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11. 发明申请

US20110313213A1 PURIFICATION OF ALCOHOLS PRIOR TO THEIR USE IN THE PRESENCE OF AN ACID CATALYST 有权
标题翻译：在酸性催化剂存在下使用醇类物质的纯化
公开(公告)号：US20110313213A1
公开(公告)日：2011-12-22
申请号：US13131407
申请日：2009-11-27
申请人： Delphine Minoux , Walter Vermeiren , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Delphine Minoux , Walter Vermeiren , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C29/74
CPC分类号： C07C29/76 , C07C1/24 , C07C29/74 , C07C29/90 , C07C11/04 , C07C31/08
摘要： Process for the purification of an alcohol in the course of a process comprising: (1) providing a reaction zone (C) comprising an acid type catalyst; (2) providing a reaction zone (B) comprising an acid adsorbent material; (3) providing an alcohol stream comprising impurities; (4) introducing the alcohol stream of (3) into the reaction zone (B) and bringing said stream into contact with the acid adsorbent material at conditions effective to reduce the amount of impurities having an adverse effect on the acid type catalyst of the reaction zone (C); (5) recovering from step (4) an alcohol stream and introducing it into the reaction zone (C); (6) optionally introducing one or more reactants (R) into the reaction zone (C); (7) operating said reaction zone (C) at conditions effective to recover a valuable effluent.
摘要翻译：在包括以下步骤的过程中醇的纯化方法：（1）提供包含酸型催化剂的反应区（C）; （2）提供包含酸吸附材料的反应区（B）; （3）提供包含杂质的醇流; （4）将（3）的醇流引入反应区（B）中，并使所述物流与酸吸附剂材料接触，有效地减少对反应的酸型催化剂具有不利影响的杂质的量区（C）; （5）从步骤（4）中回收醇流并将其引入反应区（C）中; （6）任选地将一种或多种反应物（R）引入反应区（C）中; （7）在有效回收有价值流出物的条件下操作所述反应区（C）。

12. 发明授权

US09056807B2 Process to make olefins from isobutanol 有权
标题翻译：从异丁醇制备烯烃的方法
公开(公告)号：US09056807B2
公开(公告)日：2015-06-16
申请号：US13813168
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C1/24 , C07C4/06 , C07C6/04 , C10G3/00 , C12P5/02 , C12P7/16 , B01J29/40
CPC分类号： C07C1/24 , B01J29/40 , B01J2229/42 , C07C1/22 , C07C4/06 , C07C6/04 , C07C2529/40 , C08F10/02 , C10G3/42 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： The present invention relates to a process for the conversion of an alcohol mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 450° C. in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，任选的水，任选的惰性组分，b）在有效使至少一部分异丁醇和其它醇脱水的条件下，使所述物流与催化剂（A1）在高于450℃的温度下在所述反应器（A）中接触， c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的混合物（A）的醇，各种烃和步骤a）的任选的惰性组分的流出物， d）将步骤c）的所述流出物分馏以产生至少一种乙烯流，丙烯流，基本上由具有4个碳原子或更多的烃组成的级分，水和步骤a）的任选的惰性组分，任选地将乙烯全部回收或在par 在反应器（A）的入口处，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分。

13. 发明申请

US20130204059A1 PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 有权
标题翻译：从ISOBUTANOL制造OLEFINS的过程
公开(公告)号：US20130204059A1
公开(公告)日：2013-08-08
申请号：US13813115
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C2/12
CPC分类号： C07C1/24 , C07C1/20 , C07C1/22 , C07C2/12 , C07C4/06 , C07C11/06 , C07C29/00 , C07C2529/40 , C07C2529/85 , C08F210/02 , C08F210/06 , C12P7/16 , Y02P30/42
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), mixed with a stream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 500° C. in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，与包含具有4个或更多碳原子的烯烃（C 4 +烯烃），任选的水，任选的惰性组分的流（D1）混合，b）在所述的温度高于500℃的温度下使所述料流与催化剂（A1）接触反应器（A）在有效使至少一部分异丁醇和其它醇脱水的条件下（如果有的话）并且产生裂化，c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的醇混合物（A），各种烃和步骤a）的任选的惰性组分，d）将步骤c）的所述流出物分馏以产生至少一种乙烯流，丙烯料流，基本上由具有4碳原子的烃组成的馏分原子或更多，水和步骤a）的任选的惰性组分，任选地在反应器（A）的入口处全部或部分地循环乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多碳原子的烃组成的馏分，。

