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11. 发明申请

US20060175684A1 Organosilicon compound 有权
标题翻译：有机硅化合物
公开(公告)号：US20060175684A1
公开(公告)日：2006-08-10
申请号：US11316847
申请日：2005-12-27
申请人： Hisao Oikawa , Mikio Yamahiro , Koji Ohguma , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
发明人： Hisao Oikawa , Mikio Yamahiro , Koji Ohguma , Nobumasa Ootake , Kenichi Watanabe , Kohji Ohno , Yoshinobu Tsujii , Takeshi Fukuda
IPC分类号： H01L23/58 , H01L21/31
CPC分类号： C07F7/21
摘要： Since the majority of conventional organic/inorganic composite materials are obtained by mechanical blending of a silsesquioxane and an organic polymer or other means, it was extremely difficult to control the structure of the composite as a molecular agglomerate. In order to solve such a problem, the invention is to provide a silicon compound represented by Formula (1). This novel silicon compound has a living radical polymerization initiating ability for addition polymerizable monomers of a wide range. In Formula (1), R1 is hydrogen, an alkyl, an aryl, or an arylalkyl; R2 is an alkyl, phenyl, or cyclohexyl; and A is a group having a polymerization initiating ability for addition polymerizable monomers.
摘要翻译：由于大多数常规有机/无机复合材料是通过机械共混倍半硅氧烷和有机聚合物或其它方法获得的，所以非常难以控制复合材料的结构作为分子聚集体。为了解决这个问题，本发明提供一种由式（1）表示的硅化合物。该新型硅化合物具有广泛范围的可加聚单体的活性自由基聚合引发能力。在式（1）中，R 1是氢，烷基，芳基或芳基烷基; R 2是烷基，苯基或环己基; A是具有加成聚合性单体的聚合引发能力的基团。

12. 发明申请

US20070004932A1 Silicon compound and a production process for silicon compound 有权
标题翻译：硅化合物和硅化合物的生产工艺
公开(公告)号：US20070004932A1
公开(公告)日：2007-01-04
申请号：US11517457
申请日：2006-09-08
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe
IPC分类号： C07F7/04 , C07F7/08
CPC分类号： C07F7/21 , C07F7/0876
摘要： The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T8-silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material. A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R1 group is the same as R1 in formula (1), and A1 is an organic functional group containing an acyloxy group.
摘要翻译：本发明的目的是提供一种具有酯型有机官能团的新型硅化合物和通过使用所述硅来提供具有羟基的T 8 -S-倍半硅氧烷化合物的新方法化合物作为原料。通过以式（2）表示的硅化合物为特征的制造方法得到式（1）所示的硅化合物。其中：在式（1）中，七个R 1基团中的每一个独立地选自氢，烷基，取代或未取代的芳基和取代或未取代的芳基烷基和A 2， / SUP>是羟基末端有机官能团，并且在式（2）中，R 1和R 2各自与式（1）中的R 1相同， A 1是含有酰氧基的有机官能团。

13. 发明授权

US07129370B2 Silicon compound and a production process for silicon compound 有权
标题翻译：硅化合物和硅化合物的生产工艺
公开(公告)号：US07129370B2
公开(公告)日：2006-10-31
申请号：US10664151
申请日：2003-09-17
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe
IPC分类号： C07F7/04
CPC分类号： C07F7/21 , C07F7/0876
摘要： The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T8-silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material.A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R1 group is the same as R1 in formula (1), and A1 is an organic functional group containing an acyloxy group.
摘要翻译：本发明的目的是提供一种具有酯型有机官能团的新型硅化合物和通过使用所述硅来提供具有羟基的T 8 -S-倍半硅氧烷化合物的新方法化合物作为原料。通过以式（2）表示的硅化合物为特征的制造方法得到式（1）所示的硅化合物。其中：在式（1）中，七个R 1基团中的每一个独立地选自氢，烷基，取代或未取代的芳基和取代或未取代的芳基烷基和A 2， / SUP>是羟基末端有机官能团，并且在式（2）中，R 1和R 2各自与式（1）中的R 1相同， A 1是含有酰氧基的有机官能团。

