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11. 发明授权

US4385001A Selective reduction of edible oils 失效
标题翻译：食用油的选择性还原
公开(公告)号：US4385001A
公开(公告)日：1983-05-24
申请号：US274913
申请日：1981-06-18
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C11C3/12
CPC分类号： C11C3/126
摘要： Edible oils may be selectively hydrogenated using a zerovalent, supported, catalytically active cobalt catalyst. Where the cobalt is supported on alumina, the selectivity of hydrogenation is virtually independent of the nature of the alumina. The process is sufficiently selective that continuous hydrogenation may be performed with about the same selectivity as that presently obtained in batch processes using presently conventional catalysts.
摘要翻译：食用油可以使用零价，负载的，催化活性的钴催化剂选择性氢化。当钴负载在氧化铝上时，氢化的选择性实际上与氧化铝的性质无关。该方法具有足够的选择性，可以以与目前常规催化剂的分批方法中获得的当量相同的选择性进行连续氢化。

12. 发明授权

US08242048B2 Oxidation catalyst and its preparation 有权
标题翻译：氧化催化剂及其制备方法
公开(公告)号：US08242048B2
公开(公告)日：2012-08-14
申请号：US12585984
申请日：2009-09-30
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： B01J23/52 , B01J23/22 , B01J35/08
CPC分类号： C07C51/25 , B01J21/04 , B01J23/002 , B01J23/56 , B01J23/6525 , B01J23/686 , B01J35/0026 , B01J35/10 , B01J35/1009 , B01J37/0045 , B01J2523/00 , C07C5/3332 , C07C51/215 , C07C2521/04 , C07C2523/68 , Y02P20/52 , C07C53/08 , B01J2523/19 , B01J2523/55 , B01J2523/56 , B01J2523/68 , C07C11/04
摘要： Process for the selective oxidation of ethane to ethylene and/or acetic acid, and/or the selective oxidation of ethylene to acetic acid, by contacting ethane and/or ethylene with a molecular oxygen-containing gas at elevated temperature in the presence of a spray-dried supported catalyst composition. The supported catalyst composition includes molybdenum, vanadium and niobium metal components, supported on a support comprising alpha-alumina. The supported catalyst is prepared by forming a slurry of the metal components and alpha-alumina support particles or an alpha-alumina support precursor, and spray-drying the slurry.
摘要翻译：通过使乙烷和/或乙烯与含分子氧的气体在升高的温度下在喷雾存在下接触将乙烷选择性氧化成乙烯和/或乙酸，和/或将乙烯选择性氧化成乙酸的方法 - 负载型催化剂组合物。负载的催化剂组合物包括负载在包含α-氧化铝的载体上的钼，钒和铌金属组分。通过形成金属组分和α-氧化铝载体颗粒或α-氧化铝载体前体的浆料并喷雾干燥浆料来制备负载型催化剂。

13. 发明申请

US20090292139A1 Catalyst composition and use thereof in ethane oxidation 失效
标题翻译：催化剂组成及其在乙烷氧化中的应用
公开(公告)号：US20090292139A1
公开(公告)日：2009-11-26
申请号：US12461050
申请日：2009-07-30
申请人： James Frank Brazdil , Richard J. George , Bruce I. Rosen
发明人： James Frank Brazdil , Richard J. George , Bruce I. Rosen
IPC分类号： C07C53/08
CPC分类号： B01J23/002 , B01J23/14 , B01J23/20 , B01J23/28 , B01J23/30 , B01J37/0045 , B01J37/0236 , B01J2523/00 , C07C5/48 , C07C51/215 , C07C51/25 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/14 , C07C2523/20 , C07C2523/22 , C07C2523/28 , C07C2523/30 , Y02P20/52 , C07C11/04 , C07C53/08 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/43 , B01J2523/41 , B01J2523/47
摘要： A catalyst composition and its use for the oxidation of ethane to ethylene and acetic acid which comprises (i) a support, and (ii) in combination with oxygen, the elements molybdenum, vanadium and niobium, optionally tungsten and a component Z, which is one or more metals of Group 14 of the Periodic Table of Elements; a, b, c, d and e represent the gram atom ratios of the elements Mo, W, Z, V and Nb respectively, such that 0
摘要翻译：催化剂组合物及其用于将乙烷氧化成乙烯和乙酸的用途，其包括（i）载体，和（ii）与氧组合，元素钼，钒和铌，任选的钨和组分Z，其是元素周期表第14族的一种或多种金属; a，b，c，d和e分别表示元素Mo，W，Z，V和Nb的克原子比，使得0

