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11. 发明授权

US5837641A Method of promoting the activity of solid strong acid catalysts 失效
标题翻译：促进固体强酸催化剂活性的方法
公开(公告)号：US5837641A
公开(公告)日：1998-11-17
申请号：US585986
申请日：1996-01-16
申请人： Christopher D. Gosling , Paul G. Blommel , Michelle J. Cohn , Ralph D. Gillespie , Jennifer S. Holmgren
发明人： Christopher D. Gosling , Paul G. Blommel , Michelle J. Cohn , Ralph D. Gillespie , Jennifer S. Holmgren
IPC分类号： B01J23/24 , B01J27/053 , B01J27/047 , B01J23/00 , B01J23/14
CPC分类号： B01J23/24 , B01J27/053 , Y10S502/513 , Y10S502/514
摘要： A method of continuously promoting the activity of solid strong acid catalysts used in acid catalyzed reactions by adding or generating water in the reaction mixture has been developed. The solid strong acid catalyst may be a sulfated metal oxide, a tungstated metal oxide, or a molybdated metal oxide. The metal oxides are oxides, hydroxides, oxyhydroxides, or oxide-hydrates of Group IV-A, Group III-A, Group III-B, and Group V-A metals. The catalyst may also contain a Group VIII metal, or when the metal oxide is a hydroxide, oxide, oxyhydroxide, or oxide-hydrate of the Group IV-A, Group III-A, or Group III-B metals, the catalyst may also contain an oxide, hydroxide, oxyhydroxide or oxide-hydrate of a Group V-A, Group V-B, Group VI-B, or Group VII-B metal as a promoter. The acid catalyzed reactions where the activity promotion method may be applied include catalytic cracking, catalytic reforming, hydrodesulfurization, isomerization, alkylation of aliphatic and aromatic hydrocarbons, polymerization, and oligomerization. The amount of water added to or generated in the reaction mixture may be from about 0.1 ppm to about 500 ppm water.
摘要翻译：已经开发了通过在反应混合物中加入或产生水来连续促进用于酸催化反应的固体强酸催化剂活性的方法。固体强酸催化剂可以是硫酸化金属氧化物，钨酸盐金属氧化物或钼酸盐金属氧化物。金属氧化物是IV-A族，III-A族，III-B族和V-A族金属的氧化物，氢氧化物，羟基氧化物或氧化物 - 水合物。催化剂还可以含有VIII族金属，或者当金属氧化物是IV-A族，III-A族或III-B族金属的氢氧化物，氧化物，羟基氧化物或氧化物水合物时，催化剂也可以含有VA族，VB族，VI-B族或VII-B族金属的氧化物，氢氧化物，羟基氧化物或氧化物水合物作为促进剂。可以应用活性促进方法的酸催化反应包括催化裂化，催化重整，加氢脱硫，异构化，脂族和芳烃的烷基化，聚合和低聚。在反应混合物中加入或产生的水的量可以是约0.1ppm至约500ppm的水。

12. 发明授权

US5831139A Production of aliphatic gasoline 失效
标题翻译：生产脂肪族汽油
公开(公告)号：US5831139A
公开(公告)日：1998-11-03
申请号：US832321
申请日：1997-03-26
申请人： Robert J. Schmidt , Paula L. Bogdan , Leonid B. Galperin , Jennifer S. Holmgren
发明人： Robert J. Schmidt , Paula L. Bogdan , Leonid B. Galperin , Jennifer S. Holmgren
IPC分类号： C10G59/00 , C07C1/00 , C07C5/13
CPC分类号： C10G59/00 , Y10S585/94
摘要： A process combination is disclosed to selectively upgrade naphtha in accordance with expected trends leading to more-aliphatic gasolines. Such gasolines contain lower concentrations of aromatics and have lower end points with concomitant reduced harmful automotive emissions. The present process combination converts the higher-boiling portion of the naphtha, yields isobutane and other isoparaffins which are particularly suitable for upgrading or blending, and reduces cyclics in intermediate processing steps.
摘要翻译：公开了一种方法组合以根据导致更多脂肪族汽油的预期趋势选择性地升级石脑油。这种汽油含有较低浓度的芳族化合物，具有较低的终点，同时减少有害的汽车排放。本方法组合转化石脑油的较高沸点部分，产生特别适用于升级或混合的异丁烷和其它异链烷烃，并减少中间处理步骤中的循环。