14. 发明申请

US20120271085A1 METHOD FOR PRODUCING DISTILLATE FROM A HYDROCARBON FEED, COMPRISING ALCOHOL CONDENSATION 审中-公开
标题翻译：用于生产来自油料进料的蒸馏物的方法，包含酒精浓缩
公开(公告)号：US20120271085A1
公开(公告)日：2012-10-25
申请号：US13501382
申请日：2010-10-13
申请人： Nikolai Nesterenko , Delphine Minoux , Sander Van Donk , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/20
CPC分类号： C07C29/34 , B01J29/40 , C07C2529/40 , C10G3/42 , C10G3/45 , C10G50/00 , C10G2300/1011 , C10G2300/1088 , C10G2300/4018 , C10G2300/4081 , C10G2300/70 , C10G2400/22 , Y02P30/42 , C07C31/12 , C07C31/125
摘要： The invention relates to a method for converting a hydrocarbon feed containing C3-C10 olefins into a distillate, whereby the quantities of olefins having a chain length that is too short can be reduced in order to be exploited (typically C10 or even less) and the C10+ molecule yields can be increased, while controlling the exothermicity of the oligomerisation reactions. This effect is obtained by oligomerising the hydrocarbon feed in the presence of at least one part of the products resulting from the pre-conversion, by means of condensation, of light oxygen molecules (comprising at least one alcohol having at least two carbon atoms) which can originate from biomass.
摘要翻译：本发明涉及一种将含有C 3 -C 10烯烃的烃进料转化成馏出物的方法，由此可以减少链长过短的烯烃的用量（通常为C10或更小），并且可以增加C10 +分子的产率，同时控制低聚反应的放热。这种效果是通过在至少一部分产物的存在下，通过缩合产生的轻氧分子（包含至少一种具有至少两个碳原子的至少一个醇）而产生的产物的低聚来获得的。可以源自生物量。

15. 发明申请

US20120271081A1 METHOD FOR THE PRODUCTION OF C10+ HYDROCARBONS FROM HETEROATOMIC ORGANIC COMPOUNDS 审中-公开
标题翻译：用于从异质有机化合物生产C10 +碳氢化合物的方法
公开(公告)号：US20120271081A1
公开(公告)日：2012-10-25
申请号：US13501408
申请日：2010-10-13
申请人： Nikolai Nesterenko , Delphine Minoux , Sander Van Donk , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C2/88 , C07C2/04
CPC分类号： B01J29/40 , B01J37/0009 , B01J2229/42 , C07C2529/40 , C10G3/49 , C10G50/00 , C10G2300/1011 , C10G2300/202 , C10G2300/4018 , C10G2300/4081 , C10G2300/802 , C10G2400/22 , Y02P30/20
摘要： The invention relates to a process for producing distillate from a charge of heteroatomic organic compounds comprising at least one heteroatom chosen from oxygen, sulfur and halogen, alone or in combination, in which the treatment of the charge comprises at least one step of conversion of the heteroatomic organic compounds into olefins performed in a first conversion zone, and, in at least a second oligomerization zone, a step of oligomerization of olefins originating at least partly from the conversion zone, in the presence of at least 0.5% by weight of oxygenated compounds, in order to produce a distillate. By virtue of the presence of oxygenated compounds during the oligomerization, this process makes it possible to improve the yield of distillate, making it possible to obtain a higher degree of oligomerization relative to the oligomerization of the same charge under the same reaction conditions.
摘要翻译：本发明涉及从包含至少一个选自氧，硫和卤素的杂原子的杂原子有机化合物的电荷中单独或组合生产馏出物的方法，其中电荷的处理包括至少一个转化步骤在第一转化区中进行杂原子有机化合物转化为烯烃，并且在至少第二低聚区中，在至少0.5重量％的氧化化合物的存在下至少部分地由转化区引发的烯烃的低聚步骤，以产生馏出物。由于在低聚期间含氧化合物的存在，该方法使得可以提高馏出物的产率，使得可以在相同反应条件下相对于相同电荷的低聚获得更高的低聚度程度。

