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    • 12. 发明申请
    • Seamless steel pipe and manufacturing method thereof
    • 无缝钢管及其制造方法
    • US20080257459A1
    • 2008-10-23
    • US12010459
    • 2008-01-25
    • Yuji AraiKunio KondoNobuyuki Hisamune
    • Yuji AraiKunio KondoNobuyuki Hisamune
    • C21D9/08
    • C21D8/10C21D9/08C22C38/001C22C38/002C22C38/44C22C38/50C22C38/52
    • The present invention relates to the following seamless steel pipes excellent in strength, toughness and weldability, particularly suitable for submarine flow lines, and a manufacturing method thereof.An as-quenched seamless steel pipe having a chemical composition consisting of, by mass %, C: 0.03 to 0.08%, Mn: 0.3 to 2.5%, Al: 0.001 to 0.10%, Cr: 0.02 to 1.0%, Ni: 0.02 to 1.0%, Mo: 0.02 to 0.8%, Ti: 0.004 to 0.010%, N: 0.002 to 0.008%, Ca: 0.0005 to 0.005%, and the balance Fe and impurities, with not more than 0.25% of Si, not more than 0.05% of P, not more than 0.005% of S, less than 0.005% of Nb, and less than 0.0003% of B as the impurities, and having a microstructure consisting of not more than 20 volume % of polygonal ferrite, not more than 10 volume % of a mixed microstructure of martensite and retained austenite, and the balance bainite. B can be 0.0003 to 0.001%. Mg and/or REM can be contained. The manufacturing method is characterized by the cooling rate during quenching.
    • 本发明涉及以下具有优异的强度,韧性和焊接性的无缝钢管,特别适用于海底流水线及其制造方法。 一种淬火后的无缝钢管,其组成为以质量%计含有C:0.03〜0.08%,Mn:0.3〜2.5%,Al:0.001〜0.10%,Cr:0.02〜1.0%,Ni:0.02〜 1.0%,Mo:0.02〜0.8%,Ti:0.004〜0.010%,N:0.002〜0.008%,Ca:0.0005〜0.005%,余量为Fe和杂质,不大于0.25% 0.05%的P,不大于0.005%的S,小于0.005%的Nb和小于0.0003%的作为杂质的B,并且具有不大于20体积%的多边形铁素体的微结构,不大于 10体积%的马氏体和残余奥氏体的混合显微组织,以及余量的贝氏体。 B可以为0.0003〜0.001%。 可以含有Mg和/或REM。 制造方法的特征在于淬火时的冷却速度。
    • 14. 发明申请
    • Manufacturing method of high strength, high toughness seamless steel pipe for linepipe
    • 线性管高强度,高韧性无缝钢管的制造方法
    • US20060219332A1
    • 2006-10-05
    • US11393793
    • 2006-03-31
    • Tsuneo MuraseKunio KondoNobuyuki Hisamune
    • Tsuneo MuraseKunio KondoNobuyuki Hisamune
    • C21D9/08
    • C22C38/02C21D8/10C21D9/08C22C38/04C22C38/08C22C38/12C22C38/16C22C38/18
    • A manufacturing method of high-strength, high-toughness seamless steel pipe for linepipe comprises: (1) hot piercing a billet, in which the carbon equivalent value Ceq defined by expression (a): Ceq=C+Mn/6+(Cu+Ni)/5+(Cr+Mo+V)/5[%] . . . (a) is not greater than 0.60 wt %, and then subjecting the pierced billet to hot rolling at a temperature of 950° C. or higher to obtain a seamless steel pipe; (2) putting the seamless steel pipe immediately, without cooling to Ar3 point or lower, into a furnace kept at Ar3 point+50° C. to 1100° C. to carry out heating; (3) cooling the seamless steel pipe at a cooling rate of 5° C./sec or higher; and (4) tempering the seamless steel pipe at temperature of 550° C. to Ac1 point. A high-strength and high-toughness seamless steel pipe with little strength unevenness can be manufactured, which can be effectively employed for linepipes in cold areas.
