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    • 16. 发明授权
    • Cross-linked polyphosphonate-sulfone composition for removal of metal ions from wastewater
    • 用于从废水中去除金属离子的交联聚膦酸盐 - 砜组合物
    • US08871822B2
    • 2014-10-28
    • US13652466
    • 2012-10-15
    • King Fahd University of Petroleum and Minerals
    • Shaikh Asrof AliOthman Charles Sadeq Othman Al Hamouz
    • C08J11/04
    • C08G75/20
    • The cross-linked polyphosphonate-sulfone composition for removal of metal ions from wastewater relates to a cross-linked anionic polyelectrolyte polymer for the removal of metal ions, such as lead (Pb2+) and copper (Cu2+) ions, from wastewater and the like. The cross-linked anionic polyelectrolyte polymer has the formula: The cross-linked anionic polyelectrolyte polymer is made by cyclopolymerization of diallylaminomethylphosphonic acid, 1,1,4,4-tetraallylpiperazinium dichloride (a cross-linker), and sulfur dioxide in the presence of AIBN (an initiator) in DMSO at 65° C. to form a cross-linked polyzwitterionic acid (CPZA). The CPZA is then treated with base (such as sodium hydroxide) to form the cross-linked anionic polyelectrolyte polymer having the formula shown above.
    • 用于从废水中去除金属离子的交联聚膦酸酯 - 砜组合物涉及用于从废水等中除去金属离子如铅(Pb2 +)和铜(Cu2 +)离子的交联阴离子聚电解质聚合物。 交联阴离子聚电解质聚合物具有下式:交联的阴离子聚电解质聚合物通过二烯丙基氨基甲基膦酸,1,1,4,4-四烯丙基哌嗪二氯化物(交联剂)和二氧化硫的环化聚合制备, AIBN(引发剂)在DMSO中在65℃下反应以形成交联的聚两性酸(CPZA)。 然后用碱(如氢氧化钠)处理CPZA以形成具有上述结构的交联阴离子聚电解质聚合物。