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11. 发明申请

US20050227852A1 Method for improving crystalline titanosilicate catalyst having mww structure 失效
标题翻译：改善具有mww结构的结晶钛硅酸盐催化剂的方法
公开(公告)号：US20050227852A1
公开(公告)日：2005-10-13
申请号：US10506645
申请日：2003-02-28
申请人： Hiroaki Abekawa , Masaru Ishino
发明人： Hiroaki Abekawa , Masaru Ishino
IPC分类号： B01J29/89 , B01J31/02 , B01J29/04
CPC分类号： C07D301/12 , B01J29/89 , B01J31/0272 , B01J2229/32
摘要： A method for improving a crystalline titanosilicate catalyst having an MWW structure, characterized in that it comprises treating the crystalline titanosilicate catalyst having a MWW structure with a silylating agent.
摘要翻译：一种改进具有MWW结构的结晶钛硅酸盐催化剂的方法，其特征在于其包括用甲硅烷基化剂处理具有MWW结构的结晶钛硅酸盐催化剂。

12. 发明授权

US5871707A Process for producing chlorine 失效
标题翻译：生产氯的方法
公开(公告)号：US5871707A
公开(公告)日：1999-02-16
申请号：US648976
申请日：1996-05-17
申请人： Takuo Hibi , Hiroshi Nishida , Hiroaki Abekawa
发明人： Takuo Hibi , Hiroshi Nishida , Hiroaki Abekawa
IPC分类号： B01J21/06 , B01J23/46 , B01J37/03 , C01B7/04
CPC分类号： C01B7/04 , B01J23/462 , B01J21/063 , B01J21/066 , B01J37/03
摘要： The present invention provides a process for producing chlorine by oxidation of hydrogen chloride with oxygen which process comprises using a ruthenium catalyst.
摘要翻译：本发明提供了一种通过用氧化氯化氢生产氯的方法，该方法包括使用钌催化剂。

13. 发明授权

US08273907B2 Process for producing propylene oxide 失效
标题翻译：生产环氧丙烷的方法
公开(公告)号：US08273907B2
公开(公告)日：2012-09-25
申请号：US12097975
申请日：2006-12-25
申请人： Tomonori Kawabata , Hiroaki Abekawa
发明人： Tomonori Kawabata , Hiroaki Abekawa
IPC分类号： C07D301/06
CPC分类号： B01J29/89 , B01J23/44 , B01J2229/186 , C07D301/10 , C07D301/12 , C07D303/04 , Y02P20/52
摘要： A process for more efficiently producing propylene oxide from propylene, oxygen, and hydrogen with catalysts which comprise a noble metal and a titanosilicate having pores not smaller than a 12-membered oxygen ring. The process for propylene oxide production is characterized by reacting propylene, oxygen, and hydrogen in a solution comprising water, a nitrite compound, and an ammonium salt in the presence of a noble metal catalyst and a titanosilicate catalyst having pores not smaller than a 12-membered oxygen ring.
摘要翻译：一种用丙烯，氧气和氢气更有效地生产环氧丙烷的方法，该催化剂包含贵金属和具有不小于12元氧环的孔的钛硅酸盐。环氧丙烷生产方法的特征在于在贵金属催化剂和具有不小于12重量％的孔的钛硅酸盐催化剂存在下，在包含水，亚硝酸盐化合物和铵盐的溶液中使丙烯，氧气和氢气反应，元氧环。