14. 发明授权

US06461700B2 Aromatic acid monomers, polymers, products and processes for their manufacture 有权
标题翻译：芳香族酸单体，聚合物，产品及其制造方法
公开(公告)号：US06461700B2
公开(公告)日：2002-10-08
申请号：US09935458
申请日：2001-08-23
申请人： Edward E. Paschke , Bruce I. Rosen , David A. Peterson , David E. James , Melvin L. Luetkens, Jr. , Charles W Bauer , Gary T. Brooks
发明人： Edward E. Paschke , Bruce I. Rosen , David A. Peterson , David E. James , Melvin L. Luetkens, Jr. , Charles W Bauer , Gary T. Brooks
IPC分类号： B29D2200
CPC分类号： C08G63/189 , C07C51/265 , C07C51/42 , C07C63/38 , Y10T428/1352 , Y10T428/29 , Y10T428/2913
摘要： Processes for producing aromatic monomers useful for forming polyesters are disclosed. Cost effective steps employed in the processes permit small amounts of process-related materials typically removed from monomer to remain in an aromatic monomer product. In many cases, the presence of the process-related materials left in the monomer product by the cost effective process steps can enhance the performance of the monomer in certain applications. Aromatic monomer products and polymers produced therefrom having these advantages also are disclosed, as well as products such as pasteurizable bottles made from these polymers
摘要翻译：公开了用于制备用于形成聚酯的芳族单体的方法。在该方法中使用的成本有效的步骤允许通常从单体中除去残留在芳族单体产物中的少量与工艺相关的材料。在许多情况下，通过成本有效的工艺步骤留在单体产品中的工艺相关材料的存在可以在某些应用中提高单体的性能。还公开了具有这些优点的芳族单体产物和由其制备的聚合物，以及由这些聚合物制成的诸如可巴氏消毒瓶的产品

15. 发明授权

US5756833A Catalytic purification and recovery of dicarboxylic aromatic acids 失效
标题翻译：催化净化和回收二羧酸芳香酸
公开(公告)号：US5756833A
公开(公告)日：1998-05-26
申请号：US778297
申请日：1997-01-02
申请人： Bruce I. Rosen , Thomas M. Bartos
发明人： Bruce I. Rosen , Thomas M. Bartos
IPC分类号： C07C51/487 , C07C51/42
CPC分类号： C07C51/487
摘要： Processes using a titanium dioxide-supported purification catalyst are disclosed for purification of relatively impure dicarboxylic aromatic acid produced by liquid-phase oxidation of a suitable benzene or naphthalene having two oxidizable ring substituents, and/or by recovery from polyester resin comprising repeating units of the dicarboxylic aromatic acid residue and repeating units of dihydric alcohol residue. Purification comprises passing an aqueous solution of dicarboxylic aromatic acid with small amounts of organic impurities consisting of oxygen-containing aromatic co-products of oxidation and/or other organic components, through a particulate bed of purification catalyst comprising a noble metal on a titanium dioxide support under conditions suitable for decarbonylation of organic impurities. Generally, at least one weight percent of the titanium dioxide support is in the rutile crystalline phase. Optionally, effluent aqueous solution from the bed containing noble metal on the titanium dioxide support is passed through a subsequent particulate bed of another purification catalyst in the presence of a molecular hydrogen-containing gas. Hydrogenation of the aqueous solution subsequent to decarbonylation further reduces organic impurities in dicarboxylic aromatic acid recovered by crystallization and separation from the aqueous solution. The invention provides improved processes for preparation of purified terephthalic acid wherein purified terephthalic acid product is recovered from its mother liquor while maintaining temperatures within a range downward from about 100.degree. C. to about 25.degree. C. and pressures near or at atmospheric pressure.
摘要翻译：公开了使用二氧化钛负载的净化催化剂的方法，用于纯化通过液相氧化合适的苯或具有两个可氧化环取代基的萘产生的相对不纯的二羧酸芳族化合物，和/或通过从包含重复单元的聚酯树脂二羧酸残基和二元醇残基的重复单元。纯化包括将二氧化碳芳族酸的水溶液与少量由氧化和/或其它有机组分的含氧芳族共同产物组成的有机杂质通过二氧化钛载体上含有贵金属的净化催化剂颗粒床在适合有机杂质脱羰作用的条件下。通常，至少一重量百分比的二氧化钛载体是金红石结晶相。任选地，在含有分子含氢气体的存在下，将含有二氧化钛载体上的贵金属的床的流出水溶液通过另一种纯化催化剂的随后的颗粒床。脱羰后的水溶液的氢化进一步降低了通过结晶回收的二羧酸芳族化合物中的有机杂质，并从水溶液中分离出来。本发明提供了制备纯化对苯二甲酸的改进方法，其中从其母液中回收纯化的对苯二甲酸产物，同时将温度保持在约100℃至约25℃的范围内，接近或在大气压下的压力。