    • 用于管线管的高强度,高韧性无缝钢管的制造方法包括:(1)热刺穿坯料,其中由式(a)定义的碳当量值Ceq:Ceq = C + Mn / 6 +(Cu + Ni)/ 5 +(Cr + Mo + V)/ 5 [%]。 。 。 (a)不大于0.60重量%,然后在950℃以上的温度下对穿孔坯进行热轧,得到无缝钢管; (2)将冷却至Ar3点以下的无缝钢管立即放入保持Ar3点+50℃〜1100℃的炉中进行加热; (3)以5℃/秒以上的冷却速度冷却无缝钢管; (4)将温度为550℃的无缝钢管回火至Ac1点。 可以制造出具有很小强度不均匀性的高强度高韧性无缝钢管,这可以有效地用于寒冷地区的管线管。
    • 15. 发明授权
    • Process for producing high-strength seamless steel pipe having excellent
sulfide stress cracking resistance
    • 具有优异的耐硫化物应力开裂性的高强度无缝钢管的制造方法
    • US5938865A
    • 1999-08-17
    • US952222
    • 1998-02-05
    • Kunio KondoTakahiro KushidaHajime OsakoHideki Takabe
    • Kunio KondoTakahiro KushidaHajime OsakoHideki Takabe
    • B21B19/04B21B23/00C21D8/10
    • B21B23/00C21D8/10B21B19/04
    • A process for producing a seamless steel pipe wherein pipe manufacturing steps and the heat treatment steps are carried out in one production line. The properties of the pipe are comparative or superior to those of the pipe manufactured in the conventional reheating, quenching and tempering process. The process is characterized by using the billet of a low alloy steel containing C: 0.15-0.50%, Cr: 0.1-1.5%, Mo: 0.1-1.5%, Al: 0.005-0.50%, Ti: 0.005-0.50% and Nb: 0.003-0.50%, and comprising the following steps (1) to (5).(1) hot rolling with 40% or more of cross sectional reduction ratio,(2) finishing the hot rolling in a temperature range of 800-1100.degree. C.,(3) putting the manufactured steel pipe promptly in a complementary heating apparatus after the finish rolling, and complementarily heating at the temperature and time satisfying the following formula (a).(4) quenching the steel pipe immediately after taking out of the complementary heating apparatus, and(5) tempering the pipe at a temperature not higher than the Ac.sub.1 transformation point as the last heat treatment.23500.ltoreq.(T+273).times.(21+log t).ltoreq.26000 (a)where, T (.degree.C.) is a temperature of not lower than 850.degree. C., and t is time (hr). Further, an intermediate heat treatment consisting of quenching or combination of quenching and tempering may be applied between the steps (4) and (5).
    • PCT No.PCT / JP96 / 01274 Sec。 371日期:1998年2月5日 102(e)日期1998年2月5日PCT提交1996年5月15日PCT公布。 公开号WO96 / 36742 日期:1996年11月21日一种生产无缝钢管的方法,其中在一条生产线中进行管制造步骤和热处理步骤。 管道的性能与传统的再加热,淬火和回火工艺中制造的管材的性能相比甚至更好。 该方法的特征在于使用含有C:0.15-0.50%,Cr:0.1-1.5%,Mo:0.1-1.5%,Al:0.005-0.50%,Ti:0.005-0.50%的低合金钢和Nb :0.003-0.50%,并且包括以下步骤(1)至(5)。 (1)以40%以上的横截面减速比进行热轧,(2)在800-1100℃的温度范围内完成热轧,(3)将制造的钢管迅速置于互补的加热装置中 精轧,并在满足下述式(a)的温度和时间下互补加热。 (4)在取出补充加热装置后立即淬火钢管,(5)在不高于Ac1相变点的温度下对管进行回火作为最后的热处理.23500
    • 17. 发明授权
    • High-strength stainless steel pipe excellent in sulfide stress cracking resistance and high-temperature carbonic-acid gas corrosion resistance
    • 高强度不锈钢管具有优异的耐硫化应力开裂性和高温碳酸气体耐腐蚀性能
    • US08608872B2
    • 2013-12-17
    • US13082432
    • 2011-04-08
    • Kunio KondoHisashi AmayaHideki TakabeTaro Ohe
    • Kunio KondoHisashi AmayaHideki TakabeTaro Ohe
    • C22C38/42C22C38/44
    • C22C38/42C22C38/001C22C38/02C22C38/04C22C38/06C22C38/44
    • The problem to be solved is the provision of a high-strength stainless steel pipe having a sufficient corrosion resistance in a high-temperature carbonic acid gas environment and having an excellent sulfide stress cracking resistance at normal temperature. A high-strength stainless steel pipe consist of, by mass %, C: 0.05% or less, Si: 1.0% or less, P: 0.05% or less, S: less than 0.002%, Cr: more than 16% and 18% or less, Mo: more than 2% and 3% or less, Cu: 1% to 3.5%, Ni: 3% or more and less than 5%, Al: 0.001% to 0.1% and O: 0.01% or less, Mn: 1% or less and N: 0.05% or less, and Mn and N in the above ranges satisfy formula (1), and the balance being Fe and impurities; and the metal micro-structure of the stainless steel pipe mainly includes a martensitic phase and comprises 10 to 40% of a ferritic phase by volume fraction and 10% or less of a retained γ-phase by volume fraction. [Mn]×([N]−0.0045)≦0.001  (1) wherein the symbols of elements in formula (1) respectively represent the contents (unit: mass %) of the elements in the steel.
