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    • 13. 发明授权
    • Sulfur oxide/nitrogen oxide trap system and method for the protection of nitrogen oxide storage reduction catalyst from sulfur poisoning
    • 硫氧化物/氮氧化物捕集系统和氮氧化物储存还原催化剂从硫中毒的保护方法
    • US07389638B2
    • 2008-06-24
    • US11179372
    • 2005-07-12
    • Walter WeissmanEl Mekki El Malki
    • Walter WeissmanEl Mekki El Malki
    • F01N3/00
    • F01N3/0814F01N3/035F01N3/0842F01N3/085F01N3/106F01N13/009F01N2240/40F01N2510/0684F01N2570/04F01N2610/04
    • The present invention relates to an improved exhaust gas cleaning system and method for a combustion source comprising a hydrogen generation system, a sulfur oxides trap, and a nitrogen storage reduction (NSR) catalyst trap. The improved exhaust gas cleaning system and method of the present invention also provides for a water-gas-shift catalyst between the sulfur oxides trap and the NSR catalyst trap, and a clean-up catalyst downstream of the NSR catalyst trap. The invention provides also a sulfur trap regenerable at moderate temperatures with rich pulses, rather than at high temperatures. The improved exhaust gas cleaning system of the present invention provides for the sulfur released from the sulfur trap to pass through the nitrogen oxide trap with no or little poisoning of NOx storage and reduction sites, which significantly improves NSR catalyst trap lifetime and performance to meet future emissions standards. The disclosed exhaust gas cleaning systems are suitable for use in internal combustion engines (e.g., diesel, gasoline, CNG) which operate with lean air/fuel ratios over most of the operating period.
    • 本发明涉及一种用于燃烧源的改进的废气净化系统和方法,其包括氢气产生系统,硫氧化物捕集器和氮储存还原(NSR)催化剂阱。 本发明的改进的废气净化系统和方法还提供了硫氧化物捕集器和NSR催化剂捕集器之间的水煤气变换催化剂以及NSR催化剂捕集器下游的净化催化剂。 本发明还提供了在中等温度下可富含脉冲而不是在高温下可再生的硫阱。 本发明的改进的废气净化系统提供从硫阱中释放的硫通过氮氧化物捕集器,没有或少量存在和少量的NO x x储存和还原位点,这显着地改善了NSR 催化剂陷阱寿命和性能,以满足未来的排放标准。 所公开的废气清洁系统适用于在大部分操作周期内以稀薄空气/燃料比运行的内燃机(例如柴油,汽油,CNG)。