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    • 12. 发明授权
    • Solid electrolyte capacitor, and process and apparatus for producing same
    • 固体电解电容器及其制造方法和装置
    • US06168639A
    • 2001-01-02
    • US09166910
    • 1998-10-06
    • Yutaka TaketaniKakusyo YoshidaHidenori KamigawaYasuhiro KishimotoYouichi KojimaTakeshi Takamatsu
    • Yutaka TaketaniKakusyo YoshidaHidenori KamigawaYasuhiro KishimotoYouichi KojimaTakeshi Takamatsu
    • H01G900
    • H01G9/0036H01G9/025H01G9/0425H01G11/48H01G11/56Y02E60/13Y10T29/417
    • The invention provides a process for producing solid electrolyte capacitors by forming a dielectric oxide film and a first cathode layer of solid conductive substance over the surface of an anode body of valve metal, and forming a second cathode layer of conductive high polymer on the first cathode layer by electrolytic oxidative polymerization. In forming the second cathode layer, the pH of the electrolyte to be used for electrolytic oxidative polymerization is maintained within a predetermined range by adding an acid or alkali to the electrolyte. Since the pH of the electrolyte remains substantially unaltered by the polymerization according to the invention, the electrolyte is repeatedly usable while permitting the resulting second cathode layers to retain the desired electric conductivity. The second cathode layer is formed by immersing in the electrolyte the anode body formed over the surface thereof with the oxide film and the first cathode layer, feeding a positive voltage with an external electrode piece in contact with the first cathode layer in the electrolyte, and shifting the feeding point at a predetermined time interval. The feeding point where the electrode piece is in contact with the first cathode layer for feeding shifts during the step of electrolytic oxidative polymerization, so that the thickness of the second cathode layer formed as centered about the feeding point is made uniform to the greatest possible extent over the entire anode body without increasing locally.
    • 本发明提供了一种通过在阀金属的阳极体的表面上形成电介质氧化物膜和固体导电物质的第一阴极层来制造固体电解质电容器的方法,并且在第一阴极上形成导电高聚物的第二阴极层 层通过电解氧化聚合。 在形成第二阴极层时,将用于电解氧化聚合的电解质的pH通过向电解质中加入酸或碱而保持在预定范围内。 由于通过根据本发明的聚合基本上不改变电解质的电解液,所​​以可以重复使用电解质,同时允许得到的第二阴极层保持所需的导电性。 第二阴极层是通过将氧化膜和第一阴极层在其表面上形成的阳极体浸渍在电解质中,在电解质中与外部电极片接触的第一阴极层供给正电压而形成的, 以预定的时间间隔移动馈送点。 在电解氧化聚合步骤期间电极片与第一阴极层接触供电位置的馈电点,使得以馈电点为中心形成的第二阴极层的厚度尽可能地均匀化 在整个阳极体上,而不会局部增加。
    • 16. 发明申请
    • Method of producing solid electrolytic capacitor
    • 固体电解电容器的制造方法
    • US20050030678A1
    • 2005-02-10
    • US10487072
    • 2002-08-12
    • Yutaka TaketaniYoshiaki HasabaMakoto SakamakiTadahito Ito
    • Yutaka TaketaniYoshiaki HasabaMakoto SakamakiTadahito Ito
    • H01G9/028H01G9/00H01G9/02H01G2/14
    • H01G9/0036H01G9/028
    • A manufacturing method according to the present invention of a solid electrolytic capacitor includes: a step of immersing a anode body on which the dielectrics film layer is formed in a solution that includes from 0.7 to 10% by weight of hydrogen peroxide, from 0.3 to 3% by weight of sulfuric acid and water as a main solvent, followed by, after pulling up, exposing to vapor of pyrrole or a pyrrole derivative, and thereby forming, on the dielectrics film layer, a first conductive polymer layer made of polypyrrole or a polypyrrole derivative; and a step of immersing the anode body on which the dielectrics film layer and the first conductive polymer layer are formed in a solution that includes a polymerizing monomer and a supporting electrolyte to electrolytically polymerize the polymerizing monomer, and thereby forming a second conductive polymer layer on the first conductive polymer layer.
    • 根据本发明的固体电解电容器的制造方法包括:将形成有电介质膜层的阳极体浸渍在含有0.7〜10重量%的过氧化氢的溶液中,0.3〜3 重量%的硫酸和水作为主要溶剂,然后在拉起之后暴露于吡咯或吡咯衍生物的蒸气,从而在电介质膜层上形成由聚吡咯形成的第一导电聚合物层或 聚吡咯衍生物 以及将包含电介质膜层和第一导电性聚合物层的阳极体浸渍在包含聚合性单体和支持电解质的溶液中以电解聚合聚合性单体的步骤,从而形成第二导电聚合物层 第一导电聚合物层。