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    • 16. 发明授权
    • Charge imbalanced polyelectrolyte composition
    • 电荷不平衡聚电解质组成
    • US5208295A
    • 1993-05-04
    • US796996
    • 1991-11-25
    • Ratan K. ChaudhuriRobert B. LoginLowell R. AndersonMohammed Tazi
    • Ratan K. ChaudhuriRobert B. LoginLowell R. AndersonMohammed Tazi
    • C08F8/12
    • C08F8/12C08F2810/50
    • A charge imbalanced composition comprising:(a) about 10 to 90 mole % of an amphoteric copolymer having the formula ##STR1## where R=alkyl C.sub.1 -C.sub.4,N=1-6,R.sub.1 and R.sub.2 are independently alkyl C.sub.1 -C.sub.6, andR.sub.3 is H,(b) about 10 to 90 mole % of a polymeric diacid having the formula: ##STR2## where R is as defined above, and(c) less than about 8 mole % of by-product salts which are the dialkylaminoalkylamine salts of (a) and (b).The composition described above is made by:reacting 1 mole of an anhydride compound having the formula ##STR3## where R is as defined above,with less than 1 mole of a compound having the formula ##STR4## where n, R.sub.1 and R.sub.2 are as defined above, and R.sub.3 is H, isolating the product, andhydrolyzing any residual anhydride compound in water to the corresponding diacid compound.
    • 一种电荷不平衡组合物,其包含:(a)约10至90摩尔%的具有式“IMAGE”的两性共聚物,其中R =烷基C1-C4,N = 1-6,R1和R2独立地为C1-C6烷基,和 R 3是H,(b)约10至90摩尔%的具有下式的聚合二酸:其中R如上定义,和(c)少于约8摩尔%的副产物盐,其是二烷基氨基烷基胺 (a)和(b)的盐。 上述组合物通过以下方法制备:使1摩尔具有式“IMAGE”的酸酐化合物(其中R如上所定义)与少于1摩尔具有式“IMAGE”的化合物反应,其中n,R1和R2为 并且R3是H,分离产物,并将水中的任何残留的酸酐化合物水解成相应的二酸化合物。
    • 19. 发明授权
    • Process for making ethanol solutions of alkyl half-esters of copolymers
of maleic anhydride and a C.sub.1 -C.sub.4 alkyl vinyl ether
    • 制备马来酸酐和C 1 -C 4烷基乙烯基醚共聚物的烷基半酯的乙醇溶液的方法
    • US5064897A
    • 1991-11-12
    • US574843
    • 1990-08-30
    • Mohammed TaziRobert B. Login
    • Mohammed TaziRobert B. Login
    • C08F216/18C08F2/00C08F16/16C08F20/02C08F222/06C08J3/09C08L29/10
    • C08J3/09C08J2335/08
    • What is described herein is a process for making ethanol solutions of alkyl half-esters of copolymers of maleic anhydride and a C.sub.1 -C.sub.4 alkyl vinyl ether which are benzene and acetone-free. The invention is characterized by (a) precharging a reactor with excess C.sub.1 -C.sub.4 alkyl vinyl ether as both monomer reactant and solvent, and a free radical polymerization initiator, at a reaction temperature; (b) feeding the alkyl half-ester of maleic anhydride formed by reaction of substantially one mole of maleic anhydride and substantially one mole of alkanol into the precharged reactor to form the desired alkyl half-ester of the alternating copolymer of maleic anhydride and the C.sub.1 -C.sub.4 alkyl vinyl ether in excess alkyl vinyl ether as solvent; (c) cooling the reactor to room temperature; and (d) introducing ethanol solvent into the reactor and removing excess alkyl vinyl ether to form the desired half-ester copolymer in ethanol solution.
    • 本文描述的是制备马来酸酐和不含丙酮的C 1 -C 4烷基乙烯基醚的共聚物的烷基半酯的乙醇溶液的方法。 本发明的特征在于(a)在反应温度下,用过量的C 1 -C 4烷基乙烯基醚作为单体反应物和溶剂以及自由基聚合引发剂预充电反应器; (b)通过将基本上1摩尔马来酸酐和基本上1摩尔的链烷醇反应形成的马来酸酐的烷基半酯进料到预充电的反应器中以形成马来酸酐与C1的交替共聚物的所需烷基半酯 -C 4烷基乙烯基醚,过量的烷基乙烯基醚作为溶剂; (c)将反应器冷却至室温; 和(d)将乙醇溶剂引入反应器并除去过量的烷基乙烯基醚以在乙醇溶液中形成所需的半酯共聚物。