14. 发明授权

US07999125B2 Method for producing propylene oxide 失效
标题翻译：生产环氧丙烷的方法
公开(公告)号：US07999125B2
公开(公告)日：2011-08-16
申请号：US12665172
申请日：2008-06-19
申请人： Hiroaki Abekawa , Tomonori Kawabata , Makoto Yako
发明人： Hiroaki Abekawa , Tomonori Kawabata , Makoto Yako
IPC分类号： C07D301/12 , C07D301/06
CPC分类号： C07D301/06 , Y02P20/52
摘要： There is disclosed a method for producing propylene oxide, which includes: reacting propylene, oxygen, and hydrogen in the presence of a noble metal catalyst and a titanosilicate catalyst in a liquid phase containing a polycyclic compound, which is unsubstituted or substituted with at least one substituent selected from Group B below, wherein the polycyclic compound is composed of two or more identical or different ring compounds selected from Group A below and the ring compounds are fused, directly bonded, or bonded by a linkage group selected from the group consisting of an oxygen atom, carbon chain, and a group composed of oxygen atom(s) and a carbon chain, provided that said polycyclic compound is not a polycyclic compound having hydroxy groups or oxo groups at para or. ortho positions. Group A consisting of benzene, cyclopentadiene, cycloheptatriene, furane, pyrane, cyclopentene, cyclopentane, cyclohexane, cyclohexene, cyclohexadiene, cycloheptane, cycloheptene, and cycloheptadiene. Group B consisting of halogen atom, alkyl group, alkenyl group, alkoxy group, hydroxyalkyl group, acyl group, oxo group, hydroxy group, and cyano group.
摘要翻译：公开了一种生产环氧丙烷的方法，其包括：在贵金属催化剂和钛硅酸盐催化剂存在下，在含有多环化合物的液相中使丙烯，氧和氢反应，该多环化合物是未取代的或被至少一个取代基，其中所述多环化合物由两种或更多种相同或不同的选自下述A组的环化合物组成，并且所述环化合物通过选自以下的连接基团进行稠合，直接键合或键合：氧原子，碳链和由氧原子和碳链组成的基团，条件是所述多环化合物不是在对位或具有羟基或氧代基的多环化合物。邻位。 A组由苯，环戊二烯，环庚三烯，呋喃，吡喃，环戊烯，环戊烷，环己烷，环己烯，环己二烯，环庚烷，环庚烯和环庚二烯组成。 B族由卤素原子，烷基，烯基，烷氧基，羟基烷基，酰基，氧代基，羟基和氰基组成。

15. 发明申请

US20090264665A1 PROCESS FOR PRODUCING PROPYLENE OXIDE 失效
标题翻译：生产丙烯氧化物的方法
公开(公告)号：US20090264665A1
公开(公告)日：2009-10-22
申请号：US12097975
申请日：2006-12-25
申请人： Tomonori Kawabata , Hiroaki Abekawa
发明人： Tomonori Kawabata , Hiroaki Abekawa
IPC分类号： C07D301/06
CPC分类号： B01J29/89 , B01J23/44 , B01J2229/186 , C07D301/10 , C07D301/12 , C07D303/04 , Y02P20/52
摘要： A process for more efficiently producing propylene oxide from propylene, oxygen, and hydrogen with catalysts which comprise a noble metal and a titanosilicate having pores not smaller than a 12-membered oxygen ring. The process for propylene oxide production is characterized by reacting propylene, oxygen, and hydrogen in a solution comprising water, a nitrite compound, and an ammonium salt in the presence of a noble metal catalyst and a titanosilicate catalyst having pores not smaller than a 12-membered oxygen ring.
摘要翻译：一种用丙烯，氧气和氢气更有效地生产环氧丙烷的方法，该催化剂包含贵金属和具有不小于12元氧环的孔的钛硅酸盐。环氧丙烷生产方法的特征在于在贵金属催化剂和具有不小于12重量％的孔的钛硅酸盐催化剂存在下，在包含水，亚硝酸盐化合物和铵盐的溶液中使丙烯，氧气和氢气反应，元氧环。

16. 发明授权

US07153986B2 Method for producing propylene oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US07153986B2
公开(公告)日：2006-12-26
申请号：US10506584
申请日：2003-02-28
申请人： Hiroaki Abekawa , Masaru Ishino
发明人： Hiroaki Abekawa , Masaru Ishino
IPC分类号： C07D301/02 , B01J21/06
CPC分类号： C07D301/12 , B01J29/89 , Y02P20/52
摘要： A method is provided for producing propylene oxide, wherein propylene is reacted with hydrogen peroxide in the presence of an organic solvent and a crystalline titanosilicate catalyst having an MWW structure containing Ti, the Ti having been incorporated during crystallization.
摘要翻译：提供了一种用于生产环氧丙烷的方法，其中丙烯与有机溶剂和具有包含Ti的MWW结构的结晶钛硅酸盐催化剂的存在下与过氧化氢反应，在结晶过程中引入了Ti。

17. 发明申请

US20060173200A1 Process for producing propylene oxide 失效
公开(公告)号：US20060173200A1
公开(公告)日：2006-08-03
申请号：US10547628
申请日：2004-03-04
申请人： Masaru Ishino , Hiroaki Abekawa
发明人： Masaru Ishino , Hiroaki Abekawa
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , B01J29/89 , Y02P20/52
摘要： A process for producing propylene oxide, includes the steps of reacting propylene with hydrogen peroxide in the presence of a crystalline titanosilicate catalyst having a pore structure of a 12-oxygen-membered ring or more in an organic solvent as a medium capable of being separated from water solution, obtaining a reaction mixture containing propylene oxide, separating the reaction mixture into liquid phases to obtain a water layer and an oil layer containing the organic solvent, the propylene oxide thereby being separated from the water into the oil layer.

