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    • 18. 发明授权
    • Polymer compound, acid generator, positive resist composition, and method for formation of resist patterns
    • 高分子化合物,酸发生剂,正性抗蚀剂组合物和形成抗蚀剂图案的方法
    • US07482108B2
    • 2009-01-27
    • US11572990
    • 2005-07-01
    • Shogo MatsumaruMasaru TakeshitaTakeshi IwaiHideo Hada
    • Shogo MatsumaruMasaru TakeshitaTakeshi IwaiHideo Hada
    • G30F7/00G30F7/004
    • G03F7/0045C08F220/18C08F220/28C08F220/38G03F7/0397Y10S430/106Y10S430/114
    • The invention provides a polymer compound capable of forming a positive resist composition that can form a high-resolution pattern with a reduced level of LER, an acid generator formed from such a polymer compound, a positive resist composition that includes such a polymer compound, and a method for forming a resist pattern that uses such a positive resist composition. The polymer compound includes a structural unit (a1) derived from an (α-lower alkyl) acrylate ester having an acid-dissociable, dissolution-inhibiting group, a structural unit (a2) represented by a general formula (a2-1) shown below [wherein, R represents a hydrogen atom or a lower alkyl group; A represents a divalent organic group; B represents a monovalent organic group; X represents a sulfur atom or iodine atom; n represents either 1 or 2; and Y represents a straight-chain, branched or cyclic alkyl group in which at least one hydrogen atom may be substituted with a fluorine atom], and a structural unit (a3) derived from an (α-lower alkyl) acrylate ester that contains a polar group-containing aliphatic polycyclic group.
    • 本发明提供一种能够形成正性抗蚀剂组合物的高分子化合物,其可以形成具有降低的LER水平的高分辨率图案,由这种高分子化合物形成的酸发生剂,包含这种高分子化合物的正性抗蚀剂组合物和 形成使用这种正性抗蚀剂组合物的抗蚀剂图案的方法。 高分子化合物包括衍生自具有酸解离性,溶解抑制基团的(α-低级烷基)丙烯酸酯的结构单元(a1),由以下所示的通式(a2-1)表示的结构单元(a2) [式中,R表示氢原子或低级烷基; A表示二价有机基团; B表示一价有机基团; X表示硫原子或碘原子; n表示1或2; 和Y表示其中至少一个氢原子可被氟原子取代的直链,支链或环状烷基]和衍生自(α-低级烷基)丙烯酸酯的结构单元(a3),其包含 含极性基团的脂族多环基团。