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11. 发明授权

US5959047A 3-aryl substituted indenyl containing metal complexes and polymerization process 失效
标题翻译： 3-芳基取代茚基含金属络合物和聚合方法
公开(公告)号：US5959047A
公开(公告)日：1999-09-28
申请号：US105402
申请日：1998-06-26
申请人： Peter N. Nickias , Jasson T. Patton
发明人： Peter N. Nickias , Jasson T. Patton
IPC分类号： C08F4/643 , C07F7/00 , C07F7/10 , C07F7/28 , C07F17/00 , C08F4/44 , C08F4/64 , C08F4/645 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/02 , C08F210/16 , C08F212/08
CPC分类号： C07F17/00 , C07F7/10 , C08F10/00 , C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： Group 4 metal constrained geometry complexes comprising a 3-aryl-substituted indenyl ligand, catalytic derivatives thereof and their use as olefin polymerization catalysts, especially for preparing interpolymers comprising ethylene and a monovinyl aromatic monomer are disclosed.
摘要翻译：公开了包含3-芳基取代的茚基配体，其催化衍生物和它们作为烯烃聚合催化剂的用途的第4族金属约束几何络合物，特别是用于制备包含乙烯和单乙烯基芳族单体的互聚物。

12. 发明申请

US20130047843A1 Metal Organic Framework Filled Polymer Based Membranes 审中-公开
标题翻译：金属有机骨架填充聚合物膜
公开(公告)号：US20130047843A1
公开(公告)日：2013-02-28
申请号：US13577577
申请日：2011-02-11
申请人： Scott T. Matteucci , Leonardo C. Lopez , Shawn D. Feist , Peter N. Nickias , Dean M. Millar , Michael P. Tate
发明人： Scott T. Matteucci , Leonardo C. Lopez , Shawn D. Feist , Peter N. Nickias , Dean M. Millar , Michael P. Tate
IPC分类号： C08L77/12 , B01D53/22 , C08L75/06
CPC分类号： B01D67/0079 , B01D53/228 , B01D69/148 , B01D71/028 , B01D71/56 , B01D71/80
摘要： A membrane for separation of gases, the membrane including a metal-organic phase and a polymeric phase, the metal-organic phase having porous crystalline metal compounds and ligands, the polymeric phase having a molecularly self assembling polymer.
摘要翻译：用于分离气体的膜，所述膜包括金属 - 有机相和聚合物相，所述金属 - 有机相具有多孔结晶金属化合物和配体，所述聚合物相具有分子自组装聚合物。

13. 发明授权

US5892076A Allyl containing metal complexes and olefin polymerization process 失效
标题翻译：含烯丙基的金属络合物和烯烃聚合方法
公开(公告)号：US5892076A
公开(公告)日：1999-04-06
申请号：US815913
申请日：1997-03-11
申请人： Peter N. Nickias
发明人： Peter N. Nickias
IPC分类号： C07F17/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F10/00 , C07F7/00 , C07F7/28
CPC分类号： C08F10/00 , C07F17/00 , C08F4/619 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , Y10S526/943
摘要： Metal complexes useful as olefin polymerization catalysts corresponding to the formula: ##STR1## or a dimer, solvated adduct, chelated derivative or mixture thereof, wherein:Q is a cyclic group or Y*, that is bound to M by means of a delocalized .pi.-bond, said group containing up to 50 nonhydrogen atoms;M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements;Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula, --(ER.sub.2).sub.m --, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of hydrocarbyl, hydrocarbyloxy, silyl, and germyl of up to 20 atoms other than hydrogen, and m is an integer from 1 to 3;Y* is an allyl or a hydrocarbyl-, silyl- or germyl-substituted allyl group containing up to 20 nonhydrogen atoms bonded to Z and bonded via an .eta..sup.3 -.pi. bond to M;L is a neutral confugated diene ligand having up to 20 non-hydrogen atoms;X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl group;n is a number from 0 to 3; andp is an inteaer from 0 to 2.
摘要翻译：可用作对应于下式的烯烃聚合催化剂的金属络合物：或其二聚物，溶剂化加合物，螯合衍生物或其混合物，其中：Q是环状基团或Y *，其通过离域pI 所述基团含有多达50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E独立地每次出现为碳，硅或锗，R各自独立地选自烃基，烃氧基，甲硅烷基和除氢以外的至多20个原子的甲锗烷基，m是1至3的整数; Y *是含有至多20个非氢原子的烯丙基或烃基 - 甲硅烷基或甲锗烷基取代的烯丙基，其与Z键合并通过η3键连接至M; L是具有至多20个非氢原子的中性配位二烯配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X 一起形成二价烃基; n是从0到3的数字; 并且p是从0到2的内部。

