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11. 发明授权

US08557902B2 Functionalizable synthetic hydrocarbon fluids and integrated method for production thereof 有权
标题翻译：可合成的合成烃流体及其生产方法
公开(公告)号：US08557902B2
公开(公告)日：2013-10-15
申请号：US13209215
申请日：2011-08-12
申请人： Matthew W. Holtcamp , John R. Hagadorn , Matthew S. Bedoya
发明人： Matthew W. Holtcamp , John R. Hagadorn , Matthew S. Bedoya
IPC分类号： C08L91/00 , B01J19/18
CPC分类号： C08F236/20 , C08C2019/09 , C08F4/65908 , C08F210/14 , C08F4/65927 , C08F2500/17
摘要： This invention relates to a process to produce a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) comprising: contacting at least one renewable feedstream with at least one lower olefin in the presence of a metathesis catalyst, wherein a mixture of at least one C4 to C40 linear alpha-olefin and at least one alpha, internally unsaturated, nonconjugated olefin is produced; and contacting the mixture with a metallocene catalyst system, wherein a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) is produced.
摘要翻译：本发明涉及一种生产聚（α-烯烃）（α，内部不饱和的非共轭烯烃）的方法，包括：在复分解催化剂存在下使至少一种可再生的原料流与至少一种低级烯烃接触，其中将产生至少一种C 4至C 40直链α-烯烃和至少一种α内部不饱和非共轭烯烃; 并使该混合物与金属茂催化剂体系接触，其中制备聚（α-烯烃）（α，内部不饱和的非共轭烯烃）。

12. 发明授权

US08329921B2 Metathesis catalyst and process for use thereof 有权
标题翻译：复分解催化剂及其使用方法
公开(公告)号：US08329921B2
公开(公告)日：2012-12-11
申请号：US13214506
申请日：2011-08-22
申请人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya
发明人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C07D207/04
CPC分类号： C07D207/06 , C07C6/04 , C07C2531/22 , C07F15/002 , C07F15/0046 , C10G3/44 , C10G2300/1014 , C10G2300/1088 , C10G2300/4025 , C10G2400/20 , C10G2400/22 , Y02E50/13 , C07C11/02
摘要： This invention relates to a catalyst compound comprising a combination of a cyclic alkyl amino carbene ligand and a benzylidene both attached to a Group 8 metal, preferably ruthenium atom.This invention also relates to a process to make linear alpha-olefins comprising contacting a feed material and an optional alkene (such as ethylene) with the catalyst described above, wherein the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from seed oil (e.g., biodiesel).
摘要翻译：本发明涉及包含环烷基氨基卡宾配体和亚苄基的组合的催化剂化合物，它们都附着在第8族金属，优选钌原子上。本发明还涉及制备线性α-烯烃的方法，其包括使进料和任选的烯烃（如乙烯）与上述催化剂接触，其中进料是甘油三酯，脂肪酸，脂肪酸烷基酯和 /或脂肪酸酯，通常衍生自种子油（例如，生物柴油）。

13. 发明授权

US08148470B1 Processes for making multimodal molecular weight distribution polyolefins 有权
标题翻译：制备多峰分子量分布聚烯烃的方法
公开(公告)号：US08148470B1
公开(公告)日：2012-04-03
申请号：US12950501
申请日：2010-11-19
申请人： Matthew W. Holtcamp , Matthew S. Bedoya
发明人： Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C08F8/00 , C08F2/00 , C08F2/38 , C08F4/00
CPC分类号： C08F10/00 , C08F4/63925 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F110/02 , C08F2500/05 , C08F4/63904
摘要： This invention relates to a process to make a multimodal polyolefin composition comprising: (i) contacting at least one first olefin monomer with a mixed catalyst system, under polymerization conditions, to produce at least a first polyolefin component having a Mw of 5,000 g/mol to 600,000 g/mol, wherein the mixed catalyst system comprises: (a) at least one polymerization catalyst comprising a Group 4 or Group 5 transition metal; (b) at least one organochromium polymerization catalyst; (c) an activator; and (d) a support material; (ii) thereafter, contacting the first polyolefin component/mixed catalyst system combination with a molecular switch; (iii) contacting the first polyolefin component/mixed catalyst system combination with at least one second olefin monomer, which may be the same or different, under polymerization conditions; and (iv) obtaining a multimodal polyolefin composition.
摘要翻译：本发明涉及一种制备多峰聚烯烃组合物的方法，其包括：（i）在聚合条件下使至少一种第一烯烃单体与混合催化剂体系接触，以产生至少一种Mw为5,000g / mol的第一聚烯烃组分至600,000g / mol，其中所述混合催化剂体系包含：（a）至少一种包含第4族或第5族过渡金属的聚合催化剂; （b）至少一种有机铬聚合催化剂; （c）活化剂; 和（d）支撑材料; （ii）之后，使第一聚烯烃组分/混合催化剂体系组合与分子开关接触; （iii）在聚合条件下使第一聚烯烃组分/混合催化剂体系组合与至少一种可以相同或不同的第二烯烃单体接触; 和（iv）获得多峰聚烯烃组合物。