14. 发明授权

US07563917B2 Silicon compound and a production process for silicon compound 有权
标题翻译：硅化合物和硅化合物的生产工艺
公开(公告)号：US07563917B2
公开(公告)日：2009-07-21
申请号：US11517457
申请日：2006-09-08
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe
IPC分类号： C07F7/21
CPC分类号： C07F7/21 , C07F7/0876
摘要： The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T8-silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material.A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R1 group is the same as R1 in formula (1), and A1 is an organic functional group containing an acyloxy group.
摘要翻译：本发明的目的是提供一种具有酯型有机官能团的新型硅化合物和通过使用所述硅化合物作为起始原料提供具有羟基的T8-倍半硅氧烷化合物的新方法。通过以式（2）表示的硅化合物为特征的制造方法得到式（1）所示的硅化合物。其中：在式（1）中，七个R 1基团各自独立地选自氢，烷基，取代或未取代的芳基和取代或未取代的芳基烷基，A2是羟基末端有机官能团，并且在式 2）中，R 1基与式（1）中的R 1相同，且为含有酰氧基的有机官能团。

15. 发明申请

US20050033077A1 Production process for silicon compound and the same 有权
标题翻译：硅化合物的生产工艺和相同
公开(公告)号：US20050033077A1
公开(公告)日：2005-02-10
申请号：US10664151
申请日：2003-09-17
申请人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe
发明人： Mikio Yamahiro , Hisao Oikawa , Kenya Ito , Masami Tanaka , Nobumasa Ootake , Kenichi Watanabe
IPC分类号： C07F7/08 , C07F7/21 , C07F7/04
CPC分类号： C07F7/21 , C07F7/0876
摘要： The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T8-silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material. A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R1 group is the same as R1 in formula (1), and A1 is an organic functional group containing an acyloxy group.
摘要翻译：本发明的目的是提供一种具有酯型有机官能团的新型硅化合物和通过使用所述硅化合物作为起始原料提供具有羟基的T8-倍半硅氧烷化合物的新方法。通过以式（2）表示的硅化合物为特征的制造方法得到式（1）所示的硅化合物。其中：在式（1）中，七个R 1基团中的每一个独立地选自氢，烷基，取代或未取代的芳基和取代或未取代的芳烷基，A 2是羟基末端有机官能团基团，式（2）中，R 1各自与式（1）中的R 1相同，A 1为含有酰氧基的有机官能团。

16. 发明申请

US20050049381A1 Silicon compounds 审中-公开
标题翻译：硅化合物
公开(公告)号：US20050049381A1
公开(公告)日：2005-03-03
申请号：US10482816
申请日：2002-07-04
申请人： Mikio Yamahiro , Kazuhiro Yoshida , Yasuhiro Yamamoto , Kenichi Watanabe , Nobumasa Ootake
发明人： Mikio Yamahiro , Kazuhiro Yoshida , Yasuhiro Yamamoto , Kenichi Watanabe , Nobumasa Ootake
IPC分类号： C07F7/18 , C08F2/46 , C08F4/00 , C08G77/00 , C08G77/392
CPC分类号： C08L83/08 , C08G77/388 , C08G77/392
摘要： The present invention relates to a novel silicon compound characterized by having a polymerization-initiating ability to polymerizable monomers and a polymer obtained using the same. Provided is a so-called organic-inorganic composite material of cage type silsesquioxane in which an organic substituent is bonded to a silicon atom and an organic polymer. A preparing method thereof is mixing with an organic polymer or copolymerization making use of a polymerizable functional group of cage type silsesquioxane. However, it is considered to be very difficult to evenly disperse an inorganic component in an organic polymer in either method and maintain characteristics thereof. The present invention provides a silicon compound represented by Formula (1): in Formula (1), A1 is a group having a polymerization-initiating ability to a monomer; R1 is alkyl having 2 to 10 carbon atoms; in these alkyls, at least one hydrogen may be replaced by halogen; one —CH2— may be replaced by —O—; one hydrogen may be replaced by an aromatic group or an alicyclic group; this aromatic group or alicyclic group may have a substituent; R2 and R3 are independently alkyl having 1 to 8 carbon atoms, phenyl or cyclohexyl; n is an integer of 2 to 30; e is 0 or 1; a is an integer of 1 to 2n; b is an integer of 0 to (2n−1); c is an integer of 0 to (2n−1); and the total of a, b and c is 2n. The preferred examples of A1 are a group having halogenated alkylphenyl, a group having an MgBr group and a group having a dithiocarbamate group. If initiating the polymerization of, for example, an acrylic monomer with this silsesquioxane derivative acting as a starting point, a very homogeneous organic-inorganic composite material is obtained without causing coagulation of silsesquioxane, and therefore problems in conventional methods are solved.
摘要翻译：本发明涉及一种新型的硅化合物，其特征在于对可聚合单体具有聚合引发能力和使用该聚合物获得的聚合物。本发明提供一种有机取代基与硅原子和有机聚合物结合的笼式倍半硅氧烷的有机 - 无机复合材料。其制备方法是与有机聚合物混合或使用笼型倍半硅氧烷的可聚合官能团进行共聚。然而，认为在任一方法中均匀分散无机组分到有机聚合物中并保持其特性是非常困难的。本发明提供由式（1）表示的硅化合物：在式（1）中，A 1是具有对单体的聚合引发能力的基团; R 1是具有2至10个碳原子的烷基; 在这些烷基中，至少一个氢可以被卤素取代; 一个-CH 2 - 可以被-O-取代; 一个氢可以被芳族基团或脂环族基团取代; 该芳族基团或脂环基可以具有取代基; R 2和R 3独立地为具有1至8个碳原子的烷基，苯基或环己基; n为2〜30的整数， e为0或1; a为1〜2n的整数; b为0〜（2n-1）的整数。 c为0〜（2n-1）的整数。并且a，b和c的总和是2n。 A 1的优选实例是具有卤代烷基苯基，具有MgBr基团和具有二硫代氨基甲酸酯基团的基团。如果使用该倍半硅氧烷衍生物作为起始点的丙烯酸类单体的聚合引发，则不会引起倍半硅氧烷的凝结而获得非常均匀的有机 - 无机复合材料，因此解决了常规方法中的问题。