16. 发明授权

US5159109A Purification of organic polycarboxylic acids 失效
标题翻译：有机多元羧酸的纯化
公开(公告)号：US5159109A
公开(公告)日：1992-10-27
申请号：US657451
申请日：1991-02-19
申请人： Bruce I. Rosen , David A. Peterson
发明人： Bruce I. Rosen , David A. Peterson
IPC分类号： C07C51/43 , C07C51/44
CPC分类号： C07C51/43 , C07C51/445
摘要： There is provided a method for purifying an organic polycarboxylic acid wherein the amounts of organic monofunctional impurities associated therewith are substantially reduced, which method comprises conducting steam distillation of a stream comprising said polycarboxylic acid. In one embodiment of the method, a reactor effluent comprising a polycarboxylic acid is introduced into a crystallization zone, said effluent being subjected to crystallization and steam distillation coextensively in said crystallization zone.The method of the present invention may be used suitably to purify 1,4-cyclohexanedicarboxylic acid in a reactor effluent from the hydrogenation of a terephthalic acid by reducing the amounts of 4-methyl-1-cyclohexanecarboxylic acid and cyclohexanecarboxylic acid, as well as other organic impurities, contaminating the dicarboxylic acid.There is also provided the polycarboxylic acid purified by the method of the present invention.
摘要翻译：提供了一种纯化有机多元羧酸的方法，其中与其相关的有机单官能杂质的量显着降低，该方法包括对包含所述多元羧酸的物流进行蒸汽蒸馏。在该方法的一个实施方案中，将包含多元羧酸的反应器流出物引入结晶区，所述流出物在所述结晶区中共同进行结晶和蒸汽蒸馏。本发明的方法可以适当地用于通过减少4-甲基-1-环己烷羧酸和环己烷羧酸的量以及其它的方法从对苯二甲酸氢化的反应器流出物中纯化1,4-环己烷二羧酸有机杂质，污染二羧酸。还提供了通过本发明的方法纯化的多元羧酸。

17. 发明授权

US4479902A Selective reduction of edible fats and oils; platinum and palladium on titania 失效
标题翻译：选择性还原食用油脂; 铂和钯二氧化钛
公开(公告)号：US4479902A
公开(公告)日：1984-10-30
申请号：US404724
申请日：1982-08-03
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C11C3/12
CPC分类号： C11C3/126
摘要： Selective reductions of fatty materials occur using a catalyst comprising zerovalent platinum or palladium dispersed on a support which shows strong metal-support interaction. A particularly desirable catalyst is one where the platinum or palladium is dispersed on titania which is subsequently activated in hydrogen at a temperature above about 325.degree. C. The catalyst is sufficiently selective so as to permit continuous reduction of fatty material using a fixed bed of catalyst.
摘要翻译：脂肪材料的选择性还原使用分散在显示强金属 - 载体相互作用的载体上的包含零价铂或钯的催化剂进行。特别理想的催化剂是将铂或钯分散在二氧化钛上的催化剂，二氧化钛随后在氢气中在约325℃以上的温度下活化。催化剂具有足够的选择性，以允许使用固定床催化剂连续还原脂肪材料。

