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    • 17. 发明申请
    • Process for the Preparation of Random Radical Copolymers, and Active Substance Compositions Obtainable Therefrom
    • 制备随机自由基共聚物及其可获得的活性物质组合物的方法
    • US20110237439A1
    • 2011-09-29
    • US13132117
    • 2009-11-30
    • Holger TuerkCedric DielemanHans-Guenter BohrmannSebastian Koltzenburg
    • Holger TuerkCedric DielemanHans-Guenter BohrmannSebastian Koltzenburg
    • A01N25/00C08F2/06C08F20/58A01P3/00A01P13/00
    • A01N25/10A01N43/653A01N47/24C08F2/04C08F2/06C08F220/06C08F220/18C08F220/56C08F220/58A01N2300/00
    • A process for the preparation of random radical copolymers which comprises a) at least one olefinically unsaturated sulfonic acid of the formula (I), where n is 0 to 10; X is 0 or NR5; R1 is hydrogen or methyl; R2, R3 independently of one another are hydrogen or C1- to C6-alkyl and R5 is hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, it being possible for the aryl radicals to be monosubstituted or polysubstituted, salts thereof or mixtures of acid and salts and b) at least two structurally different olefinically unsaturated monomers of the formula (II), where Y is O or NR7; R5 is hydrogen or methyl; R6 is alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 is hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, it being possible for the aryl radicals to be monosubstituted or polysubstituted, and c) if appropriate, one or more olefinically unsaturated monomers which differ structurally from components (a) and (b), d) at least one initiator being dissolved either (i) in a solvent mixture comprising water and a water-soluble organic solvent with a boiling point of less than 140° C. or (ii) being dissolved in one or more pure alcohols by heating, and being polymerized in solution, where the polymer formed remains in solution. The copolymers which are obtainable by the process are suitable as formulation adjuvants in agrochemical active substance compositions.
    • 一种制备无规自由基共聚物的方法,其包括a)至少一种式(I)的烯属不饱和磺酸,其中n为0至10; X为0或NR5; R1是氢或甲基; R 2,R 3彼此独立地是氢或C 1 -C 6 - 烷基,R 5是氢,烷基,芳基,烷基芳基,芳基烷基,烷氧基烷基,芳氧基烷基,烷氧基芳基,羟基烷基,(二)烷基氨基烷基,(二)烷基氨基芳基,(二) 芳基氨基烷基,烷基芳基氨基烷基或烷基芳基氨基芳基,芳基可以是单取代或多取代的,其盐或酸和盐的混合物,以及b)至少两种结构不同的具有式(II)的烯属不饱和单体,其中Y是O或 NR7; R5是氢或甲基; R6是烷基,羟基烷基,(二)烷基氨基烷基或(二)烷基氨基芳基,R7是氢,烷​​基,芳基,烷基芳基,芳基烷基,烷氧基烷基,芳氧基烷基,烷氧基芳基,羟基烷基,(二)烷基氨基烷基,(二)烷基氨基芳基,(二) 烷基芳基氨基烷基或烷基芳基氨基芳基,芳基可以被单取代或多取代,以及c)如果合适的话,一种或多种在结构上与组分(a)和(b)不同的烯属不饱和单体,d)至少一个引发剂 (i)在包含水和沸点小于140℃的水溶性有机溶剂的溶剂混合物中溶解,或(ii)通过加热溶解在一种或多种纯醇中,并在溶液中聚合, 所形成的聚合物保留在溶液中。 可通过该方法获得的共聚物适合作为农药活性物质组合物中的制剂佐剂。
    • 20. 发明申请
    • Preparation Comprising at Least One Conazole Fungicide
    • 包括最少一种针唑杀真菌剂的制备
    • US20080318785A1
    • 2008-12-25
    • US11918522
    • 2006-04-13
    • Sebastian KoltzenburgPeter DomboGunter OetterChristian KrugerWolfgang SchrofMatthias Bratz
    • Sebastian KoltzenburgPeter DomboGunter OetterChristian KrugerWolfgang SchrofMatthias Bratz
    • A01N43/653C08F228/02A01P3/00C08F26/06
    • C08F220/60A01N25/10A01N25/14A01N43/653C08F220/18C08F220/38A01N2300/00
    • The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant-protective substance (active substance 2) whose water solubility at a temperature of 20° C. is less than 20 g/l, c) at least one type of copolymer CP consisting of M monomers comprising α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and β) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, α) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, β1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20° C. is less than 30 g/l and β2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20° C. is greater than 50 g/l.
    • 本发明涉及制剂,特别是含有至少两种不同的活性植物保护物质的混合物的植物保护制剂,其中a)至少一种活性物质选自唑类(活性物质1)和b)另一种 在20℃温度下的水溶性小于20g / l的活性植物保护物质(活性物质2),c)由M单体组成的至少一种共聚物CP,包括α)至少一种类型的 包含至少一个磺酸基团的单烯属不饱和单体M1和β)至少一种中性单烯属不饱和单体M2,其中活性物质1与另一种活性植物保护物质2的定量比范围为1:10至10 :1。 所述发明还涉及新型共聚物CP,其以由至少三种不同单烯属不饱和单体M组成的聚合物的形式体现并且以聚合形式包含α)至少一种类型的单烯属不饱和单体M1,其包含在 至少一种磺酸基团,β1)至少一种类型的中和单烯属不饱和单体M2b,其在20℃温度下的水溶性小于30g / l和β2)至少一种中性单烯属不饱和单体M2b,其中 在20℃的温度下的水溶解度大于50g / l。