17. 发明申请

US20050215807A1 Silsesquioxane derivative 有权
标题翻译：倍半硅氧烷衍生物
公开(公告)号：US20050215807A1
公开(公告)日：2005-09-29
申请号：US11121076
申请日：2005-05-04
申请人： Yoshitaka Morimoto , Kenya Ito , Hisaoi Oikawa , Mikio Yamahiro , Kenichi Watanabe , Nobumasa Ootake
发明人： Yoshitaka Morimoto , Kenya Ito , Hisaoi Oikawa , Mikio Yamahiro , Kenichi Watanabe , Nobumasa Ootake
IPC分类号： C07F7/21 , C08G77/04
CPC分类号： C08G77/04
摘要： If chlorosilane is used in order to introduce a functional group into a silsesquioxane derivative having Si—OH, by-produced hydrogen chloride has to be treated. However, if alkoxysilane is substituted for chlorosilane, the long reaction time is required. A production process for a silsesquioxane derivative represented by Formula (2) characterized by using a compound represented by Formula (1), has been developed in order to solve such problems of conventional techniques.
摘要翻译：如果使用氯硅烷以将官能团引入具有Si-OH的倍半硅氧烷衍生物中，则必须处理副产的氯化氢。然而，如果烷氧基硅烷代替氯代硅烷，则需要较长的反应时间。为了解决现有技术的问题，已经开发出由式（2）表示的倍半硅氧烷衍生物的制备方法，其特征在于使用由式（1）表示的化合物。

18. 发明授权

US07235619B2 Silsesquioxane derivative 有权
标题翻译：倍半硅氧烷衍生物
公开(公告)号：US07235619B2
公开(公告)日：2007-06-26
申请号：US11121076
申请日：2005-05-04
申请人： Yoshitaka Morimoto , Kenya Ito , Hisaoi Oikawa , Mikio Yamahiro , Kenichi Watanabe , Nobumasa Ootake
发明人： Yoshitaka Morimoto , Kenya Ito , Hisaoi Oikawa , Mikio Yamahiro , Kenichi Watanabe , Nobumasa Ootake
IPC分类号： C08G77/16
CPC分类号： C08G77/04
摘要： A silsesquioxane derivative represented by Formula (2): wherein R is hydrogen, an alkyl, an aryl, or an arylalkyl; and X is hydrogen, chlorine, a functional group, or a group having a functional group.
摘要翻译：由式（2）表示的倍半硅氧烷衍生物：其中R是氢，烷基，芳基或芳基烷基; X为氢，氯，官能团或具有官能团的基团。