16. 发明授权

US09061954B2 Dehydration of alcohols on crystalline silicates 有权
标题翻译：醇在结晶硅酸盐上的脱水
公开(公告)号：US09061954B2
公开(公告)日：2015-06-23
申请号：US12864966
申请日：2009-02-05
申请人： Delphine Minoux , Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk , Jean-Pierre Dath
发明人： Delphine Minoux , Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/20 , C07C1/24 , B01J29/40
CPC分类号： C07C1/24 , B01J29/40 , B01J2229/16 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C2529/40 , Y02P20/52 , C07C11/04
摘要： The present invention relates to a process for the dehydration of at least an alcohol to make at least an olefin, comprising: introducing in a reactor a stream (A) comprising at least an alcohol, optionally water, optionally an inert component, contacting said stream with a catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, recovering from said reactor an olefin containing stream (B), Wherein the catalyst is: a crystalline silicate having a ratio Si/Al of at least about 100, or a dealuminated crystalline silicate, or a phosphorus modified zeolite, the WHSV of the alcohols is at least 2 h−1, the temperature ranges from 280° C. to 500° C. It relates also to the same process as above but wherein the catalyst is a phosphorus modified zeolite and at any WHSV.The partial pressure of the alcohol in the dehydration reactor advantageously ranges from 1.2 to 4 bars absolute (0.12 MPa to 0.4 MPa), the temperature of the dehydration reactor ranges advantageously from 300° C. to 400° C. and the alcohol is selected among ethanol, propanol, butanol and phenylethanol.
摘要翻译：本发明涉及一种使至少一种醇脱水以制备至少一种烯烃的方法，其包括：在反应器中引入至少包含醇，任选的水，任选的惰性组分的物流（A）在有效使至少一部分醇脱水以制备烯烃的条件下在所述反应器中的催化剂，从所述反应器回收含烯烃的料流（B），其中所述催化剂是：具有Si / Al比率的结晶硅酸盐至少约100个，或脱铝的结晶硅酸盐或磷改性沸石，醇的WHSV为至少2h -1，温度范围为280℃至500℃。它还涉及相同的方法如上所述，但是其中催化剂是磷改性沸石并且在任何WHSV。脱水反应器中的醇的分压有利地为1.2至4巴绝对压力（0.12MPa至0.4MPa），脱水反应器的温度有利地为300℃至400℃，醇选自乙醇，丙醇，丁醇和苯乙醇。

17. 发明申请

US20130204057A1 SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS 有权
标题翻译： ISOBUTANOL在酸性催化剂上的同时脱水和同位素同位素
公开(公告)号：US20130204057A1
公开(公告)日：2013-08-08
申请号：US13582759
申请日：2011-03-15
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/24 , C07C5/25
CPC分类号： C07C1/24 , B01J29/85 , C07C5/2518 , C07C5/2775 , C07C11/08 , C07C11/09 , C07C2521/04 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/127
摘要： The present invention (in a first embodiment) relates to a process for the simultaneous dehydration and skeletal isomerisation of isobutanol to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerise at least a portion of the isobutanol to make a mixture of n- butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, Wherein, the WHSV of the isobutanol is at least 1 h−1 or the temperature is from 200° C. to 600° C. and the catalyst is capable to make simultaneously the dehydration and skeletal isomerization of butene. The catalyst is a crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a dealuminated crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a phosphorus modified crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a silicoaluminaphosphate molecular sieve of the group AEL, or a silicated, zirconated or titanated or fluorinated alumina. Advantageously the stream (B) is fractionated in a step d) to produce a n-butenes stream (N) and to remove the essential part of isobutene optionally recycled with stream (A) to the dehydration/isomerization reactor of step b).
摘要翻译：本发明（在第一个实施方案中）涉及同时脱水和骨架异构化异丁醇以制备具有相同数目的碳并基本上由正丁烯和异丁烯组成的基本相应的烯烃的方法，所述方法方法包括：a）在反应器中引入包含异丁醇，任选的水，任选的惰性组分的物流（A），b）在所述反应器中使所述物流与催化剂接触，所述条件有效地脱水和骨架异构化至少部分异丁醇以制备正丁烯和异丁烯的混合物，c）从所述反应器回收流（B），除去水，惰性组分（如果有的话）和未转化的异丁醇（如果有的话）以得到正丁烯和异丁烯的混合物，丁烯，其中异丁醇的WHSV为至少1h-1或温度为200℃至600℃，并且催化剂能够同时进行bu的脱水和骨架异构化泰恩该催化剂是具有Si / Al大于10的FER，MWW，EUO，MFS，ZSM-48，MTT，MFI，MEL或TON的结晶硅酸盐，或FER，MWW，EUO等的脱铝结晶硅酸盐，具有Si / Al大于10的MFS，ZSM-48，MTT，MFI，MEL或TON，或FER，MWW，EUO，MFS，ZSM-48，MTT，MFI，MEL或TON的磷改性结晶硅酸盐，其具有 Si / Al高于10，或AEL的硅铝磷酸盐分子筛，或硅化，锆酸化或钛酸化或氟化氧化铝。有利地，在步骤d）中将流（B）分馏以产生正丁烯料流（N），并除去任选与料流（A）一起循环的异丁烯的主要部分至步骤b）的脱水/异构化反应器。

