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11. 发明授权

US06900264B2 Compositions comprising rigid-rod polymers and carbon nanotubes and process for making the same 失效
标题翻译：包含刚性棒聚合物和碳纳米管的组合物及其制备方法
公开(公告)号：US06900264B2
公开(公告)日：2005-05-31
申请号：US10228483
申请日：2002-08-27
申请人： Satish Kumar , Fred E. Arnold , Thuy D. Dang
发明人： Satish Kumar , Fred E. Arnold , Thuy D. Dang
IPC分类号： C01B31/02 , A61K9/70 , C08F14/12 , C08F14/28 , C08K7/06 , C08K7/24 , C08L79/04 , C08L101/00 , D01F1/10 , D01F6/74 , D01F6/94 , F41H5/04 , C08K3/34
CPC分类号： B82Y30/00 , A61K9/70 , C08F14/12 , C08F14/28 , C08K3/041 , C08L79/04 , D01F1/10 , D01F6/74 , F41H5/0471 , F41H5/0478 , Y10S977/753
摘要： The present invention relates to compositions comprising rigid-rod polymers and carbon nanotubes. The compositions comprise dispersed carbon nanotubes aligned with rigid-rod polymers. The alignment of the nanotubes and polymers can be liquid crystalline. The rigid-rod polymers of this invention include, but are not limited to, polymers and copolymers comprising benzobisazole, pyridobisimidazole and benzamidazobenzo-phenanthroline repeat units. Dispersion of carbon nanotubes is achieved by in-situ polymerization in the presence of the carbon nanotubes, which may be either single-wall or multi-wall or a combination of both. The polymer compositions comprising carbon nanotubes may be spun into fibers or formed into films. The strength of the resulting fibers of the present invention is significantly greater than that of fibers without carbon nanotubes.
摘要翻译：本发明涉及包含刚性棒聚合物和碳纳米管的组合物。组合物包含与刚性棒聚合物对准的分散的碳纳米管。纳米管和聚合物的排列可以是液晶的。本发明的刚性棒状聚合物包括但不限于包含苯并二唑，吡啶并二咪唑和苯并咪唑并菲 - 菲咯啉重复单元的聚合物和共聚物。碳纳米管的分散是通过在碳纳米管存在下的原位聚合实现的，其可以是单壁或多壁或两者的组合。包含碳纳米管的聚合物组合物可以纺成纤维或形成薄膜。本发明所得纤维的强度明显大于不含碳纳米管的纤维的强度。

12. 发明授权

US06437081B1 Oxyallyl pendent benzazole polymeric materials 失效
标题翻译：苯甲酰基苯并唑聚合物
公开(公告)号：US06437081B1
公开(公告)日：2002-08-20
申请号：US09777384
申请日：2001-02-13
申请人： Fred E. Arnold , Thuy D. Dang , Robert J. Spry , Max D. Alexander
发明人： Fred E. Arnold , Thuy D. Dang , Robert J. Spry , Max D. Alexander
IPC分类号： C08G7322
CPC分类号： C08G73/18 , C08G73/22
摘要： Oxyallyl pendent polymer system having repeating units of the formulae hereinafter referred to as structure A, wherein x has a value of about 0.1 to 1.0 and y has a value of 1.0-x, and hereinafter referred to as structure B, wherein the sum of p+q has a value of about 0.1 to 1.0, r has a value of 1.0-(p+q) and the molar ratio of p:q is about 9:1 to 1:9, wherein Bz is a benzazole unit selected from the group consisting of wherein X is —O—, —S— or —NH—, and R is selected from the group consisting of and wherein Ar is an aromatic group.
摘要翻译：具有以下称为结构A的重复单元的甲亚烷基侧链聚合物体系，其中x具有约0.1至1.0的值，y具有1.0-x的值，以下称为结构B，其中p + q的和具有约0.1至1.0的值，r具有1.0-（p + q）的值，并且p:q的摩尔比为约9:1至1:9，其中Bz是选自以下的苯并唑单元：其中X是-O - ， - S-或-NH-，R选自并且其中Ar是芳族基团。