14. 发明授权

US5721185A Homogeneous olefin polymerization catalyst by abstraction with lewis acids 失效
标题翻译：均相烯烃聚合催化剂与路易斯酸的萃取
公开(公告)号：US5721185A
公开(公告)日：1998-02-24
申请号：US876268
申请日：1992-05-05
申请人： Robert E. LaPointe , James C. Stevens , Peter N. Nickias , Mark H. McAdon
发明人： Robert E. LaPointe , James C. Stevens , Peter N. Nickias , Mark H. McAdon
IPC分类号： C08F4/60 , C07F17/00 , C08F4/42 , C08F4/64 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , B01J31/00
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2420/02 , C08F4/65908 , C08F4/6592
摘要： A process for preparing addition polymerization catalysts having a limiting charge separated structure corresponding to the formula: LMX.sup.+ XA.sup.-, wherein: L is a derivative of a substituted delocalized .pi.-bonded group imparting a constrained geometry to the metal active site and containing up to 50 nonhydrogen atoms; M is a metal of Group 4 or the Lanthanide series of the Periodic Table of the Elements; X independently each occurrence is hydride or a hydrocarbyl, silyl or germyl group having up to 20 carbon, silicon or germanium atoms; and A.sup.- is an anion of a Lewis acid, A, having relative Lewis acidity greater than or equal to that of phenylbis(perfluorophenyl)borane, said anion being compatible with the metal cation, the steps of the process comprising contacting a derivative of a Group 4 or Lanthanide metal corresponding to the formula: i LMX.sub.2, wherein L, M, and X are as previously defined, with the Lewis acid, A, under conditions to cause abstraction of X and formation of the anion XA.sup.-.
摘要翻译：一种制备具有对应于下列通式的极限电荷分离结构的加成聚合催化剂的方法：LMX + XA-，其中：L是取代的离域π键合基团的衍生物，其赋予金属活性位点约束几何形状， 50个非氢原子; M是第4族金属或元素周期表的镧系元素; 独立地，每次出现氢化物或具有至多20个碳，硅或锗原子的烃基，甲硅烷基或甲硅烷基; A是具有大于或等于苯基双（全氟苯基）硼烷的相对路易斯酸度的路易斯酸A的阴离子，所述阴离子与金属阳离子相容，所述方法的步骤包括使在引起X的抽出和形成阴离子XA-的条件下，与路易斯酸A相对应的式4或镧系金属，其中L，M和X如前所定义。