18. 发明申请

US20110009666A1 Oxidation catalyst and its preparation 有权
标题翻译：氧化催化剂及其制备方法
公开(公告)号：US20110009666A1
公开(公告)日：2011-01-13
申请号：US12585984
申请日：2009-09-30
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C07C51/25 , C07C51/215 , C07C5/00
CPC分类号： C07C51/25 , B01J21/04 , B01J23/002 , B01J23/56 , B01J23/6525 , B01J23/686 , B01J35/0026 , B01J35/10 , B01J35/1009 , B01J37/0045 , B01J2523/00 , C07C5/3332 , C07C51/215 , C07C2521/04 , C07C2523/68 , Y02P20/52 , C07C53/08 , B01J2523/19 , B01J2523/55 , B01J2523/56 , B01J2523/68 , C07C11/04
摘要： Process for the selective oxidation of ethane to ethylene and/or acetic acid, and/or the selective oxidation of ethylene to acetic acid, by contacting ethane and/or ethylene with a molecular oxygen-containing gas at elevated temperature in the presence of a spray-dried supported catalyst composition. The supported catalyst composition includes molybdenum, vanadium and niobium metal components, supported on a support comprising alpha-alumina. The supported catalyst is prepared by forming a slurry of the metal components and alpha-alumina support particles or an alpha-alumina support precursor, and spray-drying the slurry.
摘要翻译：通过使乙烷和/或乙烯与含分子氧的气体在升高的温度下在喷雾存在下接触将乙烷选择性氧化成乙烯和/或乙酸，和/或将乙烯选择性氧化成乙酸的方法 - 负载型催化剂组合物。负载的催化剂组合物包括负载在包含α-氧化铝的载体上的钼，钒和铌金属组分。通过形成金属组分和α-氧化铝载体颗粒或α-氧化铝载体前体的浆料并喷雾干燥浆料来制备负载型催化剂。

19. 发明申请

US20100094047A1 Catalyst composition and process for the selective oxidation of ethane and/or ethylene to acetic acid 有权
标题翻译：用于将乙烷和/或乙烯选择性氧化成乙酸的催化剂组合物和方法
公开(公告)号：US20100094047A1
公开(公告)日：2010-04-15
申请号：US12654113
申请日：2009-12-10
申请人： James Frank Brazdil , Richard J. George , Bruce I. Rosen
发明人： James Frank Brazdil , Richard J. George , Bruce I. Rosen
IPC分类号： C07C51/21 , C07C51/25 , C07C51/215
CPC分类号： B01J21/06 , B01J21/063 , B01J23/002 , B01J23/20 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/686 , B01J37/0045 , B01J37/0236 , B01J2523/00 , C07C51/215 , C07C51/25 , C07C53/08 , B01J2523/19 , B01J2523/47 , B01J2523/55 , B01J2523/56 , B01J2523/68
摘要： An oxide catalyst composition comprising the elements molybdenum, vanadium, niobium and titanium and a process for making the catalyst composition. A process for the selective oxidation of ethane and/or ethylene to acetic acid using the catalyst composition. The catalyst composition provides high selectivity to acetic acid with reduced selectivity to ethylene.
摘要翻译：包含元素钼，钒，铌和钛的氧化物催化剂组合物和制备催化剂组合物的方法。使用催化剂组合物将乙烷和/或乙烯选择性氧化成乙酸的方法。催化剂组合物对乙酸具有较高的选择性，同时乙烯的选择性降低。

20. 发明申请

US20090005586A1 MIXED METAL OXIDE CATALYSTS FOR THE AMMOXIDATION OF PROPANE AND ISOBUTANE 审中-公开
标题翻译：用于丙酮和异丁酸脱氧的混合金属氧化物催化剂
公开(公告)号：US20090005586A1
公开(公告)日：2009-01-01
申请号：US11771278
申请日：2007-06-29
申请人： James F. Brazdil, JR. , Bruce I. Rosen , Eric Moore , Joseph P. Bartek , Claus Lugmair , Benjamin Mork
发明人： James F. Brazdil, JR. , Bruce I. Rosen , Eric Moore , Joseph P. Bartek , Claus Lugmair , Benjamin Mork
IPC分类号： C07C253/24 , B01J21/08 , B01J23/10 , B01J27/057
CPC分类号： C07C253/24 , B01J23/002 , B01J23/30 , B01J37/10 , B01J2523/00 , Y02P20/52 , C07C255/08 , B01J2523/3725 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： A catalyst composition comprising molybdenum, vanadium, and antimony, and at least one other element selected from the group consisting of praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation).
摘要翻译：包含钼，钒和锑的催化剂组合物以及选自镨，钕，钐，铕，钆，铽，镝，钬，铒，ium，镱和镥中的至少一种其它元素。这种催化剂组合物可有效地将丙烷气相转化为丙烯腈和异丁烷至甲基丙烯腈（通过氨氧化）。

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