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    • 11. 发明授权
    • Security sticker and method for manufacturing the same
    • 安全贴纸及其制造方法
    • US07709417B2
    • 2010-05-04
    • US10564875
    • 2004-11-12
    • Shigeo Yukawa
    • Shigeo Yukawa
    • B41M5/20B41M5/24
    • B41M5/502B32B5/12B32B7/12B32B27/08B32B27/20B32B27/30B32B27/32B32B27/36B32B27/38B32B27/40B32B2250/05B32B2250/24B32B2307/4023B32B2307/412B32B2307/518B32B2307/552B32B2307/748B32B2405/00B32B2519/00B32B2605/08G09F3/0292Y10S428/916
    • The present invention is directed to providing a security sticker which is hard to be counterfeited, cannot be reused if being released and includes a printed image that is stable over a long period of time, and is directed to providing a method for manufacturing the same. The security sticker of the present invention includes: a surface resin layer (A)1 that has a weak affinity with a sublimable dye and allows the dye to penetrate; a print layer (B)2 that contains a low-molecular-weight compound with a molecular weight of 1300 or less in an amount of 0% to 20 wt % inclusive, has an affinity with the dye, and includes an image formed in a thickness direction of the layer by the dye; a self-destructive film layer (C1)3; and a pressure-sensitive adhesive layer (D1)4 in this order, wherein the self-destructive film layer (C1) includes a dye migration preventive resin layer (E) for preventing migration of the dye and a self-destructive layer (F), and the dye migration preventive resin layer (E) is a resin layer containing a certain kind of a vinyl resin as a main component, or a certain kind of a biaxially stretched film.
    • 本发明旨在提供一种难以伪造的安全贴纸,如果被释放则不能重复使用,并且包括长时间稳定的打印图像,并且旨在提供一种制造该方法。 本发明的安全标签包括:表面树脂层(A)1,其与升华性染料具有弱亲和性并允许染料渗透; 含有分子量为1300以下的分子量为1300以下的低分子量化合物的印刷层(B)2的含量为0〜20重量%,与染料具有亲和性,并且包含形成于 染料层厚度方向; 自毁薄膜层(C1)3; 和粘合剂层(D1)4,其中自破膜层(C1)包括用于防止染料迁移的防染色剂树脂层(E)和自破坏层(F) ,并且防染色剂树脂层(E)是含有某种乙烯基树脂作为主要成分的树脂层或某种双轴向拉伸膜。
    • 12. 发明申请
    • Hue variable retroreflective sheet
    • 色相可变逆反射片
    • US20070188866A1
    • 2007-08-16
    • US10594302
    • 2005-04-22
    • Shigeo YukawaJiro Sukoboshi
    • Shigeo YukawaJiro Sukoboshi
    • G02B5/124
    • G02B5/128B32B7/02B42D25/29B42D2033/04B42D2033/18B42D2033/20B42D2035/24B44C1/105B44F1/10G02B5/26G02B5/28Y10T428/24901Y10T428/24917Y10T428/24926Y10T428/252
    • The hue variable retroreflective sheet of the present invention includes: a surface layer (1) composed of at least one layer; and a plurality of retroreflective elements (3, 4, 5) that are positioned beneath the surface layer, wherein the retroreflective elements (3, 4, 5) retroreflect incident light toward a light source direction, at least one layer of the surface layer (1) is an optical coherent layer that changes in color depending on a point of view, and in which an optical coherent coloring material with a core material having a surface that is covered with one or more substantially transparent coating layer is dispersed, and mirror-reflects the incident light toward a direction opposite to the light source side, at least one layer of the retroreflective sheet is a colored layer containing a coloring material that colors retroreflected light, and the retroreflected light and the mirror-reflected light provide different hues. Thereby, the present invention provides the hue variable retroreflective sheet that provides hues in two or more different colors by the interference of light in daylight, provides retroreflected light in color with a hue that is different from the hue in the daylight when light is projected at night, and provides a color that has still different from the hue of the retroreflected light on the other side of an incident light beam.
    • 本发明的色调可变逆反射片包括:由至少一层构成的表面层(1) 以及多个位于表面层下方的回射元件(3,4,5),其中所述回射元件(3,4,5)将入射光朝向光源方向回射,至少一层所述表面层( 1)是根据观察点而变色的光学相干层,并且其中分散具有被一个或多个基本上透明的涂层覆盖的表面的芯材料的光学相干着色材料, 将入射光朝向与光源侧相反的方向反射,至少一层回射片是包含着色材料的着色层,该着色层对后向反射光进行着色,回射光和镜面反射光提供不同的色调。 因此,本发明提供了通过光在日光下的干涉而以两种或更多种不同颜色提供色调的色相可变逆反射片,提供了颜色上的回射光,当光投射在日光下时,与日光中的色调不同的色调 并且提供与入射光束的另一侧上的回射光的色调仍然不同的颜色。
    • 13. 发明申请
    • Retroreflection sheet and outer type illumination system
    • 回射片和外部照明系统
    • US20060256439A1
    • 2006-11-16
    • US10567259
    • 2005-03-02
    • Shigeo YukawaHideyuki OkiYoshitaka Ura
    • Shigeo YukawaHideyuki OkiYoshitaka Ura
    • G02B5/126
    • G02B5/128C08J7/04C08J2367/00C08J2423/06
    • The retroreflective sheet of the present invention comprises a surface layer (1) including at least one layer, a focusing layer (2) containing glass spheres (3), and a metal reflective layer (4) on the back side of the focusing layer (2), wherein the glass spheres (3) are disposed at random locations in the thickness direction of the focusing layer (2). The external illumination system of the present invention comprises a sign having a sign face including the above-mentioned retroreflective sheet, and an external illumination source, and the distance from the illumination source to the sign face is within a range of at least 1 m and no more than 100 m. The present invention thereby provides a retroreflective sheet and an external illumination system with which wide-angle reflective performance with a wider incidence angle and observation angle can be ensured.
    • 本发明的逆反射片包括至少包含一层的表面层(1),包含玻璃球(3)的聚焦层(2)和在聚焦层背面的金属反射层(4) 2),其中所述玻璃球(3)设置在所述聚焦层(2)的厚度方向上的随机位置。 本发明的外部照明系统包括具有包括上述回射片的标志面和外部照明光源的符号,并且从照明源到符号面的距离在至少1m的范围内, 不超过100米。 因此,本发明提供了一种可以确保具有更宽的入射角和观察角度的广角反射性能的逆反射片和外部照明系统。