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    • 15. 发明授权
    • Color photographic light-sensitive material
    • US4351897A
    • 1982-09-28
    • US291886
    • 1981-08-11
    • Kozo AokiNobuo SetoYoshiharu YabukiMasakazu MorigakiNobuo FurutachiKotaro Nakamura
    • Kozo AokiNobuo SetoYoshiharu YabukiMasakazu MorigakiNobuo FurutachiKotaro Nakamura
    • G03C7/38C07D231/52C09B26/02G03C7/384G03C1/40
    • C07D231/52G03C7/384
    • A silver halide color photographic light-sensitive material is described comprising a support having thereon a photographic layer containing at least one coupler represented by formula (I) or (II) ##STR1## wherein Ar represents a phenyl group substituted with at least one substituent selected from a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; X represents a halogen atom or an alkoxy group; R.sub.1 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acylamino group, a sulfonamido group, a sulfamoyl group, a carbamoyl group, a diacylamino group, an alkoxycarbonyl group, an alkoxysulfonyl group, an aryloxysulfonyl group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, an arylthio group, an alkyloxycarbonylamino group, an alkylureido group, an acyl group, a nitro group, a carboxy group, or a trifluoromethyl group; R.sub.2 represents a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; R.sub.3 represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; at least one of R.sub.2 and R.sub.3 represents an alkoxy group; m.sub.1 and m.sub.2 each represents an integer from 1 to 4; R.sub.4 represents an alkyl group or an aryl group; R.sub.5 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an aryl group; n represents an integer from 1 to 6; and when m.sub.1, m.sub.2 and n each is 2 or more, each R.sub.1, R.sub.3 and R.sub.5 may be the same or different.The color photographic light-sensitive material containing a 2-equivalent magenta color image-forming coupler as described above has various advantages, for example, in that the dye formation efficiency in the color development step is high, the photographic properties are not influenced by variations in the pH of the color development bath, and the color images formed are fast to heat or light.
    • 17. 发明授权
    • Silver halide color photographic material
    • 卤化银彩色照相材料
    • US5411846A
    • 1995-05-02
    • US94217
    • 1993-07-21
    • Nobuo SetoYasuhiro YoshiokaMasakazu Morigaki
    • Nobuo SetoYasuhiro YoshiokaMasakazu Morigaki
    • G03C7/392G03C7/388
    • G03C7/39268
    • A novel silver halide color photographic material comprising a support provided thereon at least one layer containing at least one compound represented by the following general formula (A): ##STR1## In the formula, L.sub.1 represents an alkylene or arylene group; R.sub.1 represents a substituent which can be substituted for a hydrogen of the benzene ring; m represents an integer 2 to 7; and n is 0 or an integer of 1 to 4, with the proviso that when either or both of m and n are at least two, the plurality of L.sub.1 groups and/or R.sub.1 groups may be the same or different, and with the proviso that the compound of formula (A) does not form a polymer via an R.sub.1 group. In a preferred embodiment, at least one compound represented by formula (A) is incorporated into a photographic silver halide emulsion layer.
    • 一种新颖的卤化银彩色照相材料,其中包含至少一层含有至少一种由以下通式(A)表示的化合物的载体的载体:式中,L1表示亚烷基或亚芳基; R1表示可以取代苯环的氢的取代基; m表示2〜7的整数, 并且n为0或1至4的整数,条件是当m和n中的任一个或两者至少为2时,多个L1基团和/或R 1基团可以相同或不同,并且条件是 式(A)的化合物不通过R 1基团形成聚合物。 在优选的实施方案中,将至少一种由式(A)表示的化合物引入到照相卤化银乳剂层中。
    • 18. 发明授权
    • Silver halide color photographic material containing an anti-facing agent
    • 含有防白色剂的卤化银彩色照相材料
    • US5278039A
    • 1994-01-11
    • US865333
    • 1992-04-08
    • Nobuo SetoHiroshi FukuzawaMasakazu Morigaki
    • Nobuo SetoHiroshi FukuzawaMasakazu Morigaki
    • C09B23/00C09B67/00G03C7/30G03C7/36G03C7/392G03C1/34
    • G03C7/3013
    • There is disclosed a silver halide color photographic light-sensitive material capable of providing a color image which does not discolor for a long period of time and having a high preservation property. The light-sensitive material contains a novel anti-fading agent represented by following Formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, or an aliphatic oxy group; R.sub.2 and R.sub.3 may be the same or different and each represent an aliphatic group, an aromatic group, and a heterocyclic group; R.sub.4 represents a substituent; R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 each represent a hydrogen atom and a substituent; R.sub.2 and R.sub.3, R.sub.3 and R.sub.4, and R.sub.4 and R.sub.2 may be combined with each other to form a 5- to 8-membered ring, and a dimer or other polymer may be formed with R.sub.1, R.sub.2, R.sub.3 and R.sub.4 ; R.sub.5 and R.sub.6, R.sub.6 and R.sub.7, R.sub.7 and R.sub.8, and R.sub.8 and R.sub.9 may be combined with each other to form a 5- to 8-membered ring; provided that R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 each does not represent an unsubstituted amino group or an unsubstituted carbamoyl group, R.sub.5 and R.sub.9 each do not represent an aliphatic oxy group, and any one of R.sub.2, R.sub.3 and R.sub.4 does not form a ring with R.sub.5, R.sub.6, R.sub.7, R.sub.8 or R.sub.9.