18. 发明申请

US20120264989A1 METHOD FOR DISTILLATE PRODUCTION BY MEANS OF CATALYTIC OLIGOMERIZATION OF OLEFINS IN THE PRESENCE OF METHANOL AND/OR DIMETHYL ETHER 审中-公开
标题翻译：通过在甲醇和/或二甲醚存在下烯烃催化低聚制备蒸馏法的方法
公开(公告)号：US20120264989A1
公开(公告)日：2012-10-18
申请号：US13501413
申请日：2010-10-13
申请人： Nikolai Nesterenko , Delphine Minoux , Sander Van Donk , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C2/02
CPC分类号： C10G50/00 , C10G2300/1014 , C10G2300/1088 , C10G2300/4018 , C10G2300/4081 , C10G2400/22 , Y02P30/20
摘要： The invention relates to a process for producing distillate by oligomerization starting with a hydrocarbon-based charge in the presence of methanol and/or dimethyl ether, which may especially be of plant origin. By addition of an oxygenated compound, this process makes it possible to reduce the amounts of olefins whose chain length is too short to be exploited (typically C10, or even less) and to increase the yields of C10+ olefins.
摘要翻译：本发明涉及一种通过在甲醇和/或二甲醚存在下由烃类电荷开始的低聚制备馏出物的方法，其可以特别是植物来源。通过加入含氧化合物，该方法可以减少链长太短而不能开发（通常为C10或甚至更少）的烯烃的量，并提高C10 +烯烃的产率。

19. 发明授权

US09056806B2 Process to make olefins from isobutanol 有权
标题翻译：从异丁醇制备烯烃的方法
公开(公告)号：US09056806B2
公开(公告)日：2015-06-16
申请号：US13813115
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C1/20 , C07C4/06 , C07C11/06 , C07C2/12
CPC分类号： C07C1/24 , C07C1/20 , C07C1/22 , C07C2/12 , C07C4/06 , C07C11/06 , C07C29/00 , C07C2529/40 , C07C2529/85 , C08F210/02 , C08F210/06 , C12P7/16 , Y02P30/42
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), mixed with a stream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 500° C. in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，与包含具有4个或更多碳原子的烯烃（C 4 +烯烃），任选的水，任选的惰性组分的流（D1）混合，b）在所述的温度高于500℃的温度下使所述料流与催化剂（A1）接触反应器（A）在有效使至少一部分异丁醇和其它醇脱水的条件下（如果有的话）并且产生裂化，c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的醇混合物（A），各种烃和步骤a）的任选的惰性组分，d）将步骤c）的所述流出物分馏以产生至少一种乙烯流，丙烯料流，基本上由具有4碳原子的烃组成的馏分原子或更多，水和步骤a）的任选的惰性组分，任选地在反应器（A）的入口处全部或部分地循环乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多碳原子的烃组成的馏分，。

20. 发明授权

US08981173B2 Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO process 有权
标题翻译：制备催化剂的方法，该催化剂包含用于MTO工艺中的磷改性沸石
公开(公告)号：US08981173B2
公开(公告)日：2015-03-17
申请号：US13522623
申请日：2011-01-25
申请人： Nikolai Nesterenko , Sander Van Donk , Delphine Minoux , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Sander Van Donk , Delphine Minoux , Jean-Pierre Dath
IPC分类号： C07C1/24 , B01J29/85 , B01J29/06 , B01J29/40 , B01J37/28 , C07C1/20 , B01J27/16 , B01J37/00
CPC分类号： C07C1/24 , B01J27/16 , B01J29/06 , B01J29/40 , B01J29/85 , B01J37/0009 , B01J37/0045 , B01J37/06 , B01J37/08 , B01J37/28 , B01J2229/18 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C2529/40 , C07C2529/85 , C07C11/02
摘要： The present invention is the use of a catalyst in a MTO process to convert an alcohol or an ether into light olefins wherein said catalyst comprises a phosphorus modified zeolite and is made by a method comprising the following steps in this order, a) the essential portion of the phosphorus is introduced into a zeolite comprising at least one ten members ring in the structure, b) the phosphorus modified zeolite of step a) is mixed with at least a component selected among one or more binders, salts of alkali-earth metals, salts of rare-earth metals, clays and shaping additives, b)* making a catalyst body from mixture b), c) an optional drying step or an optional drying step followed by a washing step, d) a calcination step, d*) an optional washing step followed by drying, e) optionally a small portion of phosphorus is introduced in the course of step b) or b)* or at end of step b) or b)*.
摘要翻译：本发明是在MTO方法中使用催化剂将醇或醚转化为轻质烯烃，其中所述催化剂包含磷改性沸石，并通过包括以下步骤的方法制备：a）主要部分的磷被引入到在结构中包含至少一个十元环的沸石中，b）步骤a）的磷改性沸石与至少一种选自一种或多种粘合剂，碱土金属盐，稀土金属盐，粘土和成型添加剂，b）*从混合物b）制备催化剂体，c）任选的干燥步骤或任选的干燥步骤，然后洗涤步骤，d）煅烧步骤d *）任选的洗涤步骤然后干燥，e）在步骤b）或b）*或步骤b）或b）*的末端引入任选的少量磷。

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