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    • 13. 发明授权
    • Method of forming dye image having superior rapid processing performance
    • US4839263A
    • 1989-06-13
    • US79220
    • 1987-07-29
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • G03C1/035G03C1/30G03C7/30G03C7/392G03C7/407
    • G03C7/3924G03C1/305Y10S430/164
    • A silver halide photographic material containing a support and, provided thereon, at least one silver halide emulsion layer, this silver halide emulsion layer containing silver halide grains containing 90 mol % or more of silver chloride, a dye-forming coupler, and a compound represented by general formula [S]; ##STR1## wherein Q is a group of atoms necessary to complete a 5- or 6-membered heterocyclic ring or a 5- or 6-membered ring fused with a benzene ring and M is a hydrogen atom, an alkali metal or an ammonium group;the silver halide layer having been hardened by a hardener represented by formula [HDA] or [HDB]; ##STR2## wherein Rd.sub.1 is selected from the group consisting of a chlorine atom, a hydroxyl group, an alkyl group, an alkoxy group, an alkylthio group, an --OM group, wherein M is an mono-valent metal atom, a --NR'R" group, wherein R' and R" are independently selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group and a --NHCOR'" group, in which R'" is selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group; Rd.sub.2 is selected from the group consisting of a hydroxyl group, an alkyl group, an alkoxy group, an alkylthio group, an --OM group, wherein M is an mono-valent metal atom, a --NR'R" group, wherein R' and R" are independently selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group and a --NHCOR'" group, in which R'" is selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group; ##STR3## wherein Rd.sub.3 and Rd.sub.4 are independently selected from the group consisting of a chlorine atom, a hydroxyl group, an alkyl group, an alkoxy group and an --OM group, in which is a mono-valent metal atom; Q and Q' is a divalent atom or group selected from --O--, --S-- and --NH--; L is an alkylene group or an arylene group; and p and q are independently integers of 0 or 1. The above-described silver halide photographic material is processed with a color developing solution containing a sulfite ion in a quantity of 2.times.10.sup.-4 to 1.times.10.sup.-2 moles per liter, this developing solution being substantially free of bromide ion. The above-described material and process for developing the same, being better suited for use in rapid developing processes.
    • 20. 发明授权
    • Developing inhibitor arrangment in light-sensitive silver halide color
photographic materials
    • 在感光卤化银彩色照相材料中开发抑制剂排列
    • US4725529A
    • 1988-02-16
    • US854141
    • 1986-04-21
    • Hiroshi ShimazakiEiichi SakamotoSatoshi NakagawaHiroshi InoieMinoru Ishikawa
    • Hiroshi ShimazakiEiichi SakamotoSatoshi NakagawaHiroshi InoieMinoru Ishikawa
    • G03C7/26G03C7/20G03C7/305G03C7/32G03C1/46
    • G03C7/30594Y10S430/158
    • There is disclosed a light-sensitive silver halide photographic material, having two or more light-sensitive silver halide emulsion layers different in color sensitivities on a support, at least two of the light-sensitive silver halide emulsion layers different in color sensitivities containing a DIR compound capable of releasing a developing inhibitor or developing inhibitor precursor through the reaction with the oxidized product of a developing agent, the developing inhibitor or developing inhibitor precursor released from the DIR compound being diffusive, wherein the following conditions A:DIR compounds are added and incorporated in the emulsion layers so that the developing inhibitor released from the DIR compound incorporated in one color-sensitive silver halide emulsion layer and the developing inhibitor released from the DIR compound incorporated in the other color-sensitive silver halide emulsion layer are reversed in developing inhibiting power when the DIR compounds to be incorporated in the respective light-sensitive silver halide emulsion layers are exchanged with each other, and also each DIR compound may have greater inhibiting power for the other light-sensitive silver halide emulsion layer rather than for the light-sensitive silver halide emulsion layer in which it is incorporated,is satisfied for the at least two light-sensitive silver halide emulsion layers different in color sensitivities.
    • 公开了一种感光卤化银照相材料,其具有在支持体上具有不同颜色敏感度的两种或更多种感光卤化银乳剂层,至少两种不同颜色敏感度的感光卤化银乳剂层含有DIR 能够通过与显影剂的氧化产物的反应释放显影抑制剂或显影抑制剂前体的化合物,从DIR化合物释放的显影抑制剂或显影抑制剂前体被扩散,其中以下条件A:加入DIR化合物并加入 在乳液层中,从引入到一个感光卤化银乳剂层中的DIR化合物释放的显影抑制剂和从另一个感光卤化银乳剂层中掺入的DIR化合物释放的显影抑制剂在显影抑制力方面相反 当DIR化合物成为我时 组合在相应的感光卤化银乳剂层中的每一个都可以相互交换,并且每个DIR化合物对于其它感光卤化银乳剂层而言可能具有更大的抑制力,而不是对于感光卤化银乳剂层,其中 对于不同于颜色敏感度的至少两种感光卤化银乳剂层而言,它是被合并的。