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    • 12. 发明授权
    • Photoresponsive polymer, built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them
    • 光响应聚合物,聚合型乙炔聚合物,羧酸铵的结晶及其制造方法
    • US07981968B2
    • 2011-07-19
    • US12382527
    • 2009-03-18
    • Akikazu MatsumotoToru Odani
    • Akikazu MatsumotoToru Odani
    • C08F8/30C08F20/00C07C69/74C07C63/04
    • C08G61/08C08G73/00
    • A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained.
    • 在不存在液体介质的情况下,将羧酸晶体和至少一种选自胺和氨的化合物混合。 羧酸是共轭二烯,如(Z,Z) - 木聚糖酸,共轭二烯包括羧基。 所述至少一种选自胺和氨的含氮化合物是由RCH 2 NH 2表示的伯胺,其中R是芳基,或是含有5个或更多个碳原子的正烷基。 此外,作为二价基团的由Ar和Ar'独立地为芳香族烃二价基团的-Ar-N = N-Ar'表示的胺插入聚合物如多粘多糖酸的层状结晶中 包括羧基的层状晶体。 以这种方式获得新的光响应聚合物。
    • 13. 发明申请
    • Photoresponsive polymer,built-up type diacetylene polymer, crystal of ammonium carboxylate, and method of manufacturing them
    • 光响应聚合物,积聚型乙炔聚合物,铵晶体
    • US20090253870A1
    • 2009-10-08
    • US12382527
    • 2009-03-18
    • Akikazu MatsumotoToru Odani
    • Akikazu MatsumotoToru Odani
    • C08F265/02
    • C08G61/08C08G73/00
    • A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained.Also obtained is a crystal of ammonium carboxylate including at least one kind of carboxyl acid and at least one kind of amine, at least one kind of compound selected from (i) the at least one kind of carboxyl acid and (ii) the at least one kind of amine being a diacetylene derivative. The crystal of ammonium carboxylate is subjected to light or heat, to obtain a built-up type diacetylene polymer.
    • 在不存在液体介质的情况下,将羧酸晶体和至少一种选自胺和氨的化合物混合。 羧酸是共轭二烯,如(Z,Z) - 木聚糖酸,共轭二烯包括羧基。 所述至少一种选自胺和氨的含氮化合物是由RCH 2 NH 2表示的伯胺,其中R是芳基,或是含有5个或更多个碳原子的正烷基。 此外,作为二价基团的由Ar和Ar'独立地为芳香族烃二价基团的-Ar-NN-Ar'-表示的胺插入聚合物如多粘多糖酸的层状结晶中, 包括羧基的层状晶体。 以这种方式获得新的光响应聚合物。 还得到了包含至少一种羧酸和至少一种胺的至少一种羧酸铵的结晶,至少一种选自(i)至少一种羧酸的化合物和(ii)至少一种 一种胺为二乙炔衍生物。 将羧酸铵的结晶经受光或热,得到积聚型的乙炔聚合物。
    • 16. 发明授权
    • Methods of producing resin moldings
    • 生产树脂模制品的方法
    • US06274070B1
    • 2001-08-14
    • US09589068
    • 2000-06-08
    • Tsuyoshi TanigakiShogo IzawaAkikazu MatsumotoTadahiko Kohama
    • Tsuyoshi TanigakiShogo IzawaAkikazu MatsumotoTadahiko Kohama
    • B29C4516
    • B29C45/0013B29C45/16B29C70/882B29C2045/169H01H1/029H01H2011/0081H05K2201/0215H05K2201/09118H05K2203/0113
    • Provided are a conductive resin composition having little negative impact on the environment, a resin molding which includes conductive parts of the conductive resin composition and insulating parts, and their methods of production. The production costs for the resin molding are low. The conductive resin composition is formed by kneading a thermoplastic or thermosetting resin with a low melting point alloy, wherein the low melting point alloy is moldable with the resin and consists essentially of tin and is free of lead. An insulating body is formed through primary molding of a thermoplastic or thermosetting resin, and is integrated with conductive parts of the conductive resin composition through secondary molding; or alternatively, conductive parts are formed through primary molding of the conductive resin composition and an insulating body is formed while being integrated with the conductive parts through secondary molding.
    • 提供对环境几乎没有负面影响的导电树脂组合物,包括导电树脂组合物的导电部分和绝缘部分的树脂模制品及其制备方法。 树脂成型的生产成本低。 导电树脂组合物通过将热塑性或热固性树脂与低熔点合金捏合而形成,其中低熔点合金可与树脂成型并且基本上由锡组成并且不含铅。 通过热塑性或热固性树脂的初级成型形成绝缘体,并通过二次成型与导电性树脂组合物的导电性部分一体化; 或者,通过导电树脂组合物的一次成型形成导电部件,并且通过二次成型与导电部件一体形成绝缘体。
    • 19. 发明授权
    • Photoresponsive polymer, built-up type diacetylene polymer, crystal of ammonium carboxylate, and method for manufacturing them
    • 光响应聚合物,聚合型乙炔聚合物,羧酸铵的结晶及其制造方法
    • US07750084B2
    • 2010-07-06
    • US10487849
    • 2002-08-26
    • Akikazu MatsumotoToru Odani
    • Akikazu MatsumotoToru Odani
    • C08F8/30C08F20/00C07C69/74C07C63/04
    • C08G61/08C08G73/00
    • A crystal of carboxyl acid and at least one compound selected from the group consisting of amine and ammonia are mixed in an absence of a liquid medium. The carboxyl acid is conjugated diene such as (Z,Z)-muconic acid, the conjugated diene including a carboxyl group. The at least one nitrogen-containing compound selected from the group consisting of amine and ammonia is primary amine represented by RCH2NH2, where R is an aryl group, or is a normal alkyl group that contains five or more carbon atoms. Moreover, such amine that is a bivalent group and that is represented by —Ar—N═N—Ar′—, where Ar and Ar′ are independently aromatic hydrocarbon bivalent groups, is intercalated in a layered crystal of a polymer such as polymuconic acid, the layered crystal including a carboxyl group. In this way, a novel photoresponsive polymer is obtained. Also obtained is a crystal of ammonium carboxylate including at least one kind of carboxyl acid and at least one kind of amine, at least one kind of compound selected from (i) the at least one kind of carboxyl acid and (ii) the at least one kind of amine being a diacetylene derivative. The crystal of ammonium carboxylate is subjected to light or heat, to obtain a built-up type diacetylene polymer.
    • 在不存在液体介质的情况下,将羧酸晶体和至少一种选自胺和氨的化合物混合。 羧酸是共轭二烯,如(Z,Z) - 木聚糖酸,共轭二烯包括羧基。 所述至少一种选自胺和氨的含氮化合物是由RCH 2 NH 2表示的伯胺,其中R是芳基,或是含有5个或更多个碳原子的正烷基。 此外,作为二价基团的由Ar和Ar'独立地为芳香族烃二价基团的-Ar-N = N-Ar'表示的胺插入聚合物如多粘多糖酸的层状结晶中 包括羧基的层状晶体。 以这种方式获得新的光响应聚合物。 还得到了包含至少一种羧酸和至少一种胺的至少一种羧酸铵的结晶,至少一种选自(i)至少一种羧酸的化合物和(ii)至少一种 一种胺是二乙炔衍生物。 将羧酸铵的结晶经受光或热,得到积聚型的乙炔聚合物。