13. 发明授权

US5360536A Removal of sulfur compounds from liquid organic feedstreams 失效
标题翻译：从液体有机原料流中除去硫化合物
公开(公告)号：US5360536A
公开(公告)日：1994-11-01
申请号：US103388
申请日：1993-08-09
申请人： Laszlo T. Nemeth , Santi Kulprathipanja , Blaise J. Arena , Jennifer S. Holmgren
发明人： Laszlo T. Nemeth , Santi Kulprathipanja , Blaise J. Arena , Jennifer S. Holmgren
IPC分类号： C10G25/00 , C10G29/16
CPC分类号： C10G25/003
摘要： A process for removing sulfur containing compounds from various liquid organic feedstreams has been developed. The process involves contacting the feed stream with a metal oxide solid solution which adsorbs the sulfur containing compounds. Examples of these solid solutions are Mg/Al and Ni/Mg/Al oxide solid solutions.
摘要翻译：已经开发了从各种液体有机原料流中除去含硫化合物的方法。该方法包括使进料流与吸附含硫化合物的金属氧化物固溶体接触。这些固溶体的实例是Mg / Al和Ni / Mg / Al氧化物固溶体。

14. 发明授权

US5258558A Direct conversion of butyraldehyde to 2-ethylhexanol-1 失效
标题翻译：将丁醛直接转化为2-乙基己醇-1
公开(公告)号：US5258558A
公开(公告)日：1993-11-02
申请号：US884000
申请日：1992-05-18
申请人： Blaise J. Arena , Jennifer S. Holmgren
发明人： Blaise J. Arena , Jennifer S. Holmgren
IPC分类号： B01J21/10 , B01J23/00 , B01J37/02 , B01J37/03 , C07C45/74 , C07C29/141 , C07C29/14
CPC分类号： C07C45/74 , B01J21/10 , B01J37/0236 , B01J37/03 , B01J23/007
摘要： Solid solutions of magnesium oxide-aluminum oxide related to hydrotalcite and what previously has been referred to as synthetic hydrotalcites, have been prepared with a surface area in excess of 250 m.sup.2 /g, especially at low Mg/Al atom ratios. Such high surface area materials are found to be quite effective in the aldol condensation of aldehydes, and in particular in the conversion of n-butyraldehyde to 2-ethyl-2-hexenal in high yield and with good selectivity in a liquid phase reaction at temperatures under about 200.degree. C.
摘要翻译：制备了与水滑石相关的氧化镁 - 氧化铝和以前称为合成水滑石的固体溶液，其表面积超过250m2 / g，特别是在低Mg / Al原子比下。发现这种高表面积材料在醛的醛醇缩合中是非常有效的，特别是在高产率下将正丁醛转化为2-乙基-2-己烯醛，并且在温度下在液相反应中具有良好的选择性在约200℃

15. 发明授权

US5254743A Solid bases as catalysts in aldol condensations 失效
标题翻译：固体碱作为醛醇缩合物中的催化剂
公开(公告)号：US5254743A
公开(公告)日：1993-10-19
申请号：US987838
申请日：1992-12-09
申请人： Jennifer S. Holmgren , Blaise J. Arena
发明人： Jennifer S. Holmgren , Blaise J. Arena
IPC分类号： B01J23/00 , B01J35/00 , C07C45/62 , C07C45/66 , C07C45/72 , C07C45/73 , C07C45/74
CPC分类号： B01J35/0006 , C07C45/62 , C07C45/66 , C07C45/72 , C07C45/73 , C07C45/74 , B01J23/007
摘要： Solid solutions of a class of divalent metal oxides and a class of trivalent metal oxides resulting from calcination of layered double hydroxides related to hydrotalcite have been prepared with a surface area in excess of 150 m.sup.2 /g. Such high surface area materials are found to be quite effective in the aldol condensation of aldehydes and ketones, and in particular in the conversion of n-butyraldehyde to 2-ethyl-2-hexenal in high yield and with good selectivity in a liquid phase reaction at temperatures under about 200.degree. C. Variants can be devised where the aldol condensation product, an .alpha.,.beta.-unsaturated aldehyde or ketone, is concurrently reduced to the saturated alcohol under process conditions.
摘要翻译：已经制备了表面积超过150m 2 / g的一类二价金属氧化物和由煅烧与水滑石相关的层状双氢氧化物产生的一类三价金属氧化物的固溶体。发现这种高表面积的材料在醛和酮的醛醇缩合中是非常有效的，特别是在以高产率和良好的液相反应选择性将正丁醛转化成2-乙基-2-己烯醛在约200℃的温度下，可以设计出变体，其中醛醇缩合产物，α，β-不饱和醛或酮在工艺条件下同时还原成饱和醇。

