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    • 15. 发明申请
    • Method and structure for desulfurizing gasoline or diesel fuel for use in a fuel cell power plant
    • 用于燃料电池发电厂的用于脱硫汽油或柴油的方法和结构
    • US20060213813A1
    • 2006-09-28
    • US11302106
    • 2005-12-13
    • He HuangZissis DardasRoger Lesieur
    • He HuangZissis DardasRoger Lesieur
    • C10G45/00C10G17/00
    • B01J20/28045B01J19/2485B01J19/249B01J19/2495B01J20/02B01J20/06B01J20/08B01J20/103B01J20/28014B01J20/28016B01J20/28042B01J20/28057B01J20/28059B01J20/28097B01J20/3042B01J20/3204B01J20/3236B01J20/3289B01J20/3293B01J23/755B01J35/04B01J37/0215B01J2208/00132B01J2208/0015B01J2219/00081B01J2219/00085B01J2219/2453B01J2219/2458B01J2219/2459B01J2219/2479B01J2219/2485B01J2220/42C10G25/003C10G29/04H01M8/0675
    • A sulfur scrubbing method and structure is operable to remove substantially all of the sulfur present in an undiluted oxygenated hydrocarbon fuel stock supply which can be used to power an internal combustion engine or a fuel cell power plant in a mobile environment, such as an automobile, bus, truck, boat, or the like, or in a stationary environment. The fuel stock can be gasoline, diesel fuel, or other like fuels which contain relatively high levels of organic sulfur compounds such as mercaptans, sulfides, disulfides, thiophenes, and the like. The undiluted hydrocarbon fuel supply is passed through a desulfurizer bed which is provided with a high surface area nickel reactant, and wherein essentially all of the nickel reactant in the scrubber bed reacts with sulfur in the fuel stream, so as to remove sulfur from the fuel stream by converting it to nickel sulfide on the scrubber bed. The desulfurized organic remnants of the fuel stream continue through the remainder of the fuel processing system in the fuel cell power plant, or through the internal combustion engine. The desulfurizer bed is preferably formed from a high surface area ceramic foam monolith, the pores of which are coated with the high surface area nickel reactant. The use of the foam monolith combined with the high surface area of the reactant, enables essentially 100% of the nickel reactant to come into contact with the fuel stream being desulfurized. The scrubber bed can also be formed from high surface area nickel coated alumina pellets, from a high surface area nickel coated ceramic extrusion, from high surface area nickel pellets, and from high surface area nickel extrudates.
    • 硫洗涤方法和结构可操作以基本上除去未稀释的含氧烃燃料原料供应中存在的硫,其可用于为移动环境(例如汽车)中的内燃机或燃料电池发电厂供电, 公共汽车,卡车,船等,或在静止的环境中。 燃料原料可以是汽油,柴油燃料或含有比较高含量的有机硫化合物如硫醇,硫化物,二硫化物,噻吩等的类似燃料。 未稀释的碳氢化合物燃料供应通过脱硫器床,该脱硫器床设置有高表面积的镍反应物,并且其中洗涤床中的基本上所有的镍反应物与燃料流中的硫反应,以便从燃料中除去硫 将其转化为洗涤床上的硫化镍。 燃料流的脱硫有机残余物继续通过燃料电池发电厂的燃料处理系统的其余部分,或通过内燃机。 脱硫剂床优选由高表面积的陶瓷泡沫整体形成,其孔被高表面积的镍反应物涂覆。 使用与反应物的高表面积结合的泡沫整体使基本上100%的镍反应物与正在脱硫的燃料流接触。 洗涤床还可以由高表面积镍涂层氧化铝颗粒,高表面积镍涂层陶瓷挤出物,高表面积镍颗粒和高表面积镍挤出物形成。
    • 16. 发明申请
    • Structure for desulfurizing gasoline or diesel fuel for use in a fuel cell power plant
    • 用于燃料电池发电厂的用于脱硫汽油或柴油的结构
    • US20050031506A1
    • 2005-02-10
    • US10635269
    • 2003-08-07
    • He HuangZissis DardasJoseph Sangiovanni
    • He HuangZissis DardasJoseph Sangiovanni
    • B01D20060101B01J8/04B01J19/24C10G11/18
    • B01J19/2495B01J2219/00081C10G11/18
    • A sulfur scrubber structure is operable to remove substantially all of the sulfur present in an undiluted oxygenated hydrocarbon fuel stock supply for a fuel cell power plant assembly which is used to power an engine in a mobile environment, such as an automobile, bus, truck, boat, or the like, or in a stationary environment. The fuel stock can be gasoline, diesel fuel, or other like fuels which contain relatively high levels of organic sulfur compounds such as mercaptans, sulfides, disulfides, and the like. The undiluted hydrocarbon fuel supply is passed through a nickel reactant desulfurizer bed (2) wherein essentially all of the nickel reactant in the scrubber bed reacts with sulfur in the fuel stream, whereby the nickel reactant is converted to nickel sulfide, while the desulfurized organic remnants of the fuel stream continue through the remainder of the fuel processing system. The desulfurizer bed can be formed from a highly porous ceramic or metallic foam monolith, the pores (6) of which are coated with a nickel reactant. The foam monolith can be formed from elemental nickel per se. The use of the high surface area porous foam monolith enables essentially 100% of the nickel reactant to come into contact with the fuel stream being desulfurized.
    • 硫洗涤器结构可操作以去除用于燃料电池组件的未稀释的含氧烃燃料原料供应中基本上所有的硫,其用于为诸如汽车,公共汽车,卡车的移动环境中的发动机供电, 船等,或在静止的环境中。 燃料原料可以是含有比较高含量的有机硫化合物如硫醇,硫化物,二硫化物等的汽油,柴油燃料或其他类似的燃料。 未稀释的碳氢燃料供应通过镍反应物脱硫器床(2),其中洗涤床中基本上所有的镍反应物与燃料流中的硫反应,由此将镍反应物转化为硫化镍,而脱硫的有机残余物 的燃料流继续通过燃料处理系统的其余部分。 脱硫器床可以由高度多孔的陶瓷或金属泡沫整体形成,孔(6)涂覆有镍反应物。 泡沫整体可以由元素镍本身形成。 使用高表面积的多孔泡沫整体体使得基本上100%的镍反应物与正在脱硫的燃料流接触。