19. 发明授权

US07291747B2 Silicon compounds and process for preparation thereof 有权
标题翻译：硅化合物及其制备方法
公开(公告)号：US07291747B2
公开(公告)日：2007-11-06
申请号：US10478483
申请日：2002-05-17
申请人： Hisao Oikawa , Kenichi Watanabe , Nobumasa Ootake , Kazuhiro Yoshida , Keizou Iwatani
发明人： Hisao Oikawa , Kenichi Watanabe , Nobumasa Ootake , Kazuhiro Yoshida , Keizou Iwatani
IPC分类号： C07F7/00
CPC分类号： C07F7/21
摘要： An organic silicon compound, having high reactivity, represented by the following Formula (1): wherein R and M are defined in the specification. The organic silicon compound is produced by reacting polysilsesquioxane, which is obtained by hydrolyzing a silane compound having three hydrolyzable groups and represented by the following Formula (2), with a monovalent alkaline metal hydroxide in an organic solvent, or by subjecting the silane compound having three hydrolyzable groups to hydrolysis and polycondensation in the presence of an organic solvent and an alkaline metal hydroxide: R—Si X3 (2) wherein R is the same as in Formula (1) and X represents a hydrolyzable group.
摘要翻译：具有高反应性的有机硅化合物由下式（1）表示：其中R和M在说明书中定义。有机硅化合物是通过使有机硅溶胶中的硅烷化合物与有机溶剂中的一价碱金属氢氧化物水解而得到的聚倍半硅氧烷，其通过将具有3个可水解基团的硅烷化合物水解，由下式（2）三个可水解基团在有机溶剂和碱金属氢氧化物存在下进行水解和缩聚：<？in-line-formula description =“In-line formula”end =“lead”？> R-Si X 3 （2）<？in-line-formula description =“In-line formula”end =“tail”？>其中R与式（1）中相同，X表示可水解基团。

20. 发明授权

US07373060B2 Optical waveguide using polymer composed of silsesquioxane derivative 有权
标题翻译：光波导使用由倍半硅氧烷衍生物构成的聚合物
公开(公告)号：US07373060B2
公开(公告)日：2008-05-13
申请号：US11363177
申请日：2006-02-28
申请人： Hideshi Satake , Nobuyuki Ootsuka , Yasuhiro Yamamoto , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
发明人： Hideshi Satake , Nobuyuki Ootsuka , Yasuhiro Yamamoto , Kenya Ito , Nobumasa Ootake , Kazuhiro Yoshida
IPC分类号： G02B6/02 , C08G77/04
CPC分类号： C08G77/38 , G02B6/02033
摘要： An optical waveguide is produced by using a polymer obtained by using a silsesquioxane derivative represented by the formula (1-0). In the formula (1-0), R0 independently represents hydrogen, alkyl having 1 to 40 carbon atoms in which optional hydrogen may be replaced by fluorine and optional —CH2— may optionally be replaced by —O—, —CH═CH—, cycloalkylene, or cycloalkenylene, aryl in which optional hydrogen may optionally be replaced by halogen, or with alkyl having 1 to 20 carbon atoms whereby optional hydrogen may be replaced by fluorine and optional —CH2— may be replaced by —O—, —CH═CH—, cycloalkylene, or phenylene, or arylalkyl in which optional hydrogen in the aryl may be replaced by halogen or alkyl having 1 to 20 carbon atoms, and hydrogen in the alkylene of the arylalkyl may be replaced by fluorine, and optional —CH2— in the alkylene of the arylalkyl may be replaced by —O—, —CH═CH—, or cycloalkylene, and Y is a group represented by the formula (a) or (b):
摘要翻译：通过使用通过使用由式（1-0）表示的倍半硅氧烷衍生物获得的聚合物制备光波导。在式（1-0）中，R 0独立地表示氢，具有1至40个碳原子的烷基，其中任选的氢可以被氟取代，并且任选的-CH 2 - 可以任选地被-O-，-CH-CH-，亚环烷基或环亚烯基取代，其中任选的氢可以任选被卤素取代的芳基或具有1至20个碳原子的烷基，由此任选的氢可被氟代替和任选的-CH 2 - 可以被-O - ， - CH-，亚环烷基或亚苯基取代，或芳基烷基，其中芳基中任选的氢可被卤素或具有1 至20个碳原子，芳基烷基的亚烷基中的氢可以被氟代替，并且芳基烷基的亚烷基中任选的-CH 2 - 可以被-O - ， - CH-CH - 或亚环烷基，Y为由式（a）或（b）表示的基团：

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