    • 公开了一种卤化银彩色摄影感光材料,其能够提供长时间不变色并具有高保存性能的彩色图像。 感光材料含有由下式(I)表示的新型抗褪色剂:(*化学结构*)其中R 1表示氢原子,脂族基团,芳族基团,杂环基或脂族氧基 ; R2和R3可以相同或不同,各自表示脂族基团,芳族基团和杂环基团; R4表示取代基; R5,R6,R7,R8和R9各自表示氢原子和取代基; R 2和R 3,R 3和R 4以及R 4和R 2可以彼此结合形成5-至8-元环,并且可以用R 1,R 2,R 3和R 4形成二聚体或其它聚合物; R 5和R 6,R 6和R 7,R 7和R 8以及R 8和R 9可以相互结合形成5-8元环; 条件是R5,R6,R7,R8和R9各自不表示未取代的氨基或未取代的氨基甲酰基,R5和R9各自不表示脂族氧基,R2,R3和R4中的任一个不形成 与R5,R6,R7,R8或R9环。
    • 19. 发明授权
    • Silver halide color photographic material containing color stain
inhibitors and discoloring inhibitors
    • 含有染色抑制剂和变色抑制剂的卤化银彩色照相材料
    • US5242785A
    • 1993-09-07
    • US873340
    • 1992-04-20
    • Masakazu MorigakiNobuo Seto
    • Masakazu MorigakiNobuo Seto
    • G03C7/30G03C7/392
    • G03C7/39296G03C7/3005G03C7/39208G03C7/39284
    • A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide color photographic material contains (1) at least one compound selected from the group consisting of compounds represented by the general formula (I), (II) or (III) and dimers or higher polymers containing at least one moiety derived from the compounds, and (2) at least one compound selected from the group consisting of organic color fading preventing agents represented by the general formula (IV) and dimers or higher polymers containing at least one moiety derived from the agents, organic metal complexes containing copper, cobalt, nickel, palladium or platinum as the central metal and having at least one organic ligand having at least one conformation and dimers or higher polymers containing at least one moiety derived from the complexes: ##STR1## wherein R.sub.30 represents an aliphatic group, an aromatic group or a heterocyclic group; R.sub.31 represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group or ##STR2## W represents --O--, --S-- or ##STR3## wherein R.sub.30 and R.sub.31, or R.sub.35 and R.sub.30 or R.sub.31 may be connected to each other to form a 5-membered to 7-membered ring.
    • 一种卤化银彩色照相材料,其包含其上具有至少一个卤化银乳剂层的载体,其中所述卤化银彩色照相材料含有(1)至少一种选自由通式(I)表示的化合物, (II)或(III)和含有至少一个衍生自化合物的部分的二聚体或更高级聚合物,和(2)至少一种选自由通式(IV)表示的有机防褪色剂和 含有至少一个衍生自试剂的部分的二聚体或更高级聚合物,含有铜,钴,镍,钯或铂作为中心金属的有机金属络合物,并且具有至少一个具有至少一个构象的有机配体和二聚体或更高级聚合物 (II)RZ(III)R30WR31(Ⅳ)其中R30表示脂族基团,芳香族基团 基团或杂环基团; R 31表示氢原子,脂族基团,芳族基团,杂环基,W表示-O-,-S-或者其中R 30和R 31或R 35和R 30或R 31可以连接到每个 另外形成5元至7元环。
    • 20. 发明授权
    • Silver halide color photosensitive material
    • 卤化银色感光材料
    • US5190853A
    • 1993-03-02
    • US440298
    • 1989-11-22
    • Nobuo SetoMasakazu Morigaki
    • Nobuo SetoMasakazu Morigaki
    • G03C7/30
    • G03C7/3013
    • A silver halide color photosensitive material is disclosed. The photosensitive material comprises a support and a hydrophilic colloidal layer containing a yellow coupler. According to the present invention, the layer further contains a color image stabilizer in an amount of 10 to 200 mole % based on the amount of the yellow coupler. The color image stabilizer and the yellow coupler are together contained in droplets of a medium which are dispersed in the layer. The color image stabilizer is an organic compound having the following formula [I] or [II]: ##STR1## in which each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently is hydrogen, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxycarbonyl group, an aryloxycarbonyl group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphoryl group, a carbamoyl group or a sulfamoyl group; each of R.sup.5 and R.sup.6 independently is hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a phosphoryl group, a sulfinyl group, an alkylcarbamoyl group, an arylcarbamoyl group, an alkylsulfamoyl group, an arylsulfamoyl group, an alkoxycarbonyl group or an aryloxycarbonyl group; and Y is a non-metallic atomic group which forms, together with the two nitrogen atoms, a 5- to 8-membered heterocyclic ring.
    • 公开了一种卤化银色感光材料。 感光材料包括载体和含有黄色成色剂的亲水胶体层。 根据本发明,该层还包含基于黄色成色剂的量的10至200摩尔%的彩色图像稳定剂。 彩色图像稳定器和黄色耦合器一起被包含在分散在该层中的介质的液滴中。 彩色图像稳定剂是具有下式[I]或[II]的有机化合物:其中R 1,R 2,R 3和R 4各自独立地为氢,烷基 烯基,芳基,杂环基,烷氧基羰基,芳氧基羰基,酰基,磺酰基,亚磺酰基,磷酰基,氨基甲酰基或氨磺酰基; R 5和R 6各自独立地为氢,烷基,环烷基,烯基,环烯基,芳基,杂环基,酰基,磺酰基,磷酰基,亚磺酰基, 烷基氨基甲酰基,芳基氨基甲酰基,烷基氨磺酰基,芳基氨磺酰基,烷氧基羰基或芳氧基羰基; Y是与两个氮原子一起形成5-至8-元杂环的非金属原子团。