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    • 13. 发明授权
    • High rate metal oxyhalide cells
    • 高速金属卤氧化物细胞
    • US4710437A
    • 1987-12-01
    • US818072
    • 1986-01-13
    • Narayan Doddapaneni
    • Narayan Doddapaneni
    • H01M4/66H01M4/90H01M6/14H01M10/36
    • H01M6/14H01M4/663H01M4/9008
    • Improved catalysts for the reduction of oxyhalide depolarizers such as SOCl.sub.2 and SO.sub.2 Cl.sub.2 in active-metal non-aqueous cells are provided which are easier to prepare and less expensive than phthalocyanine complexes and which are generally more stable in the cell environment. These catalysts include certain macrocyclic complexes of Schiff's base prepared by the reaction of an aldehyde with a primary diamine. The preferred embodiments include mononuclear metal macrocyclic complexes made from salicylaldehyde and o-phenylenediamine and binuclear metal macrocyclic complexes of 5-methyl isophthalaldehyde and 1,3-diaminopropane.
    • 提供了改进的用于还原卤化物去极化剂如活性金属非水电解液中的SOCl 2和SO 2 Cl 2的催化剂,其比酞菁络合物更容易制备并且更便宜,并且其在细胞环境中通常更稳定。 这些催化剂包括通过醛与伯二胺反应制备的希夫碱的某些大环络合物。 优选的实施方案包括由水杨醛和邻苯二胺制备的单核金属大环络合物和5-甲基间苯二醛和1,3-二氨基丙烷的双核金属大环络合物。