14. 发明授权

US08063232B2 Metathesis catalyst and process for use thereof 有权
标题翻译：复分解催化剂及其使用方法
公开(公告)号：US08063232B2
公开(公告)日：2011-11-22
申请号：US12939054
申请日：2010-11-03
申请人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya
发明人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C07D207/04
CPC分类号： C07F15/0046 , C07D207/06 , C10G3/00 , C10G2300/1014 , C10G2300/1088 , C10G2400/20 , C10G2400/22 , Y02E50/13
摘要： This invention relates to a catalyst compound comprising a combination of a cyclic alkyl amino carbene ligand and a benzylidene both attached to a Group 8 metal, preferably ruthenium atom.This invention also relates to a process to make linear alpha-olefins comprising contacting a feed material and an optional alkene (such as ethylene) with the catalyst described above, wherein the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from seed oil (e.g., biodiesel).
摘要翻译：本发明涉及包含环烷基氨基卡宾配体和亚苄基的组合的催化剂化合物，它们都附着在第8族金属，优选钌原子上。本发明还涉及制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与上述催化剂接触，其中进料是甘油三酯，脂肪酸，脂肪酸烷基酯和 /或脂肪酸酯，通常衍生自种子油（例如，生物柴油）。

15. 发明授权

US08524930B2 Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof 有权
标题翻译：烯烃复分解催化剂类，制备方法及其使用方法
公开(公告)号：US08524930B2
公开(公告)日：2013-09-03
申请号：US13149012
申请日：2011-05-31
申请人： Matthew W. Holtcamp , Matthew S. Bedoya
发明人： Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C07F15/00 , C07C2/04 , C08F4/80
CPC分类号： C07F15/0046 , B01J31/2265 , B01J31/24 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/06 , C07C2531/22 , C07C2531/24 , C07C13/44 , C07C13/68
摘要： This invention relates to a metathesis catalyst comprising a Group 8 metal complex represented by the formula: wherein: M is a Group 8 metal; each X is independently an anionic ligand; R1 and R2 are independently selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R3 and R4 are independently selected from the group consisting of hydrogen, C1 to C12 hydrocarbyl groups, substituted C1 to C12 hydrocarbyl groups, and halides; and L is a neutral donor ligand. This invention also relates to processes for performing a metathesis reaction, in particular ring opening cross metathesis reactions and ring opening metathesis polymerization reactions, using the Group 8 metal complexes.
摘要翻译：本发明涉及包含由下式表示的第8族金属络合物的复分解催化剂：其中：M是第8族金属; 每个X独立地是阴离子配体; R 1和R 2独立地选自氢，C 1至C 30烃基和C 1至C 30取代的烃基; R3和R4独立地选自氢，C1至C12烃基，取代的C1至C12烃基和卤化物; L是中性供体配体。本发明还涉及使用第8族金属络合物进行复分解反应，特别是开环交叉复分解反应和开环易位聚合反应的方法。

