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    • 14. 发明授权
    • Polylactic acid resin composition, process for producing the same, biaxially stretched polylactic acid film, and molded articles thereof
    • 聚乳酸树脂组合物,其制造方法,双轴拉伸聚乳酸薄膜及其成型体
    • US07718718B2
    • 2010-05-18
    • US10550666
    • 2004-02-10
    • Takeshi KanzawaSakayuki KobayashiMinoru YoshidaFumie SakidaJiro Kumaki
    • Takeshi KanzawaSakayuki KobayashiMinoru YoshidaFumie SakidaJiro Kumaki
    • C09D101/18
    • C08L67/04C08J5/18C08J2367/04C08L1/10C08L25/18C08L33/08C08L33/10C08L2666/26C08L2666/06C08L2666/04
    • A resin composition contains poly(lactic acid) and a cellulosic ester, a resin composition excellent in transparency, mechanical properties, and thermostability; a biaxially drawn film containing poly(lactic acid) and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60° C. or higher; and a biaxially drawn film excellent in transparency, mechanical properties, and thermostability. The resin composition is obtained by melt-kneading a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and a cellulosic ester; a resin composition excellent in transparency and having luminous transmittance of 40% or higher for visible light with 400 nm; a molded article and a film made of the resin composition; a poly(lactic acid) biaxially drawn film containing a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60° C. or higher; a poly(lactic acid) biaxially drawn film excellent in transparency and having film haze of 10% or lower.
    • 树脂组合物含有聚(乳酸)和纤维素酯,透明性,机械性能和热稳定性优异的树脂组合物; 含有聚(乳酸)和至少一种选自纤维素酯,聚(甲基)丙烯酸酯和玻璃化转变温度为60℃以上的聚乙烯基化合物的化合物的双轴拉伸膜; 以及透明性,机械性能和热稳定性优异的双轴拉伸膜。 树脂组合物通过熔融捏合重均分子量为50,000以上的聚(乳酸)聚合物和纤维素酯而得到; 对于400nm的可见光,透明性优异,透光率为40%以上的树脂组合物; 模塑制品和由该树脂组合物制成的薄膜; 含有重均分子量为50,000以上的聚(乳酸)聚合物的聚(乳酸)双轴拉伸膜和至少一种选自纤维素酯,聚(甲基)丙烯酸酯和具有玻璃化转变的聚乙烯基化合物的化合物 温度为60℃以上; 具有透明性优异且膜雾度为10%以下的聚(乳酸)双轴拉伸膜。
    • 16. 发明授权
    • Polyamide resin composition and forming from the same
    • 聚酰胺树脂组合物及其形成
    • US06617381B1
    • 2003-09-09
    • US09034817
    • 1998-03-04
    • Jiro KumakiMitsunari SotokawaKouzou MurataKoya Kato
    • Jiro KumakiMitsunari SotokawaKouzou MurataKoya Kato
    • C08K51539
    • C08K7/04C08K9/08C08L77/00
    • Disclosed is a polyamide resin composition, a method for producing the composition, and articles from the composition. The polyamide resin composition polyamide resin composition is formed by melt-kneading (A) 100 parts by weight of nylon resin, and (B) 5-150 parts by weight of at least one of a non-fibrous inorganic filler having an average particle diameter of 0.05-10 &mgr;m and a fibrous inorganic filler, excluding glass fiber, having a fiber diameter of 0.05-10 &mgr;m. In the polyamide resin composition, an amount of a polyamide resin component deposit remaining on the inorganic filler when the inorganic filler is recovered by dissolving the polyamide resin composition into hexafluoroisopropanol is at least 4 g/m2 per unit surface area of the inorganic filler measured by a BET method. The nylon resin composition is excellent in rigidity and toughness and particularly excellent in high-speed surface impact fracture characteristic. The resin composition also achieve excellent surface external appearance and excellent dimensional stability in good balance in a formed article. The resin composition can suitably be formed by injection forming, extrusion, blow forming and the like, into various vehicular exterior parts, under-hood formed parts for motor vehicles, portable device casings and the like.
    • 公开了一种聚酰胺树脂组合物,该组合物的制造方法和该组合物的制品。 聚酰胺树脂组合物聚酰胺树脂组合物通过将(A)熔融捏合(A)100重量份的尼龙树脂和(B)5-150重量份的至少一种平均粒径的非纤维无机填料 0.05-10μm的纤维直径为0.05-10μm的纤维状无机填料,不包括玻璃纤维。 在聚酰胺树脂组合物中,当通过将聚酰胺树脂组合物溶解到六氟异丙醇中回收无机填料时残留在无机填料上的聚酰胺树脂组分沉积物的量为无机填料的每单位表面积至少为4g / m 2 BET方法。 尼龙树脂组合物的刚性和韧性优异,特别优异的是高速表面冲击断裂特性。 树脂组合物还可以在成型制品中获得优异的表面外观和良好的尺寸稳定性。 树脂组合物可以适当地通过注射成型,挤出,吹塑成型等形成各种车辆外部部件,用于机动车辆的发动机罩下部形成部件,便携式装置壳体等。