    • 要解决的问题是在高温碳酸气体环境中提供具有足够耐腐蚀性的高强度不锈钢管,并且在常温下具有优异的耐硫化物应力开裂性。 高强度不锈钢管以质量%计含有C:0.05%以下,Si:1.0%以下,P:0.05%以下,S:小于0.002%,Cr:16%以上18以下 %以下,Mo:大于2%,3%以下,Cu:1〜3.5%,Ni:3%以上且小于5%,Al:0.001〜0.1%,O:0.01%以下 ,Mn:1%以下,N:0.05%以下,上述范围的Mn和N满足式(1),余量为Fe和杂质; 并且不锈钢管的金属微结构主要包括马氏体相,并且包含10〜40体积%的铁素体相和10体积%以下的γ相。 [Mn]×([N] -0.0045)@ 0.001(1)其中,式(1)中的元素的符号分别表示钢中元素的含量(单位:质量%)。
    • 19. 发明申请
    • ELECTROLUMINESCENT ELEMENT, METHOD FOR MANUFACTURING ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE AND ILLUMINATING DEVICE
    • 电致发光元件,制造电致发光元件的方法,显示装置和照明装置
    • US20120299469A1
    • 2012-11-29
    • US13519599
    • 2010-12-21
    • Kunio KondoKanjiro SakoMasaru TajimaKatsumasa Hirose
    • Kunio KondoKanjiro SakoMasaru TajimaKatsumasa Hirose
    • H05B33/12H05B33/10
    • H01L51/5275H01L27/3281H01L27/329H01L51/5209H05B33/14
    • Disclosed is an electroluminescent element (10) which includes an anode layer (12), a cathode layer (14), a first low refractive index layer (13) that is formed between the anode layer (12) and the cathode layer (14), a recessed portion (16) that penetrates at least the anode layer (12) and the first low refractive index layer (13), a second low refractive index layer (19) that is formed on the bottom of the recessed portion (16), and a light emitting portion (17) that is formed on the second low refractive index layer (19). The electroluminescent element (10) is also characterized in that the refractive index of the first low refractive index layer (13) and the refractive index of the second low refractive index layer (19) are lower than the refractive index of the light emitting portion (17). The electroluminescent element (10) provides an electroluminescent element which has high light-emitting efficiency when the light emitted from the light emitting portion is taken out from the substrate side.
    • 公开了一种电致发光元件(10),其包括形成在阳极层(12)和阴极层(14)之间的阳极层(12),阴极层(14),第一低折射率层(13) ,至少穿透所述阳极层(12)和所述第一低折射率层(13)的凹部(16),形成在所述凹部(16)的底部上的第二低折射率层(19) 和形成在第二低折射率层(19)上的发光部分(17)。 电致发光元件(10)的特征还在于,第一低折射率层(13)的折射率和第二低折射率层(19)的折射率低于发光部分(的折射率) 17)。 电致发光元件(10)提供当从基板侧取出从发光部分发出的光时具有高发光效率的电致发光元件。