 1可以相同或不同并且各自表示具有1至6个碳原子的一价烃基）的疏水性二氧化硅微粒的表面引入其表面而被制成更高疏水性，。含有球形疏水性二氧化硅微粒的化妆品是可扩展性和功能性提高的产品。

19. 发明授权

US6166163A Process for producing organosilicon resin and process for producing polyurethane foam by using the organosilicon resin obtained by that process 失效
标题翻译：生产有机硅树脂的方法和使用通过该方法获得的有机硅树脂生产聚氨酯泡沫的方法
公开(公告)号：US6166163A
公开(公告)日：2000-12-26
申请号：US593058
申请日：2000-06-13
申请人： Muneo Kudo , Shinichi Morioka , Mitsuo Asai
发明人： Muneo Kudo , Shinichi Morioka , Mitsuo Asai
IPC分类号： C08G18/00 , C08G77/06 , C08G77/08 , C08G101/00
CPC分类号： C08G77/10 , C08G77/06
摘要： A process for producing an organosilicon resin is disclosed. The process includes the steps of equilibrating a mixture of silane compounds of Si(OR.sup.3).sub.4 wherein R.sup.3 's are a monovalent hydrocarbon group having 1 to 6 carbon atoms; R.sup.2 Si(OR.sup.4).sub.3 wherein R.sup.2 is a monovalent hydrocarbon group having 1 to 20 carbon atoms, and R.sup.4 's are a monovalent hydrocarbon group having 1 to 6 carbon atoms; and R.sup.1.sub.3 SiX wherein X is an --OH group, an --OSiR.sup.1.sub.3 group or a hydrolyzable group, and R.sup.1 's are a monovalent hydrocarbon group having 1 to 6 carbon atoms; adding water to the product of the equilibration reaction to carry out hydrolysis reaction; and adding an aqueous alkali to the product of the hydrolysis reaction to carry out condensation reaction. The organosilicon resin obtained is well dispersible in a resin premix containing a polyol, a blowing agent, a catalyst and a foam stabilizer, and also is highly hydrophobic and low reactive. Hence, the resin premix containing the organosilicon resin has good storage stability. Accordingly, this resin premix need not be agitated when used and also can provide polyurethane foams having superior properties such as dimensional stability.
摘要翻译：公开了一种制备有机硅树脂的方法。该方法包括使Si（OR 3）4的硅烷化合物的混合物平衡的步骤，其中R 3是具有1至6个碳原子的一价烃基; R2Si（OR4）3，其中R2是具有1至20个碳原子的一价烃基，R4是具有1至6个碳原子的一价烃基; 和R 13 SiX，其中X为-OH基，-OSiR13基或可水解基，R 1为具有1至6个碳原子的一价烃基; 向平衡反应产物中加入水进行水解反应; 并向水解反应产物中加入碱水溶液进行缩合反应。获得的有机硅氧烷树脂可以良好地分散在含有多元醇，发泡剂，催化剂和泡沫稳定剂的树脂预混物中，并且还具有高疏水性和低反应性。因此，含有有机硅树脂的树脂预混物具有良好的储存稳定性。因此，该树脂预混物在使用时不需要搅拌，也可以提供具有优异性能如尺寸稳定性的聚氨酯泡沫。

20. 发明授权

US5840952A Method of manufacturing 3-mercaptopropylalkoxy silane 失效
标题翻译：制备3-巯基丙基烷氧基硅烷的方法
公开(公告)号：US5840952A
公开(公告)日：1998-11-24
申请号：US741684
申请日：1996-10-31
申请人： Muneo Kudo , Hideyoshi Yanagisawa , Shoji Ichinohe , Akira Yamamoto , Satoru Beppu , Hiroyuki Iwaki , Satoshi Sekizawa
发明人： Muneo Kudo , Hideyoshi Yanagisawa , Shoji Ichinohe , Akira Yamamoto , Satoru Beppu , Hiroyuki Iwaki , Satoshi Sekizawa
IPC分类号： C07F7/18 , C07F7/08
CPC分类号： C07F7/1892
摘要： After reacting sodium sulfide anhydride and hydrogen sulfide, 3-halopropylalkoxy silane represented by the general formula X (CH.sub.2).sub.3 Si (OR).sub.a R.sub.3-a (I) is added reacted, wherein X denotes Cl or Br; R denotes a methyl, ethyl or propyl group wherein R's can be all identical or different from each other; and "a" denotes an integer 1, 2 or 3.
摘要翻译：在使硫化钠酐和硫化氢反应后，加入由通式X（CH 2）3 Si（OR）aR 3-a（I）表示的3-卤代丙基烷氧基硅烷反应，其中X表示Cl或Br; R表示甲基，乙基或丙基，其中R可以彼此相同或不同; “a”表示整数1,2或3。

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