16. 发明授权

US5192725A Gallium/germanium dioctahedral smectite clay and process for preparing the clay 失效
标题翻译：镓/锗二八面体蒙皂石和制备粘土的方法
公开(公告)号：US5192725A
公开(公告)日：1993-03-09
申请号：US753511
申请日：1991-09-03
申请人： Jennifer S. Holmgren
发明人： Jennifer S. Holmgren
IPC分类号： B01J20/06 , B01J20/12 , B01J21/16 , B01J29/04
CPC分类号： B01J29/049 , B01J20/12 , B01J21/16
摘要： This invention relates to a novel dioctahedral smectite layered clay, a process for preparing the clay and a process using the clay. The clay is characterized in that the aluminum can be substituted by gallium and the silicon can be substituted by germanium. Therefore, some of the possible clays that can be prepared are gallium/silicon, gallium/germanium, or aluminum/germanium smectite clays. The clay is prepared from a reaction mixture containing reactive sources of the metals, i.e., aluminum, silicon, gallium and germanium, a templating agent and water. This reaction mixture is reacted at a pH of about 8.5 to about 14, a temperature of about 150.degree. to about 210.degree. C. for a time of about 1 to about 20 days to give a desired composition. The clay compositions of the instant invention can be used to catalyze various hydrocarbon conversion processes such as alkylation and hydrocracking.
摘要翻译：本发明涉及新型二八面体蒙皂石层状粘土，制备粘土的方法和使用该粘土的方法。该粘土的特征在于铝可以被镓取代，硅可以被锗取代。因此，可以制备的一些可能的粘土是镓/硅，镓/锗或铝/锗蒙皂石粘土。粘土由含有金属反应性源的反应混合物制备，即铝，硅，镓和锗，模板剂和水。该反应混合物在约8.5至约14的pH，约150至约210℃的温度下反应约1至约20天的时间，得到所需的组合物。本发明的粘土组合物可用于催化各种烃转化方法如烷基化和加氢裂化。

17. 发明授权

US5114895A Alumina clay compositions 失效
标题翻译：氧化铝粘土组合物
公开(公告)号：US5114895A
公开(公告)日：1992-05-19
申请号：US632244
申请日：1990-12-20
申请人： Jennifer S. Holmgren , Stanley A. Gembicki , Michael W. Schoonover , Joseph A. Kocal
发明人： Jennifer S. Holmgren , Stanley A. Gembicki , Michael W. Schoonover , Joseph A. Kocal
IPC分类号： B01J21/16 , B01J29/04 , C07C4/06 , C10G47/12
CPC分类号： C07C4/06 , B01J21/16 , B01J29/049 , C10G47/12 , B01J2229/42 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/16 , C07C2527/16
摘要： This invention relates to a composition, a method of preparing the composition and a catalyst using the composition. The composition consists essentially of a layered clay homogeneously dispersed in an inorganic oxide matrix. The clay is dispersed in such a way that the clay layers are completely surrounded by the inorganic oxide matrix. The inorganic oxide is selected from the group consisting of alumina, titania, silica, zirconia, P.sub.2 O.sub.5 and mixtures thereof. The clay can be a natural clay such as montmorillonite, a metal exchanged clay (Fe.sup.+3 exchanged) or a pillared clay such as aluminum chlorohydrate (ACH) pillared clay. The composition can be used as a catalyst for alkylation or hydrocracking or metals can be dispersed on it to provide a catalyst which is also useful for hydrocracking or alkylation.
摘要翻译：本发明涉及组合物，制备该组合物的方法和使用该组合物的催化剂。该组合物基本上由均匀分散在无机氧化物基质中的层状粘土组成。粘土以这样的方式分散，即粘土层被无机氧化物基体完全包围。无机氧化物选自氧化铝，二氧化钛，二氧化硅，氧化锆，P 2 O 5及其混合物。粘土可以是天然粘土，例如蒙脱石，金属交换的粘土（Fe + 3交换的）或柱状粘土如水合氯化铝（ACH）柱状粘土。该组合物可以用作烷基化或加氢裂化的催化剂，或者可以将金属分散在其上以提供也可用于加氢裂化或烷基化的催化剂。

