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    • 15. 发明授权
    • Low loss glass and optical fibers therefrom
    • 低损玻璃和光纤
    • US5305414A
    • 1994-04-19
    • US923450
    • 1992-08-03
    • Paige L. HigbyIshwar D. AggarwalEdward J. Friebele
    • Paige L. HigbyIshwar D. AggarwalEdward J. Friebele
    • C03C3/253C03C13/04G02B6/02G02B6/10G02B5/14
    • G02B6/102C03C13/048C03C3/253G02B6/02
    • Optical fibers and glass composition comprising a mixture of barium oxide, gallium oxide, germanium oxide, and a modifying agent selected from lanthium oxide, indium oxide, and mixtures thereof; molar ratio of barium oxide to gallium oxide is from about 4:1 to about 1:1, preferably 2:1 to 1, and especially about 1:1; amount of germanium oxide is at least 40 mole percent, preferably 60 to 95 mole percent, and especially 65 to 90 mole percent; about 0.1 to about 5 mole percent, preferably 0.5 to 4, of gallium oxide is replaced with the modifying agent. The optical fibers made from the glass composition defined herein, with or without the modifying agent, have light transmission wavelength band of about 0.3 to 4 microns; lower optical loss than silica-based optical fibers, the minimum optical loss of the novel fibers having the potential of 0.05 dB/km at 2 microns.
    • 包含氧化钡,氧化镓,氧化锗和选自氧化铟,氧化铟及其混合物的改性剂的混合物的光纤和玻璃组合物; 氧化钡与氧化镓的摩尔比为约4:1至约1:1,优选2:1至1,特别是约1:1; 氧化锗的量为至少40摩尔%,优选为60〜95摩尔%,特别优选为65〜90摩尔%。 约0.1至约5摩尔%,优选0.5至4的氧化镓被改性剂代替。 由本文定义的玻璃组合物制成的具有或不具有改性剂的光纤具有约0.3至4微米的透光波长带; 比二氧化硅基光纤更低的光损耗,在2微米处具有0.05dB / km的电位的新型光纤的最小光损耗。