18. 发明授权

US5908607A Process for producing chlorine 失效
标题翻译：生产氯的方法
公开(公告)号：US5908607A
公开(公告)日：1999-06-01
申请号：US908958
申请日：1997-08-08
申请人： Hiroaki Abekawa , Yoshiaki Ito , Takuo Hibi
发明人： Hiroaki Abekawa , Yoshiaki Ito , Takuo Hibi
IPC分类号： B01J21/06 , B01J23/46 , C01B7/04 , C01B7/01
CPC分类号： B01J23/462 , C01B7/04 , B01J21/063 , B01J21/066
摘要： A process for producing chlorine by oxidizing hydrogen chloride with oxygen, which comprises using at least one catalyst selected from the group consisting of a supported ruthenium chloride catalyst, a catalyst obtained by supporting at least one ruthenium compound, a ruthenium oxide catalyst obtained by oxidizing a catalyst which is prepared by supporting at least one ruthenium compound, and a catalyst obtained by calcining ruthenium chloride supported on a carrier at the temperature of not less than 280.degree. C.
摘要翻译：一种通过用氧氧化氯化氢来生产氯的方法，该方法包括使用至少一种选自负载的氯化钌催化剂，通过负载至少一种钌化合物获得的催化剂的催化剂，氧化氧化钌通过负载至少一种钌化合物制备的催化剂和通过在不低于280℃的温度下负载在载体上煅烧氯化钌而获得的催化剂。

19. 发明授权

US07994349B2 Process for producing of epoxy compound 失效
标题翻译：环氧化合物的制备方法
公开(公告)号：US07994349B2
公开(公告)日：2011-08-09
申请号：US12087461
申请日：2007-01-09
申请人： Tomonori Kawabata , Hiroaki Abekawa
发明人： Tomonori Kawabata , Hiroaki Abekawa
IPC分类号： C07D301/12 , C07D301/06
CPC分类号： C07D301/06
摘要： An object of the present invention is to provide an efficient process for producing an epoxy compound from olefin, oxygen and hydrogen. The process of the present invention is characterized in that an olefin, oxygen and hydrogen are reacted in a liquid phase in the presence of a titanosilicate selected from the group consisting of a crystalline titanosilicate having MEL structure, MTW structure, BEA structure, MWW structure or DON structure, a mesoporous titanosilicate and a lamellar titanosilicate, a noble metal catalyst, and a quinoid compound or a dihydro-form of quinoid compound.
摘要翻译：本发明的目的是提供从烯烃，氧和氢生产环氧化合物的有效方法。本发明的方法的特征在于，在钛酸硅酸盐存在下，在液相中使烯烃，氧和氢反应，所述钛硅酸盐选自具有MEL结构的结晶钛硅酸盐，MTW结构，BEA结构，MWW结构或 DON结构，介孔钛硅酸盐和层状钛硅酸盐，贵金属催化剂和醌类化合物或二氢型喹啉化合物。

20. 发明申请

US20110009651A1 REGENERATION METHOD OF TITANOSILICATE CATALYST 审中-公开
标题翻译：钛酸酯催化剂的再生方法
公开(公告)号：US20110009651A1
公开(公告)日：2011-01-13
申请号：US12921130
申请日：2009-03-03
申请人： Tomonori Kawabata , Hiroaki Abekawa , Makoto Yako
发明人： Tomonori Kawabata , Hiroaki Abekawa , Makoto Yako
IPC分类号： C07D301/04 , B01J38/50 , B01J38/02 , B01J38/00
CPC分类号： C07D301/02 , B01J29/89 , B01J29/90 , B01J38/50 , Y02P20/584 , Y02P20/588
摘要： The present invention provides a regeneration method of a titanosilicate catalyst, specifically provides a regeneration method of a titanosilicate catalyst which comprises contacting the titanosilicate catalyst deteriorated in catalytic ability with a nitrile compound or a mixture of water and a nitrile compound at a temperature from 25° C. to 200° C.
摘要翻译：本发明提供钛硅酸盐催化剂的再生方法，具体提供钛硅酸盐催化剂的再生方法，该方法包括使催化能力劣化的钛硅酸盐催化剂与腈化合物或水与腈化合物的混合物在25℃ C.至200℃

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