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    • 14. 发明授权
    • Mixed carbon material and negative electrode for a nonaqueous secondary battery
    • 用于非水二次电池的混合碳材料和负极
    • US08501047B2
    • 2013-08-06
    • US13006693
    • 2011-01-14
    • Hiroshi YamamotoTatsuo NagataTooru Fujiwara
    • Hiroshi YamamotoTatsuo NagataTooru Fujiwara
    • H01B1/02
    • H01M4/587C01B32/20H01M4/133H01M10/0525
    • A negative electrode material provided by the present invention capable of suppressing a decrease in charge acceptance and high temperature storage properties in an electrode with a high capacity and a high density is a mixed carbon material comprising carbon material A having cores of graphite powder with amorphous carbon and/or turbostratic carbon adhered to or coated on the surface of the cores and carbon material B which is graphite powder, the compressibility which is the density (g/cm3) of the material when 1.00 grams of the material are packed into a cylindrical mold with an inner diameter of 15 mm and compressed by applying a pressing force of 8.7 kN and reducing the pressing force to 0.15 kN is 1.60-1.78 g/cm3 for carbon material A and 1.75-1.85 g/cm3 for carbon material B, the compressibility of carbon material A is less than the compressibility of carbon material B, and the mixing ratio (carbon material A/carbon material B) is 1-9 as a mass ratio.
    • 本发明提供的能够抑制具有高容量和高密度的电极中的电荷接受性和高温保存性降低的负极材料是包含碳材料A的混合碳材料,所述碳材料A具有具有无定形碳的石墨粉末的芯 和/或渗透碳附着在或涂覆在芯的表面上,并且作为石墨粉末的碳材料B,当将1.00克材料包装到圆柱形模具中时,该材料的密度(g / cm 3)的可压缩性 通过施加8.7kN的压力并将压力降低至0.15kN而压缩的碳素材料A为1.60-1.78g / cm 3,碳材料B为1.75-1.85g / cm 3,压缩率 碳材料A的比例小于碳材料B的压缩率,混合比(碳材料A /碳材料B)的质量比为1-9。