13. 发明授权

US5508376A Alcohol soluble rigid-rod benzobisazole polymers 失效
标题翻译：醇溶性刚性棒苯并二唑聚合物
公开(公告)号：US5508376A
公开(公告)日：1996-04-16
申请号：US393589
申请日：1995-02-21
申请人： Thuy D. Dang , Jom P. Chen , Fred E. Arnold
发明人： Thuy D. Dang , Jom P. Chen , Fred E. Arnold
IPC分类号： C08G73/22 , C08G75/32
CPC分类号： C08G75/32 , C08G73/22
摘要： Alcohol-soluble aromatic heterocyclic polymers and copolymers having repeating units of the formulae I or II: ##STR1## wherein Q is a benzobisazole of the formula: ##STR2## wherein X is --O-- or --S--; wherein x has a value of 0.0 to 1.00 and y has a value of 0.05 to 1.00, and R is selected from the group consisting of: ##STR3## and R' is selected from the group consisting of alkyl having 1 to 5 carbon atoms, alkaryl having 7 to 12 carbon atoms, aralkyl having 7 to 12 carbon atoms and substituted aromatic having 1 to 3 substituent groups. The alcohol-soluble polymers and copolymers may be used for fabricating organic/inorganic hybrid composites with metal alkoxides M(OZ).sub.v, wherein M is Si, Ti, Al or the like and Z is a lower alkyl group. These polymers and copolymers can also be used to coat materials or substrates which are susceptible to attack by highly corrosive acids. On drying, the ionic bond between the trialkylamine and the sulfo group is broken and the (co)polymer reverts to the parent structure, thereby leaving a (co)polymer coating. Yet further, the original amine can be exchanged with a less volatile amine or an amine having a desired functionality. After removal of the solvent, the resulting material is mono-dispersed and stable.
摘要翻译：具有式I或II的重复单元的醇可溶性芳族杂环聚合物和共聚物：其中Q是下式的苯并二唑：其值为0.0至1.00，y具有值为0.05〜1.00，R为选自由以下组成的组：R 1选自碳原子数1〜5的烷基，碳原子数7〜12的烷芳基，碳原子数为7的芳烷基至12个碳原子和具有1至3个取代基的取代芳族。醇溶性聚合物和共聚物可用于制备与金属醇盐M（OZ）v的有机/无机混合复合材料，其中M为Si，Ti，Al等，Z为低级烷基。这些聚合物和共聚物也可用于涂覆易受高腐蚀性酸侵蚀的材料或基材。在干燥时，三烷基胺和磺基之间的离子键断裂，（共）聚合物回到母体结构，从而留下（共）聚合物涂层。此外，原始胺可以与挥发较少的胺或具有所需官能度的胺交换。除去溶剂后，所得物质是单分散的并且稳定。

14. 发明授权

US5312895A Benzobisazole copolymer system soluble in aprotic solvents 失效
标题翻译：苯并二唑共聚物体系可溶于非质子溶剂
公开(公告)号：US5312895A
公开(公告)日：1994-05-17
申请号：US30527
申请日：1993-03-12
申请人： Thuy D. Dang , Fred E. Arnold
发明人： Thuy D. Dang , Fred E. Arnold
IPC分类号： C08G73/18 , C08G73/22 , C08G75/32
CPC分类号： C08G73/18 , C08G73/22 , C08G75/32
摘要： Para-ordered aromatic heterocyclic polymers having repeating units of the formula: ##STR1## wherein n has a value of 0.05 to 1.00 and Q is a benzobisazole of the formula ##STR2## wherein X is --S-- or --O--, are soluble in aprotic solvents.
摘要翻译：具有下式重复单元的对位芳族杂环聚合物：其中n具有0.05至1.00的值，Q是式为“IMAGE”的苯并二唑，其中X为-S-或-O-，可溶于非质子溶剂。

