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11. 发明授权

US5629393A Initiating process and system for the anionic polymerization of acrylic monomers 失效
标题翻译：用于丙烯酸单体的阴离子聚合的引发方法和系统
公开(公告)号：US5629393A
公开(公告)日：1997-05-13
申请号：US91403
申请日：1993-07-14
申请人： Sunil K. Varshney , Roger Fayt , Philippe Teyssie
发明人： Sunil K. Varshney , Roger Fayt , Philippe Teyssie
IPC分类号： C08F4/56 , C08F20/12 , C08F20/14 , C08F297/02 , C08F210/00 , C08F212/06 , C08F220/10 , C08F226/06 , C08F293/00 , B01T31/00
CPC分类号： C08F20/12 , C08F20/14 , C08F297/026
摘要： The initiating system for the anionic polymerization of acrylic monomers, and where necessary, vinyl comonomers, including at least one R-M initiator in which M=a metal chosen from among the alkaline and alcaline earth metals and R=an alkyl with a linear or branched chain at C.sub.2 -C.sub.6 or aryl or arylalkyl, is characterized by the fact that the polymerization takes place in the presence also of at least one R.sub.1 OM.sub.1 alkaline metal alcoholate, in which R=an alkyl with a linear or branched chain at C.sub.1 -C.sub.6 or aryl or aryalkyl and M.sub.1 =an alkaline metal, on condition that when M.sub.1 is lithium, then R=an aryl or arylalkyl. Said process for the polymerization of primary, secondary, or tertiary alkyl acrylates, and possibly of vinyl comonomers, is characterized by the fact that the polymerization takes place in the presence of an initiating system as described above.
摘要翻译：用于丙烯酸单体的阴离子聚合的引发体系，以及必要时的乙烯基共聚单体，包括至少一种RM引发剂，其中M =选自碱金属和碱土金属的金属，R =具有直链或支链的烷基在C2-C6或芳基或芳基烷基上，其特征在于聚合反应在还存在至少一种R1OM1碱金属醇化物的情况下进行，其中R =在C 1 -C 6或芳基上具有直链或支链的烷基或烷基，M1 =碱金属，条件是当M1为锂时，R =芳基或芳基烷基。用于聚合丙烯酸伯，仲或叔烷基酯和可能的乙烯基共聚单体的所述方法的特征在于聚合在如上所述的引发体系存在下进行。

12. 发明授权

US5591816A Heat-resistant maleimido polymers/block copolymers 失效
公开(公告)号：US5591816A
公开(公告)日：1997-01-07
申请号：US167032
申请日：1993-12-16
申请人： Sunil K. Varshney , Philippe Teyssie , Roger Fayt
发明人： Sunil K. Varshney , Philippe Teyssie , Roger Fayt
IPC分类号： C08F4/06 , C08F4/46 , C08F22/36 , C08F22/40 , C08F122/40 , C08F293/00 , C08F297/00 , C08F297/02 , C08F222/40
CPC分类号： C08F297/026 , C08F122/40
摘要： Novel N-substituted maleimide homopolymers having a number-average molecular weight ranging from 12,000 to about 100,000 are prepared by anionically polymerizing an N-substituted maleimide monomer, in solvent phase, in the presence of at least one organometallic polymerization initiator which comprises sec-butyllithium, a sodium alcoholate, diphenylmethylpotassium, naphthalenelithium or naphthalenesodium, and novel N-substituted maleimide homopolymers having a polydispersity index ranging from 1.1 to 1.5 are prepared by anionically polymerizing an N-substituted maleimide monomer, in solvent phase, in the presence of at least one alkali metal organometallic polymerization initiator and at least one inorganic or organic salt of an alkali or alkaline earth metal; novel block copolymers include blocks of the above maleimido homopolymers and, e.g., blocks of an acrylic or methacrylic polymer.

13. 发明授权

US5294674A Heat-resistant maleimido polymers/block copolymers 失效
标题翻译：耐热马来酰亚胺聚合物/嵌段共聚物
公开(公告)号：US5294674A
公开(公告)日：1994-03-15
申请号：US804674
申请日：1991-12-10
申请人： Sunil K. Varshney , Philippe Teyssie , Roger Fayt
发明人： Sunil K. Varshney , Philippe Teyssie , Roger Fayt
IPC分类号： C08F4/06 , C08F4/46 , C08F22/36 , C08F22/40 , C08F122/40 , C08F293/00 , C08F297/00 , C08F297/02 , C08F267/10 , C08F271/02
CPC分类号： C08F297/026 , C08F122/40
摘要： Novel N-substituted maleimide homopolymers having a number-average molecular weight ranging from 12,000 to about 100,000 are prepared by anionically polymerizing an N-substituted maleimide monomer, in solvent phase, in the presence of at least one organometallic polymerization initiator which comprises sec-butyllithium, a sodium alcoholate, diphenylmethylpotassium, naphthalenelithium or naphthalenesodium, and novel N-substituted maleimide homopolymers having a polydispersity index ranging from 1.1 to 1.5 are prepared by anionically polymerizing an N-substituted maleimide monomer, in solvent phase, in the presence of at least one alkali metal organometallic polymerization initiator and at least one inorganic or organic salt of an alkali or alkaline earth metal; novel block copolymers include blocks of the above maleimido homopolymers and, e.g., blocks of an acrylic or methacrylic polymer.
摘要翻译：通过在至少一种有机金属聚合引发剂的存在下，在溶剂相中阴离子聚合N-取代的马来酰亚胺单体，制备数均分子量为12,000至约100,000的新型N-取代的马来酰亚胺均聚物，该有机金属聚合引发剂包括仲丁基锂，醇钠，二苯基甲基钾，萘锂或萘钠，以及分子量指数为1.1〜1.5的新型N-取代马来酰亚胺均聚物，是通过在溶剂相中，在至少一种碱金属有机金属聚合引发剂和至少一种碱金属或碱土金属的无机或有机盐; 新的嵌段共聚物包括上述马来酰亚胺均聚物的嵌段和例如丙烯酸或甲基丙烯酸聚合物的嵌段。

14. 发明授权

US4461874A Block copolymers of conjugated dienes or vinyl substituted aromatic hydrocarbons and acrylic esters and process for their manufacture 失效
标题翻译：共轭二烯或乙烯基取代的芳族烃和丙烯酸酯的嵌段共聚物及其制备方法
公开(公告)号：US4461874A
公开(公告)日：1984-07-24
申请号：US431961
申请日：1982-10-01
申请人： Philippe Teyssie , Robert Jerome , Trazollah Ouhadi , Roger Fayt
发明人： Philippe Teyssie , Robert Jerome , Trazollah Ouhadi , Roger Fayt
IPC分类号： C08F4/00 , C08F4/42 , C08F236/00 , C08F236/10 , C08F297/02 , C08F297/04
CPC分类号： C08F297/026
摘要： Block copolymers having a first sequence formed with a conjugated diene or a vinyl substituted aromatic hydrocarbon other than alpha-methylstyrene, a second sequence formed with an acrylic ester, and a linking intermediate sequence formed with alpha-methylstyrene. An anionic polymerization process is used to form these block copolymers.
摘要翻译：具有由共轭二烯或除α-甲基苯乙烯以外的乙烯基取代的芳族烃形成的第一序列的嵌段共聚物，由丙烯酸酯形成的第二序列和由α-甲基苯乙烯形成的连接中间体序列。使用阴离子聚合方法形成这些嵌段共聚物。

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