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    • 12. 发明授权
    • Electrode for fuel cell and fuel cell employing the electrode
    • 用于燃料电池的电极和使用电极的燃料电池
    • US08679705B2
    • 2014-03-25
    • US11765033
    • 2007-06-19
    • Hee-young SunSeong-woo ChoiTae-young Kim
    • Hee-young SunSeong-woo ChoiTae-young Kim
    • H01M4/62H01M4/86H01M4/88H01M4/92H01M8/00
    • H01M4/8663H01M4/8652H01M4/8807H01M4/8828H01M4/9008H01M4/92H01M8/0234H01M2008/1095Y02P70/56Y10T29/49115
    • An electrode for fuel cells including a catalyst layer containing a benzoxazine monomer, a catalyst and a binder, and a fuel cell employing the electrode. The electrode for the fuel cells contains an even distribution of benzoxazine monomer, which is a hydrophilic (or phosphoric acidophilic) material and dissolves in phosphoric acid but does not poison catalysts, thereby improving the wetting capability of phosphoric acid (H3PO4) within the electrodes and thus allowing phosphoric acid to permeate first into micropores in electrodes. As a result, flooding is efficiently prevented. That is, liquid phosphoric acid existing in large amount within the electrodes inhibits gas diffusion which; this flooding occurs when phosphoric acid permeates into macropores in the electrodes. This prevention of flooding increases the three-phase interfacial area of gas (fuel gas or oxidized gas)-liquid (phosphoric acid)-solid (catalyst). Therefore, the fuel cell employing the electrode can operate under conditions of high-temperature and a dry environment and demonstrate improved cell performance.
    • 包括含有苯并恶嗪单体,催化剂和粘合剂的催化剂层的燃料电池用电极和使用该电极的燃料电池。 用于燃料电池的电极含有均匀分布的苯并吩嗪单体,其为亲水性(或磷酸性)材料,并溶解于磷酸中,但不会中毒催化剂,从而提高电极内磷酸(H 3 PO 4)的润湿能力, 从而允许磷酸首先渗透到电极中的微孔中。 结果,有效地防止了淹水。 也就是说,在电极内大量存在的液体磷酸抑制气体扩散, 当磷酸渗透到电极中的大孔中时,发生这种溢流。 这种防止淹水增加了气体(燃料气体或氧化气体) - 液体(磷酸) - 固体(催化剂)的三相界面面积。 因此,使用电极的燃料电池可以在高温和干燥环境的条件下工作,并且表现出改善的电池性能。
    • 13. 发明申请
    • ELECTRODE FOR FUEL CELL AND FUEL CELL EMPLOYING THE ELECTRODE
    • 用于燃料电池的电极和使用电极的燃料电池
    • US20080020264A1
    • 2008-01-24
    • US11765033
    • 2007-06-19
    • Hee-young SUNSeong-woo ChoiTae-young Kim
    • Hee-young SUNSeong-woo ChoiTae-young Kim
    • H01M4/94H01M4/84H01M8/02H01M4/88
    • H01M4/8663H01M4/8652H01M4/8807H01M4/8828H01M4/9008H01M4/92H01M8/0234H01M2008/1095Y02P70/56Y10T29/49115
    • An electrode for fuel cells including a catalyst layer containing a benzoxazine monomer, a catalyst and a binder, and a fuel cell employing the electrode. The electrode for the fuel cells contains an even distribution of benzoxazine monomer, which is a hydrophilic (or phosphoric acidophilic) material and dissolves in phosphoric acid but does not poison catalysts, thereby improving the wetting capability of phosphoric acid (H3PO4) within the electrodes and thus allowing phosphoric acid to permeate first into micropores in electrodes. As a result, flooding is efficiently prevented. That is, liquid phosphoric acid existing in large amount within the electrodes inhibits gas diffusion which; this flooding occurs when phosphoric acid permeates into macropores in the electrodes. This prevention of flooding increases the three-phase interfacial area of gas (fuel gas or oxidized gas)-liquid (phosphoric acid)-solid (catalyst). Therefore, the fuel cell employing the electrode can operate under conditions of high-temperature and a dry environment and demonstrate improved cell performance.
    • 包括含有苯并恶嗪单体,催化剂和粘合剂的催化剂层的燃料电池用电极和使用该电极的燃料电池。 用于燃料电池的电极含有均匀分布的苯并吩嗪单体,其为亲水性(或磷酸性)材料,并溶解于磷酸中,但不会中毒催化剂,从而提高电极内磷酸(H 3 PO 4)的润湿能力, 从而允许磷酸首先渗透到电极中的微孔中。 结果,有效地防止了淹水。 也就是说,在电极内大量存在的液体磷酸抑制气体扩散, 当磷酸渗透到电极中的大孔中时,发生这种溢流。 这种防止淹水增加了气体(燃料气体或氧化气体) - 液体(磷酸) - 固体(催化剂)的三相界面面积。 因此,使用电极的燃料电池可以在高温和干燥环境的条件下工作,并且表现出改善的电池性能。