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    • 14. 发明授权
    • Quantitative transient analysis of localized corrosion
    • 局部腐蚀的定量瞬态分析
    • US07713405B2
    • 2010-05-11
    • US12116003
    • 2008-05-06
    • Vladimir JovancicevicCarlos M. MenendezPaul HammondsWai Yeung Mok
    • Vladimir JovancicevicCarlos M. MenendezPaul HammondsWai Yeung Mok
    • G01N17/04
    • G01N17/02
    • An electrochemical noise method, apparatus and system may be used to estimate and/or calculate parameters of interest related to corrosion rates of an electrically conductive article. The apparatus involves a working electrode (having substantially the same composition of the electrically conductive article), a reference electrode, and a counter electrode in an environment of interest. The working electrode is placed under potentiostatic control. A current transient between the working electrode and the counter electrode is measured. The working electrode is switched to open potential. A potential transient is measured over the duration of a localized corrosion event. The localized corrosion may then be calculated based on the measured potential transient and the current transient.
    • 可以使用电化学噪声方法,装置和系统来估计和/或计算与导电制品的腐蚀速率相关的感兴趣参数。 该设备包括在感兴趣的环境中的工作电极(具有基本相同的导电制品组成),参考电极和对电极。 工作电极置于恒电位控制下。 测量工作电极和对电极之间的电流瞬变。 工作电极切换到开放电位。 在局部腐蚀事件的持续时间内测量潜在的瞬态。 然后可以基于测量的电位瞬变和电流瞬态来计算局部腐蚀。
    • 15. 发明授权
    • Quantitative, real time measurements of localized corrosion events
    • 局部腐蚀事件的定量,实时测量
    • US07686938B2
    • 2010-03-30
    • US11262861
    • 2005-10-31
    • Raymond Paul GillVladimir JovancicevicWai Yeung MokPaul Hammonds
    • Raymond Paul GillVladimir JovancicevicWai Yeung MokPaul Hammonds
    • G01N17/04
    • G01N17/02
    • An electrochemical noise method, apparatus and system calculates parameters of interest related to corrosion rates of an electrically conductive article. The method involves placing a test electrode, a reference electrode, and an auxiliary electrode in an environment of interest; placing the test electrode under potentiostatic control regime for a potential scan; measuring the relationship of current v. potential (polarization resistance, Rp) of the test electrode relative to the reference electrode during a first period; switching from potentiostatic control to the open circuit potential (OCP) of the test electrode; monitoring the OCP of the test electrode during a second period; determining ΔI from the relationship Rp=ΔV/ΔI, where ΔV is measured over a second period of time; and calculating the localized corrosion from the measured potential and current data.
    • 电化学噪声方法,装置和系统计算与导电制品的腐蚀速率有关的参数。 该方法包括在感兴趣的环境中放置测试电极,参考电极和辅助电极; 将测试电极置于恒电位控制方案下进行电位扫描; 测量在第一周期期间测试电极相对于参考电极的电流v电位(极化电阻Rp)的关系; 从恒电位控制切换到测试电极的开路电位(OCP); 在第二期间监测测试电极的OCP; 根据关系Rp =&Dgr; V /&Dgr; I,其中&Dgr; V在第二时间段内测量并确定Dgr; I; 并从测量的电位和当前数据计算局部腐蚀。
    • 18. 发明授权
    • Scale prediction probe
    • 缩放预测探测器
    • US06792796B2
    • 2004-09-21
    • US09754792
    • 2001-01-03
    • Paul Hammonds
    • Paul Hammonds
    • G01N1700
    • E21B37/06E21B47/00
    • A method for predicting scale deposition in a general environment has been discovered which involves providing a localized environment where scale would preferentially form, where the localized environment is adjacent the general environment. Monitoring the deposition of scale in the localized environment is performed for the purpose of taking preemptive action to prevent scale deposition in the general environment once scale begins to form, or a certain threshold is reached. Scale is removed from the localized environment so that monitoring can be performed by the probe again. Preemptive action will often be the introduction of a scale inhibiting agent into the general environment. An apparatus for practicing the method of predicting and preventing scale deposition in a general environment is also described.
    • 已经发现了一种用于在一般环境中预测尺度沉积的方法,其涉及提供局部化环境,其中优先形成尺度,其中局部环境与一般环境相邻。 在局部环境中监测刻度的沉积是为了采取先发制人的动作,以防止一旦刻度开始形成,或达到一定的阈值,在一般环境中的刻度沉积。 缩放从本地化环境中移除,以便再次由探测器执行监视。 先发制人的行为往往是在一般环境中引入阻垢剂。 还描述了在一般环境中实施预测和防止垢沉积的方法的装置。