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    • 13. 发明授权
    • Fluorine-containing elastomer composition and molded article comprising the same
    • 含氟弹性体组合物和包含其的模制品
    • US07659347B2
    • 2010-02-09
    • US11587573
    • 2005-04-22
    • Keiko WashinoKazuyoshi KawasakiMitsuru Kishine
    • Keiko WashinoKazuyoshi KawasakiMitsuru Kishine
    • C08F8/30
    • C08K5/0025C08K5/16C09K3/1009F16J15/102C08L27/12C08L27/16
    • The present invention provides a fluorine-containing elastomer composition excellent in heat resistance, comprising a fluorine-containing elastomer containing a vinylidene fluoride unit, which is capable of a crosslinking reaction, and a crosslinking agent. The present invention also provides a molded article, a sealing material, and a sealing material for an oxygen sensor excellent in heat resistance, which comprises the composition. The present invention is a fluorine-containing elastomer composition comprising (A) at least one compound selected form the group consisting of a compound containing at least two crosslinking reaction group s represented by the general formula (1), a compound represented by the general formula (2), a compound represented by the general formula (3) and a compound represented by the general formula (4); and (B) a fluorine-containing elastomer capable of a crosslinking reaction with the compound (A), comprising a vinylidene fluoride unit.
    • 本发明提供耐热性优异的含氟弹性体组合物,其含有能够进行交联反应的偏二氟乙烯单元的含氟弹性体和交联剂。 本发明还提供一种模制品,密封材料和用于具有优异耐热性的氧传感器的密封材料,其包含该组合物。 本发明是一种含氟弹性体组合物,其含有(A)至少一种选自由通式(1)表示的至少两个交联反应基团的化合物,由通式 (2)表示的化合物,由通式(3)表示的化合物和由通式(4)表示的化合物。 和(B)能够与化合物(A)交联反应的含氟弹性体,其包含偏二氟乙烯单元。
    • 14. 发明申请
    • Fluorine-Containing Elastomer Composition And Molded Article Comprising The Same
    • 含氟弹性体组合物和包含它的成型品
    • US20070219332A1
    • 2007-09-20
    • US11587573
    • 2005-04-22
    • Keiko WashinoKazuyoshi KawasakiMitsuru Kishine
    • Keiko WashinoKazuyoshi KawasakiMitsuru Kishine
    • C08F16/24
    • C08K5/0025C08K5/16C09K3/1009F16J15/102C08L27/12C08L27/16
    • The present invention provides a fluorine-containing elastomer composition excellent in heat resistance, comprising a fluorine-containing elastomer containing a vinylidene fluoride unit, which is capable of a crosslinking reaction, and a crosslinking agent. The present invention also provides a molded article, a sealing material, and a sealing material for an oxygen sensor excellent in heat resistance, which comprises the composition. The present invention is a fluorine-containing elastomer composition comprising (A) at least one compound selected form the group consisting of a compound containing at least two crosslinking reaction group s represented by the general formula (1), a compound represented by the general formula (2), a compound represented by the general formula (3) and a compound represented by the general formula (4); and (B) a fluorine-containing elastomer capable of a crosslinking reaction with the compound (A), comprising a vinylidene fluoride unit.
    • 本发明提供耐热性优异的含氟弹性体组合物,其含有能够进行交联反应的偏二氟乙烯单元的含氟弹性体和交联剂。 本发明还提供一种模制品,密封材料和用于具有优异耐热性的氧传感器的密封材料,其包含该组合物。 本发明是一种含氟弹性体组合物,其含有(A)至少一种选自由通式(1)表示的至少两个交联反应基团的化合物,由通式 (2)表示的化合物,由通式(3)表示的化合物和由通式(4)表示的化合物。 和(B)能够与化合物(A)交联反应的含氟弹性体,其包含偏二氟乙烯单元。
    • 19. 发明申请
    • Process for preparing vulcanizable fluorine-containing elastomer
    • 制备可硫化含氟弹性体的方法
    • US20070299207A1
    • 2007-12-27
    • US11892702
    • 2007-08-27
    • Yousuke NishimuraMasaki IrieSadashige IrieManabu FujisawaSatoshi TokunoMitsuru Kishine
    • Yousuke NishimuraMasaki IrieSadashige IrieManabu FujisawaSatoshi TokunoMitsuru Kishine
    • C08L27/14
    • C08F214/28C08F214/18C08F214/22
    • The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.
    • 本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。 本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。 该方法是在临界常数降低至少为0.95,临界常数降低至少为0.80的条件下进行的间歇共聚方法,其中降低的温度和减压是使用Peng-Robinson公式 在临界温度下,在具有下式的化合物的存在下,在反应容器中的气相中的每种单体的临界压力和组成比共聚,其中含有至少一个氟烯烃的烯键式不饱和化合物在具有下式的化合物的存在下共聚: 其中R 1是饱和或不饱和的氟代烃或其中R 1,R 2,R 3,R 4, 具有1至16个碳原子的氯氟烃基,x是R 1和...的整数1至4的整数。