15. 发明授权

US5532394A Addition polymerization catalysts comprising reduced oxidation state metal complexes 失效
标题翻译：包含还原氧化态金属络合物的加成聚合催化剂
公开(公告)号：US5532394A
公开(公告)日：1996-07-02
申请号：US295768
申请日：1994-09-02
申请人： Robert K. Rosen , Peter N. Nickias , David D. Devore , James C. Stevens , Francis J. Timmers
发明人： Robert K. Rosen , Peter N. Nickias , David D. Devore , James C. Stevens , Francis J. Timmers
IPC分类号： C08F4/645 , C07F17/00 , C08F4/02 , C08F4/42 , C08F4/60 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： Metal complexes useful in the formation of addition polymerization catalysts of the formula: ##STR1## wherein Cp"' is a cyclopentadienyl group or substituted derivative thereof;Z is a divalent moiety comprising oxygen, nitrogen, phosphorous, boron or a member of Group 4 of the Periodic Table of Elements;Y is a linking group comprising nitrogen, phosphorus, oxygen or sulfur;M is a Group 4 metal in the +3 oxidation state; andL"' is a monovalent anionic stabilizing ligand.
摘要翻译： PCT No.PCT / US93 / 02584第 371日期：1994年9月2日 102（e）1994年9月2日PCT PCT 1993年3月19日PCT公布。第WO93 / 19104号PCT公告日本9月30日，1993年。金属络合物可用于形成下式的加成聚合催化剂：其上述或取代的衍生物; Z是包含氧，氮，磷，硼或元素周期表第4族成员的二价部分; Y是包含氮，磷，氧或硫的连接基团; M是+3氧化态的第4族金属; L“是一价阴离子稳定配体。

16. 发明授权

US5494874A Homogenous, stabilized, reduced metal addition polymerization catalysts, process for preparation and method of use 失效
标题翻译：均匀，稳定，还原金属加成聚合催化剂，制备方法和使用方法
公开(公告)号：US5494874A
公开(公告)日：1996-02-27
申请号：US294469
申请日：1994-08-23
申请人： Robert K. Rosen , David D. Devore , Peter N. Nickias , James C. Stevens , Francis J. Timmers
发明人： Robert K. Rosen , David D. Devore , Peter N. Nickias , James C. Stevens , Francis J. Timmers
IPC分类号： C08F4/645 , C07F17/00 , C08F4/02 , C08F4/42 , C08F4/60 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/18
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： Complexes useful as addition polymerization catalysts, a process for their manufacture and addition polymerization processes wherein the complex comprises a Group 4 metal in the .sup.+ 3 oxidation state, a delocalized n-bonding moiety, and at least one stabilizing ligand.
摘要翻译：可用作加成聚合催化剂的络合物，其制备方法和加成聚合方法，其中络合物包含+3氧化态的第4族金属，离域的n键结构部分和至少一种稳定配体。

17. 发明授权

US5347024A Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation 失效
标题翻译：通过路易斯酸制备加成聚合催化剂减轻金属中心氧化
公开(公告)号：US5347024A
公开(公告)日：1994-09-13
申请号：US34434
申请日：1993-03-19
申请人： Peter N. Nickias , David D. Devore , Francis J. Timmers , Robert K. Rosen , Robert D. Mussell
发明人： Peter N. Nickias , David D. Devore , Francis J. Timmers , Robert K. Rosen , Robert D. Mussell
IPC分类号： C08F4/64 , C07F5/02 , C07F7/10 , C07F9/50 , C07F17/00 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F10/00 , C07C7/00
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/6592
摘要： Addition polymerization catalysts comprising a derivative of a titanium or zirconium in the +4 oxidation state prepared by metal center oxidation and cation complex formation of a reduced metal precursor complex via electron transfer in a single step by use of a neutral organic oxidant, optionally in the presence of a Lewis acid mitigator.
摘要翻译：包含通过金属中心氧化制备的+4氧化态的钛或锆的衍生物的加成聚合催化剂，并且通过使用中性有机氧化剂在一个步骤中通过电子转移阳离子络合物形成还原金属前体复合物，任选地在存在路易斯酸缓释剂。

18. 发明申请

US20130133515A1 Separation of Acidic Constituents by Self Assembling Polymer Membranes 审中-公开
标题翻译：通过自组装聚合物膜分离酸性成分
公开(公告)号：US20130133515A1
公开(公告)日：2013-05-30
申请号：US13577582
申请日：2011-02-11
申请人： Scott T. Matteucci , Leonardo C. Lopez , Shawn D. Feist , Peter N. Nickias , William J. Harris
发明人： Scott T. Matteucci , Leonardo C. Lopez , Shawn D. Feist , Peter N. Nickias , William J. Harris
IPC分类号： B01D71/48 , B01D71/56 , B01D71/54 , B01D53/22 , B01D71/52
CPC分类号： B01D71/48 , B01D53/228 , B01D71/52 , B01D71/54 , B01D71/56 , B01D71/80
摘要： A method of removing an acidic gas from a gas stream by contacting said gas stream with a polymer, wherein the polymer is a macromolecularly self assembling polymeric material, the method including the steps of contacting the gas mixture with the membrane; and extracting the acidic gas from the gas stream.
摘要翻译：一种通过使所述气流与聚合物接触而从气流中除去酸性气体的方法，其中所述聚合物是大分子自组装聚合物材料，所述方法包括使气体混合物与膜接触的步骤; 并从气流中提取酸性气体。

