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    • 14. 发明申请
    • Flue gas denitration catalyst and preparation process thereof
    • 烟气脱硝催化剂及其制备方法
    • US20050054523A9
    • 2005-03-10
    • US10705365
    • 2003-11-10
    • Shigeru NojimaKozo IidaYoshiaki ObayashiKatsumi NochiMasashi Kiyosawa
    • Shigeru NojimaKozo IidaYoshiaki ObayashiKatsumi NochiMasashi Kiyosawa
    • B01D53/94B01D53/86B01J23/00B01J23/30B01J35/04B01J37/02
    • B01D53/8631B01D53/8628B01J23/002B01J23/30B01J35/04B01J37/0238
    • Provided are a flue gas denitration catalyst having high denitration activity and capable of suppressing a side reaction, that is, oxidation of SO2; and a preparation process of the catalyst. The flue gas denitration catalyst comprises TiO2, WO3 and V2O5. In the surface layer of the catalyst within 200 μm from the surface thereof, V2O5 is supported on a carrier containing TiO2 and WO3. The supported amounts of V2O5 range from 0.4 to 5 wt. % based on the weight of the surface layer and range from 0.1 to 0.9 wt. % based on the total weight of the catalyst. The V2O5 thus supported has a crystallite size of less than 10 nm as measured by X-ray diffraction. The catalyst can be available by preparing a mixture containing TiO2 and WO3 and having V2O5 supported on the surface of an extruded product of the prepared mixture by a vapor phase method. The catalyst can be also available by having V2O5 supported on a powder of the prepared mixture by a vapor phase method and having the resulting powder supported on the surface of a formed product.
    • 本发明提供一种脱硝活性高,能够抑制副反应即SO2氧化的烟道气脱硝催化剂。 和催化剂的制备方法。 烟气脱硝催化剂包括TiO 2,WO 3和V 2 O 5。 在催化剂的表面200μm以内的表面层中,将V 2 O 5负载在含有TiO 2和WO 3的载体上。 V2O5的负载量为0.4〜5wt。 %,基于表层的重量,为0.1-0.9wt。 %,基于催化剂的总重量。 如此支持的V 2 O 5通过X射线衍射测得的微晶尺寸小于10nm。 催化剂可以通过制备含有TiO 2和WO 3的混合物并且通过气相法将V 2 O 5负载在所制备的混合物的挤出产品的表面上来获得。 催化剂也可以通过使V 2 O 5通过气相法在制备的混合物的粉末上负载并将所得粉末负载在成形产品的表面上来获得。
    • 17. 发明申请
    • BURNER
    • 刻录机
    • US20090291401A1
    • 2009-11-26
    • US12373008
    • 2007-08-07
    • Keiichi NakagawaNaohiko MatsudaKatsuki YagiShigeru NojimaAkira Goto
    • Keiichi NakagawaNaohiko MatsudaKatsuki YagiShigeru NojimaAkira Goto
    • F23D11/10
    • F23D11/107F23D11/404
    • An object of the present invention is to provide a burner such as a two-fluid spray burner which can produce a large amount of combustion exhaust gas with a simple structure, does not cause unburned gas and accidental fire, and furthermore can provide shortened flame and a uniform distribution of the flow rate of the combustion exhaust gas. Accordingly, the burner includes: a cylindrical combustion air passage (15) formed between a two-fluid sprayer (12) and a burner outer cylinder (48) surrounding a periphery of the two-fluid sprayer; a plate (shield plate) (18) separating the combustion air passage and a combustion space portion (13); and a combustion air passage hole (52) provided in the outer periphery of the plate. Combustion air (50) flowing down the combustion air passage is blocked by the plate and introduced to the outer periphery of the plate to be kept away from the two-fluid spray nozzle (38). The combustion air then flows through the combustion air passage hole into the combustion space portion. Furthermore, a first cylinder (16) for delaying supply of the combustion air and a second cylinder (17) for preventing stagnation are provided on the undersurface of the plate. A throttle plate with a passage hole opened in central part is provided in the combustion space portion.
    • 本发明的目的是提供一种能够以简单结构产生大量燃烧废气的双流体喷射燃烧器等燃烧器,不会引起未燃烧气体和意外的火灾,并且还能够提供缩短的火焰和 燃烧废气流量的均匀分布。 因此,燃烧器包括:形成在双流体喷射器(12)和围绕双流体喷射器的周边的燃烧器外筒(48)之间的圆柱形燃烧空气通道(15) 分隔燃烧空气通道和燃烧空间部分(13)的板(屏蔽板)(18); 以及设置在板的外周的燃烧空气通路孔(52)。 从燃烧空气通道向下流动的燃烧空气(50)被板阻挡并被引入板的外周,以远离二流体喷嘴(38)。 燃烧空气然后通过燃烧空气通道孔流入燃烧空间部分。 此外,用于延迟供给燃烧空气的第一气缸(16)和用于防止停滞的第二气缸(17)设置在板的下表面上。 在燃烧空间部分设置有在中心部分开口的通孔的节流板。
    • 18. 发明授权
    • Flue gas denitration catalyst and preparation process thereof
    • 烟气脱硝催化剂及其制备方法
    • US07256155B2
    • 2007-08-14
    • US10705365
    • 2003-11-10
    • Shigeru NojimaKozo IidaYoshiaki ObayashiKatsumi NochiMasashi Kiyosawa
    • Shigeru NojimaKozo IidaYoshiaki ObayashiKatsumi NochiMasashi Kiyosawa
    • B01J23/00B01J21/00
    • B01D53/8631B01D53/8628B01J23/002B01J23/30B01J35/04B01J37/0238
    • Provided are a flue gas denitration catalyst having high denitration activity and capable of suppressing a side reaction, that is, oxidation of SO2; and a preparation process of the catalyst. The flue gas denitration catalyst comprises TiO2, WO3 and V2O5. In the surface layer of the catalyst within 200 μm from the surface thereof, V2O5 is supported on a carrier containing TiO2 and WO3. The supported amounts of V2O5 range from 0.4 to 5 wt. % based on the weight of the surface layer and range from 0.1 to 0.9 wt. % based on the total weight of the catalyst. The V2O5 thus supported has a crystallite size of less than 10 nm as measured by X-ray diffraction. The catalyst can be available by preparing a mixture containing TiO2 and WO3 and having V2O5 supported on the surface of an extruded product of the prepared mixture by a vapor phase method. The catalyst can be also available by having V2O5 supported on a powder of the prepared mixture by a vapor phase method and having the resulting powder supported on the surface of a formed product.