15. 发明授权

US06362313B1 Allyl pendent homo- and co-polymeric systems 失效
标题翻译：烯丙基悬挂均聚和共聚体系
公开(公告)号：US06362313B1
公开(公告)日：2002-03-26
申请号：US09780705
申请日：2001-02-13
申请人： Fred E. Arnold , Thuy D. Dang
发明人： Fred E. Arnold , Thuy D. Dang
IPC分类号： C08G7356
CPC分类号： C08G61/12 , C08G61/124 , C08G73/18 , C08G73/22
摘要： Allyl pendent benzazole polymer system having repeating units of the formula: wherein Bz is a benzazole unit selected from the group consisting of wherein X is —O—, —S— or —NH—, and R is selected from the group consisting of wherein Ar is an aromatic group; and wherein x has a value of about 1.0 to 0.1 and y has a value of 1.0−x.
摘要翻译：具有下式重复单元的烯丙基侧链苯并唑体系：其中Bz是选自由X所组成的组中的苯并唑单元，其中R是-O - ， - S-或-NH-，R选自Ar在芳香族; 并且其中x具有约1.0至0.1的值，y具有1.0-x的值。

16. 发明授权

US6057417A High temperature polymers with low dielectric properties 失效
标题翻译：具有低介电性能的高温聚合物
公开(公告)号：US6057417A
公开(公告)日：2000-05-02
申请号：US321447
申请日：1999-05-27
申请人： Fred E. Arnold , Thuy D. Dang , Robert J. Spry , Max D. Alexander , Patrick T. Mather
发明人： Fred E. Arnold , Thuy D. Dang , Robert J. Spry , Max D. Alexander , Patrick T. Mather
IPC分类号： C08G73/22 , C08G63/02
CPC分类号： C08G73/22
摘要： A polymer system having repeating units of the formula: ##STR1## wherein A is --H or --OH, x has a value of 0.5 to 1.0 and y has a value of 1.0-x, exhibits a high glass transition temperature (T.sub.g) and a low dielectric constant. The polymer system is useful in the area of microelectronic packaging.
摘要翻译：具有下式重复单元的聚合物体系：其中A是-H或-OH，x具有0.5至1.0的值，y具有1.0-x的值，显示出高玻璃化转变温度（Tg）和低电介质不变。聚合物体系在微电子封装领域是有用的。

17. 发明授权

US6025439A Processing of thermoplastic rigid-rod molecular composites 失效
标题翻译：热塑性刚性棒分子复合材料的加工
公开(公告)号：US6025439A
公开(公告)日：2000-02-15
申请号：US126571
申请日：1998-07-30
申请人： Fred E. Arnold , Narayanan Venkatasubramanian , Thuy D. Dang , Derrick R. Dean
发明人： Fred E. Arnold , Narayanan Venkatasubramanian , Thuy D. Dang , Derrick R. Dean
IPC分类号： C08G73/22 , C08G75/32 , C08L79/04 , C08G73/18 , C08L79/06
CPC分类号： C08G75/32 , C08G73/22 , C08L79/04
摘要： Molecular dispersions of rigid-rod polybenzobisazole polymer/copolymer in thermoplastic matrices in a weight ratio of about 1:99 to 50:50 are prepared by dissolving the rigid-rod polymer in an alcoholic or aprotic solvent, dissolving the thermoplastic polymer in an alcoholic or aprotic solvent, combining the two solutions and recovering the resulting molecular composite from the combined solution. These molecular dispersions consist essentially of rigid-rod polybenzobisazole polymer/copolymer having sulfonic acid groups pendant to the polymer/copolymer backbone and thermoplastic polymers selected from the group consisting of polyvinylpyridines, poly(arylene ether ketone)s with a pyridyl functionality, aromatic poly(pyridine ether)s and poly(pyridine ether sulfone) copolymers, and polyimides with a pyridyl functionality.
摘要翻译：通过将刚性棒状聚合物溶解在醇或非质子溶剂中，将热塑性聚合物溶解在酒精或酒精中，制备刚性棒状聚苯并双酚聚合物/共聚物在热塑性基质中的重量比约1:99至50:50的分散体非质子溶剂，结合两种溶液并从组合溶液中回收得到的分子复合物。这些分子分散体基本上由具有垂直于聚合物/共聚物主链的磺酸基的刚性棒聚苯并双酚聚合物/共聚物和选自聚乙烯吡啶，具有吡啶基官能团的聚（亚芳基醚酮），芳族聚（吡啶醚）和聚（吡啶醚砜）共聚物和具有吡啶基官能团的聚酰亚胺。