16. 发明授权

US08519147B2 Carbene complexes of lithium and/or magnesium metal salts, and uses thereof 有权
标题翻译：锂和/或镁金属盐的卡宾络合物及其用途
公开(公告)号：US08519147B2
公开(公告)日：2013-08-27
申请号：US12939063
申请日：2010-11-03
申请人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya , Renuka N. Ganesh
发明人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya , Renuka N. Ganesh
IPC分类号： C07F3/02 , C07F1/02
CPC分类号： C07F15/0046 , C07D207/06 , C10G3/00 , C10G2300/1014 , C10G2300/1088 , C10G2400/20 , C10G2400/22 , Y02E50/13
摘要： This invention relates to a carbene complex of metal salt represented by the formula: [T−M(R)c]n wherein, R is a monoanionic group; c is 1 or 2; M is a Li or Mg; T is a cyclic carbene ligand; and n is selected from the group of integers comprising 1 to 24 wherein the complex has 50% or less decomposition when stored in 0.01 molar benzene at 23° C. for a period of 1 hour. This invention also relates to transition-metal-carbene complexes prepared from such carbene complexes of metal salts, where the transition-metal-carbene complex is represented by the formula: [M*(T)(L0)q(L1−)s(L2−)t]g, where M* is a transition metal from Group 6, 7, 8, 9, 10, 11 or 12, T is a cyclic carbene ligand, L0 is a neutral ligand, L1− is a monoanionic ligand, L2− is a dianionic ligand, q is 0, 1, 2, 3 or 4, s is 0, 1, 2, 3, or 4, t is 0, 1, 2, 3, or 4, g is the overall charge of the molecule. The transition-metal-carbene complexes may be used for synthesis reactions, including metathesis of olefins.
摘要翻译：本发明涉及由式[T-M（R）c] n表示的金属盐的卡宾络合物，其中R是单阴离子基团; c为1或2; M是Li或Mg; T是环卡宾配体; 并且n选自包含1至24的整数组，其中当在23℃下在0.01摩尔苯中储存1小时时，所述络合物具有50％或更少的分解。本发明还涉及由金属盐的这种卡宾络合物制备的过渡金属 - 卡宾络合物，其中过渡金属 - 卡宾络合物由下式表示：[M *（T）（L0）q（L1-）s L2-）t] g，其中M *是第6,7,8,9,10,11或12族的过渡金属，T是环卡宾配体，L 0是中性配体，L1-是单阴离子配体， L2-是二阴离子配体，q是0,1,2,3或4，s是0,1,2,3或4，t是0,1,2,3或4，g是总电荷的分子。过渡金属 - 卡宾络合物可用于合成反应，包括烯烃的复分解。

17. 发明申请

US20130041122A1 Polymers Prepared By Ring Opening / Cross Metathesis 有权
标题翻译：通过开环/交叉复分解制备的聚合物
公开(公告)号：US20130041122A1
公开(公告)日：2013-02-14
申请号：US13209242
申请日：2011-08-12
申请人： Matthew W. Holtcamp , John R. Hagadorn , Caol P. Huff , Matthew S. Bedoya , Catherine Anne Faler
发明人： Matthew W. Holtcamp , John R. Hagadorn , Caol P. Huff , Matthew S. Bedoya , Catherine Anne Faler
IPC分类号： C08F32/08 , C08F4/80 , C08F136/20
CPC分类号： C08F4/80 , C08F32/08 , C08F136/20 , C08G2261/1642 , C08G2261/3325 , C08G2261/418 , C10M107/10 , C10M2205/0285 , C10N2270/00
摘要： This invention relates to a process for producing a polymer of a cyclic olefin and a linear mono-olefin, the process comprising contacting at least one C5 based cyclic olefin with at least one linear mono-olefin having from two to twenty carbon atoms in the presence of an alkene metathesis catalyst, and the polymer so produced.
摘要翻译：本发明涉及一种制备环状烯烃和直链单烯烃聚合物的方法，该方法包括使至少一种C 5基环烯烃与至少一种具有2-20个碳原子的直链单烯烃在存在的烯烃复分解催化剂和如此制备的聚合物。

18. 发明申请

US20110306815A1 Metathesis Catalyst and Process for Use Thereof 有权
标题翻译：复分解催化剂及其使用方法
公开(公告)号：US20110306815A1
公开(公告)日：2011-12-15
申请号：US13214506
申请日：2011-08-22
申请人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya
发明人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya
IPC分类号： C07C1/207 , C07F15/00
CPC分类号： C07D207/06 , C07C6/04 , C07C2531/22 , C07F15/002 , C07F15/0046 , C10G3/44 , C10G2300/1014 , C10G2300/1088 , C10G2300/4025 , C10G2400/20 , C10G2400/22 , Y02E50/13 , C07C11/02
摘要： This invention relates to a catalyst compound comprising a combination of a cyclic alkyl amino carbene ligand and a benzylidene both attached to a Group 8 metal, preferably ruthenium atom.This invention also relates to a process to make linear alpha-olefins comprising contacting a feed material and an optional alkene (such as ethylene) with the catalyst described above, wherein the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from seed oil (e.g., biodiesel).
摘要翻译：本发明涉及包含环烷基氨基卡宾配体和亚苄基的组合的催化剂化合物，它们都附着在第8族金属，优选钌原子上。本发明还涉及制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与上述催化剂接触，其中进料是甘油三酯，脂肪酸，脂肪酸烷基酯和 /或脂肪酸酯，通常衍生自种子油（例如，生物柴油）。