    • 提供了具有高脱硝活性并能够抑制副反应,即SO 2氧化的烟道气脱硝催化剂。 和催化剂的制备方法。 烟道气脱硝催化剂包括TiO 2,WO 3和V 2 O 5。 在催化剂的表面200μm以内的表面层中,V 2 O 2 O 5负载在含有TiO 2和WO 2的载体上 3 。 V 2 O 5的支持量为0.4-5重量%。 %,基于表层的重量,为0.1-0.9wt。 %,基于催化剂的总重量。 如此支撑的V 2 O 5 5具有通过X射线衍射测量的小于10nm的微晶尺寸。 催化剂可以通过制备含有TiO 2和WO 3的混合物并具有V 2 O 5 O 5 在制备的混合物的挤出产物的表面上通过气相法。 催化剂也可以通过使V 2 O 2 O 5通过气相法负载在所制备的混合物的粉末上,并将所得粉末负载在表面上 成型产品。
    • 19. 再颁专利
    • Ammonia decomposition catalysts
    • 氨分解催化剂
    • USRE39041E1
    • 2006-03-28
    • US10052225
    • 2002-01-16
    • Shigeru NojimaRie TokuyamaKouzo Iida
    • Shigeru NojimaRie TokuyamaKouzo Iida
    • C01B3/04
    • B01D53/8634B01J29/04B01J29/082B01J29/084B01J29/18B01J29/7003B01J37/0246Y02E60/364
    • An ammonia decomposition catalyst wherein a first catalyst having a crystalline silicate which is represented by the formula in terms of molar ratio of oxides as dehydrated: (1±0.8)R2O.[aM2O3.bM′O.cAl2O3].ySiO2, wherein R denotes an alkaline metal ion and/or hydrogen ion, M denotes a VIII Group element, rare earth element, titanium, vanadium, chromium, niobium, antimony or gallium, M′ denotes magnesium, calcium, strontium or barium, a≧0, 20>b≧0, a+c=1, 3000>y>11 or a specific porous material as a carrier and iridium or a noble metal as an active metal is present together with or covered with a second catalyst having at least one element selected from the group consisting of titanium, vanadium, tungsten and molybdenum, if necessary, as well as a method of using the same.
    • 一种氨分解催化剂,其中具有由以式表示的结晶硅酸盐的第一催化剂以氧化物的脱水摩尔比计:<?in-line-formula description =“In-line Formulas”end =“lead” (1±0.8)R 2 O 2。[aM 2 O 3] 3 .M'O.cAl 2 O &lt; 3-in-line-formula description =“In-line formula”end =“tail”?>其中R表示碱金属离子, /或氢离子,M表示VIII族元素,稀土元素,钛,钒,铬,铌,锑或镓,M'表示镁,钙,锶或钡,a> = 0,20> b> = 0 ,a + c = 1,3000> y> 11或作为载体的特定多孔材料,作为活性金属的铱或贵金属与第二催化剂一起存在或被具有至少一种选自以下的元素的第二催化剂覆盖: 的钛,钒,钨和钼,如果需要,以及使用它们的方法。
    • 20. 发明授权
    • Joining structure for electrical connection box
    • 电接线盒连接结构
    • US06710247B2
    • 2004-03-23
    • US10465621
    • 2003-06-20
    • Shigeru Nojima
    • Shigeru Nojima
    • H01R400
    • H02G3/086
    • A lock element provided on an exterior surface of a relay box engages with an engagement portion provided on an exterior surface of a junction box. A wire guide channel is provided on the junction box at a position adjacent to the relay box. A guide portion is provided on the relay box adjacent the lock element at a position corresponding to the wire guide channel, and a guide rail to be fitted into the guide portion is provided on the junction box. A wire is connected to the junction box and arranged along the wire guide channel. The guide portion of the relay box serves as a guide wall to control the direction of the wire in the wire guide channel. Breaking of the lock portions is prevented, and the direction of wire is controlled regardless of the diameter thereof.
    • 设置在继电器箱的外表面上的锁定元件与设置在接线盒的外表面上的接合部分接合。 导线通道设置在接线盒的靠近继电器箱的位置。 引导部分设置在邻近锁定元件的继电器盒上,位于对应于线引导通道的位置处,并且在接线盒上设置有装配到引导部分中的导轨。 导线连接到接线盒并沿导线通道布置。 继电器箱的引导部分用作引导壁,用于控制导线通道中导线的方向。 防止锁定部的断裂,并且不管其直径如何都控制线的方向。