18. 发明授权

US5136012A Dihydroxy-pendant rigid-rod benzobisazole copolymer 失效
标题翻译：二羟基 - 侧链刚性棒苯并二唑共聚物
公开(公告)号：US5136012A
公开(公告)日：1992-08-04
申请号：US709252
申请日：1991-06-03
申请人： Thuy D. Dang , Hoe H. Chuah , Loon S. Tan , Fred E. Arnold
发明人： Thuy D. Dang , Hoe H. Chuah , Loon S. Tan , Fred E. Arnold
IPC分类号： C08G73/18 , C08G73/22 , C08G75/32
CPC分类号： C08G75/32 , C08G73/18 , C08G73/22
摘要： There are provided novel rod-like heterocyclic aromatic copolymers having peating groups of the formula: ##STR1## wherein n has a value of 0.01 to 0.50, wherein Ar is a para-oriented aromatic group and Q is an aromatic heterocyclic group of the formula: ##STR2## wherein Y is --S--, --O-- or --NR--, wherein R is selected from the group consisting of --H, alkyl having 1 to 4 carbon atoms, and aromatic having 1 or 2 aromatic rings.
摘要翻译：提供了具有下式重复基团的新型棒状杂环芳族共聚物：其中n为0.01至0.50，其中Ar为对位取向芳族基团，Q为下式芳族杂环基：其中Y是-S-，-O-或-NR-，其中R选自-H，具有1至4个碳原子的烷基和具有1或2个芳环的芳族。

19. 发明授权

US5106940A Dihydroxy-pendant rigid-rod benzobisazole polymer 失效
标题翻译：二羟基 - 侧链刚性棒苯并双酚聚合物
公开(公告)号：US5106940A
公开(公告)日：1992-04-21
申请号：US709250
申请日：1991-06-03
申请人： Thuy D. Dang , Hoe H. Chuah , Loon S. Tan , Fred E. Arnold
发明人： Thuy D. Dang , Hoe H. Chuah , Loon S. Tan , Fred E. Arnold
IPC分类号： C08G75/18 , C08G75/22 , C08G75/32 , H05K3/10
CPC分类号： C08G75/22 , C08G75/18 , C08G75/32 , H05K3/105
摘要： There are provided novel rod-like heterocyclic aromatic polymers having repeating groups of the formula: ##STR1## wherein Y is --S--, --O-- or --NR--, R is -H, an alkyl group having 1 to 4 carbon atoms or an aromatic group having 1 or 2 aromatic rings, and the bullet symbol (.cndot.) indicates hydrogen bonding.
摘要翻译：提供了具有下式重复基团的新型棒状杂环芳族聚合物：其中Y是-S-，-O-或-NR-，R是-H，烷基具有1〜 4个碳原子或具有1或2个芳香环的芳族基团，并且子符号（。）表示氢键。

20. 发明授权

US5039778A Dihydroxy-pendant rigid-rod benzobisazole copolymer 失效
标题翻译：二羟基 - 侧链刚性棒苯并二唑共聚物
公开(公告)号：US5039778A
公开(公告)日：1991-08-13
申请号：US498256
申请日：1990-03-23
申请人： Thuy D. Dang , Hoe H. Chuah , Loon S. Tan , Fred E. Arnold
发明人： Thuy D. Dang , Hoe H. Chuah , Loon S. Tan , Fred E. Arnold
IPC分类号： C08G73/18 , C08G73/22 , C08G75/32
CPC分类号： C08G75/32 , C08G73/18 , C08G73/22
摘要： There are provided novel rod-like heterocyclic aromatic copolymers having repeating groups of the formula: ##STR1## wherein n has a value of 0.01 to 0.50, wherein Ar is a para-oriented aromatic group and Q is an aromatic heterocyclic group of the formula: ##STR2## wherein Y is --S--, --O-- or --NR--, wherein R is selected from the group consisting of --H, alkyl having 1 to 4 carbon atoms, and aromatic having 1 or 2 aromatic rings.
摘要翻译：提供了具有下式重复基团的新型棒状杂环芳族共聚物：其中n为0.01至0.50，其中Ar为对位取向芳族基团，Q为下式芳族杂环基：其中Y是-S-，-O-或-NR-，其中R选自-H，具有1至4个碳原子的烷基和具有1或2个芳环的芳族。

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