19. 发明申请

US20110112349A1 Metathesis Catalyst and Process for Use Thereof 有权
标题翻译：复分解催化剂及其使用方法
公开(公告)号：US20110112349A1
公开(公告)日：2011-05-12
申请号：US12705136
申请日：2010-02-12
申请人： Matthew W. Holtcamp , Catherine Anne Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
发明人： Matthew W. Holtcamp , Catherine Anne Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
IPC分类号： C07C6/04 , C07F15/00 , C07C1/213
CPC分类号： C07F15/0046 , C07D207/06 , C10G3/00 , C10G2300/1014 , C10G2300/1088 , C10G2400/20 , C10G2400/22 , Y02E50/13
摘要： This invention relates to a catalyst compound for the metathesis of olefins represented by the formula: wherein M is a Group 8 metal; X and X1 are anionic ligands; L is a neutral two electron donor; L1 is N, O, P, or S, preferably N or O; R is a C1 to C30 hydrocarbyl or a C1 to C30 substituted hydrocarbyl; G* is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R1 is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and G is independently selected from the group consisting of hydrogen, halogen, C1 to C30 hydrocarbyls and C1 to C30 substituted hydrocarbyls. This invention also relates to process to make alphaolefins comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with the catalyst compound described above. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.
摘要翻译：本发明涉及一种用于由下式表示的烯烃复分解的催化剂化合物：其中M是第8族金属; X和X1是阴离子配体; L是中性二电子给体; L1是N，O，P或S，优选N或O; R是C1至C30烃基或C1至C30取代的烃基; G *选自氢，C1至C30烃基和C1至C30取代的烃基; R1选自氢，C1至C30烃基和C1至C30取代的烃基; 且G独立地选自氢，卤素，C 1至C 30烃基和C 1至C 30取代的烃基。本发明还涉及制备α-烯烃的方法，包括使烯烃如乙烯与含有三酰基甘油酯（通常为脂肪酸酯（如油酸甲酯））的进料油与上述催化剂化合物接触。脂肪酸酯可以是衍生自生物柴油的脂肪酸甲酯。

20. 发明申请

US20110112304A1 Carbene Complexes of Lithium And/Or Magnesium Metal Salts, And Uses Thereof 有权
标题翻译：锂和/或镁金属盐的卡宾络合物及其用途
公开(公告)号：US20110112304A1
公开(公告)日：2011-05-12
申请号：US12939063
申请日：2010-11-03
申请人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya , Renuka N. Ganesh
发明人： John R. Hagadorn , Matthew W. Holtcamp , Matthew S. Bedoya , Renuka N. Ganesh
IPC分类号： C07F15/00 , C07D207/06 , C10G1/00
CPC分类号： C07F15/0046 , C07D207/06 , C10G3/00 , C10G2300/1014 , C10G2300/1088 , C10G2400/20 , C10G2400/22 , Y02E50/13
摘要： This invention relates to a carbene complex of metal salt represented by the formula: [T−M(R)c]n wherein, R is a monoanionic group; c is 1 or 2; M is a Li or Mg; T is a cyclic carbene ligand; and n is selected from the group of integers comprising 1 to 24 wherein the complex has 50% or less decomposition when stored in 0.01 molar benzene at 23° C. for a period of 1 hour. This invention also relates to transition-metal-carbene complexes prepared from such carbene complexes of metal salts, where the transition-metal-carbene complex is represented by the formula: [M*(T)(L0)q(L1−)s(L2−)t]g, where M* is a transition metal from Group 6, 7, 8, 9, 10, 11 or 12, T is a cyclic carbene ligand, L° is a neutral ligand, L1− is a monoanionic ligand, L2− is a dianionic ligand, q is 0, 1, 2, 3 or 4, s is 0, 1, 2, 3, or 4, t is 0, 1, 2, 3, or 4, g is the overall charge of the molecule. The transition-metal-carbene complexes may be used for synthesis reactions, including metathesis of olefins.
摘要翻译：本发明涉及由式[T-M（R）c] n表示的金属盐的卡宾络合物，其中R是单阴离子基团; c为1或2; M是Li或Mg; T是环卡宾配体; 并且n选自包含1至24的整数组，其中当在23℃下在0.01摩尔苯中储存1小时时，所述络合物具有50％或更少的分解。本发明还涉及由金属盐的这种卡宾络合物制备的过渡金属 - 卡宾络合物，其中过渡金属 - 卡宾络合物由下式表示：[M *（T）（L0）q（L1-）s L2-）t] g，其中M *是来自第6,7,8,9,10,11或12族的过渡金属，T是环卡宾配体，L°是中性配体，L1-是单阴离子配体，L2-是二阴离子配体，q是0,1,2,3或4，s是0,1,2,3或4，t是0,1,2,3或4，g是整体分子的电荷。过渡金属 - 卡宾络合物可用于合成反应，包括烯烃的复分解。

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