19. 发明授权

US06410629B1 Incorporation of free radical inhibitors in polyolefins 失效
标题翻译：在聚烯烃中引入自由基抑制剂
公开(公告)号：US06410629B1
公开(公告)日：2002-06-25
申请号：US08920625
申请日：1997-08-27
申请人： Michael J. Mullins , Peter N. Nickias , Jorge Soto
发明人： Michael J. Mullins , Peter N. Nickias , Jorge Soto
IPC分类号： C08K551
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61927 , C08F110/06 , C08F2/44 , C08F4/61912
摘要： The invention includes a process for inhibiting deterioration in an olefin polymer by adding a phenolic free radical inhibitor during or before polymerization with a metallocene type transition metal catalyst without inactivating the free radical inhibitor because does not inhibit the transition metal catalyst activity. Preferably the free radical inhibitor is first to remove compounds which inhibit catalyst activity. The invention also includes a composition comprising at least one olefin monomer, a polymer of the monomer, a metallocene type transition metal catalyst and at least one free radical inhibitor having sufficient substituents to hinder the active inhibiting group such that it does not undesirably inhibit the transition metal catalyst.
摘要翻译：本发明包括通过在茂金属型过渡金属催化剂中聚合期间或之后添加酚类自由基抑制剂而不使自由基抑制剂失活而抑制烯烃聚合物的劣化的方法，因为不抑制过渡金属催化剂活性。优选地，自由基抑制剂首先是去除抑制催化剂活性的化合物。本发明还包括包含至少一种烯烃单体，单体的聚合物，茂金属型过渡金属催化剂和至少一种具有足够的取代基的自由基抑制剂的组合物，其阻碍活性抑制基团，使得其不会不希望地抑制转变金属催化剂。

20. 发明授权

US06235917B1 Dinuclear complexes and polymerization catalysts therefrom 有权
标题翻译：双核络合物和聚合催化剂
公开(公告)号：US06235917B1
公开(公告)日：2001-05-22
申请号：US09234192
申请日：1999-01-20
申请人： David D. Graf , Jerzy Klosin , Peter N. Nickias , Jasson T. Patton
发明人： David D. Graf , Jerzy Klosin , Peter N. Nickias , Jasson T. Patton
IPC分类号： C07F1700
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/6592 , C08F10/02 , C08F210/16 , C08F2410/03 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/03 , C08F2500/12
摘要： Group 3-6 or Lanthanide metal complexes possessing two metal centers joined by means of a divalent bridging group joining trivalent moieties comprising boron or a member of Group 14 of the Periodic Table of the Elements, and optionally also comprising nitrogen, phosphorus, sulfur or oxygen, in the complexes, catalysts derived therefrom by combining the same with strong Lewis acids, Bronsted acid salts, salts containing a cationic oxidizing agent or subjected to bulk electrolysis in the presence of compatible, inert non-coordinating anions and the use of such catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers are disclosed.
摘要翻译：具有两个金属中心的第3-6族或镧系元素金属络合物通过连接包含硼或元素周期表第14族成员的三价基团的二价桥连基团连接，并且任选还包含氮，磷，硫或氧在络合物中，通过将其与强路易斯酸，布朗斯台德酸盐，含有阳离子氧化剂的盐或在相容的惰性非配位阴离子存在下进行本体电解，并将其用于公开了烯烃，二烯烃和/或炔属不饱和单体的聚合。

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