18. 发明授权

US6063977A Selective aromatics disproportionation process 有权
标题翻译：选择性芳烃歧化过程
公开(公告)号：US6063977A
公开(公告)日：2000-05-16
申请号：US213959
申请日：1998-12-17
申请人： Gregory J. Gajda , Edwin P. Boldingh , Jennifer S. Holmgren
发明人： Gregory J. Gajda , Edwin P. Boldingh , Jennifer S. Holmgren
IPC分类号： B01J27/16 , B01J29/40 , B01J29/70 , B01J37/00 , C07C6/12 , C07C5/22
CPC分类号： B01J37/0009 , B01J27/16 , B01J29/40 , B01J29/70 , B01J37/0072 , C07C6/123 , B01J2229/26 , B01J2229/42 , C07C2529/06 , Y02P20/52
摘要： An improved catalyst and process are disclosed for the selective disproportionation of toluene. The process uses a zeolitic catalyst which is oil-dropped in an aluminum phosphate binder and has an X-ray diffraction pattern showing characteristic intensities at specified Bragg angles. Optionally, the catalyst is selectively precoked prior to toluene disproportionation. The catalyst and process provide improved selectivity for the production of paraxylene.
摘要翻译：公开了改进的催化剂和方法用于甲苯的选择性歧化。该方法使用在磷酸铝粘合剂中油滴的沸石催化剂，并且具有在特定布拉格角下显示特征强度的X射线衍射图。任选地，在甲苯歧化之前选择性地预先催化剂。催化剂和方法为对二甲苯的生产提供了改进的选择性。

19. 发明授权

US5807475A Process for removing sulfur compounds from hydrocarbon streams 失效
标题翻译：从烃流中除去硫化合物的方法
公开(公告)号：US5807475A
公开(公告)日：1998-09-15
申请号：US751829
申请日：1996-11-18
申请人： Santi Kulprathipanja , Laszlo T. Nemeth , Jennifer S. Holmgren
发明人： Santi Kulprathipanja , Laszlo T. Nemeth , Jennifer S. Holmgren
IPC分类号： C10G25/00 , C10G25/05 , C10G17/00
CPC分类号： C10G25/05 , C10G25/003
摘要： A process for removing sulfur containing compounds from various hydrocarbon streams is disclosed and claimed. The process involves contacting the feedstream with an adsorbent such as nickel exchanged zeolite X or Y, or a smectite layered clay having a surface area of at least 150 m.sup.2 /g, thereby adsorbing the sulfur compounds onto the adsorbent.
摘要翻译：公开并要求保护从各种烃流中除去含硫化合物的方法。该方法包括使进料流与诸如镍交换的沸石X或Y的吸附剂或表面积至少为150m 2 / g的蒙皂石层状粘土接触，从而将硫化合物吸附到吸附剂上。

20. 发明授权

US5733439A Hydrocarbon conversion processes using substituted fluoride smectite clays 失效
标题翻译：使用取代氟化物蒙脱石粘土的烃转化方法
公开(公告)号：US5733439A
公开(公告)日：1998-03-31
申请号：US571665
申请日：1995-12-13
申请人： Jennifer S. Holmgren
发明人： Jennifer S. Holmgren
IPC分类号： B01J21/16 , B01J23/00 , C01B33/40 , C07C2/08 , C07C2/10 , C07C2/54 , C10G47/12 , C10G50/00 , C10G47/02 , C07C2/02 , C07C2/58
CPC分类号： B01J21/16 , B01J23/007 , C01B33/40 , C01B33/405 , C07C2/08 , C07C2/10 , C07C2/54 , C10G47/12 , C10G50/00 , C07C2521/16
摘要： Hydrocarbon conversion processes, e.g., alkylation, are disclosed and claimed which use as the catalyst novel fluoride containing substituted smectite clays. The clay has the formula A.sub.x (M.sub.y M'.sub.4-y)(Si.sub.8-x M.sub.t M'.sub.v)O.sub.20 (OH).sub.4-u F.sub.u where A is a cation, M and M' are metals having a +3 oxidation state, each selected from the group consisting of aluminum, gallium, iron and chromium, x is the moles of A, y is the moles of M, t and v are the moles of M and M' in the tetrahedral layer and t+v=x and u is the moles of F. The clay composition may be used as is or after pillaring to catalyze hydrocarbon conversion processes such as alkylation.
摘要翻译：烃转化方法，例如烷基化，被公开和要求保护，其用作催化剂新型含氟取代的绿土粘土。粘土具有式Ax（MyM'4-y）（Si8-xMtM'v）O20（OH）4-uFu，其中A是阳离子，M和M'是具有+3氧化态的金属，由铝，镓，铁和铬组成的组，x是A的摩尔数，y是M的摩尔数，t和v是四面体层中M和M'的摩尔数，t + v = x，u是粘土组合物可以原样使用或在柱后使用以催化烃转化过程如烷基化。

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