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    • 14. 发明授权
    • Solvent dewaxing using combination poly (n-C.sub.24)
alkylmethacrylate-poly (C.sub.8 -C.sub.20 alkyl (meth-) acrylate
dewaxing aid
    • 溶剂脱蜡使用组合聚(n-C24)甲基丙烯酸烷基酯 - 聚(C8-C20烷基(甲基)丙烯酸酯脱蜡助剂
    • US4728414A
    • 1988-03-01
    • US933126
    • 1986-11-21
    • Theodore H. WestDavid J. Martella
    • Theodore H. WestDavid J. Martella
    • C10G73/12C10G73/04
    • C10G73/04
    • Solvent dewaxing of waxy hydrocarbon oils is improved by using a poly (n-C.sub.24) alkyl methacrylate polymer dewaxing aid in combination with lower melting point weight poly (C.sub.8 -C.sub.20) alkyl methacrylate polymer dewaxing aids. The solvent dewaxing processes improved using this combination dewaxing aid are the incremental and total predilution solvent type processes employing either surface chilled indirect heat exchanger means or direct chilling using cold solvent.The solvent dewaxing processes are those employing normally liquid dewaxing solvents, as exemplified by C.sub.3 -C.sub.6 ketones, such as methyl ethyl ketone, methyl isobutyl ketone and mixtures thereof, mixtures of ketones with aromatic such as MEK/toluene, halogenated C.sub.2 -C.sub.4 hydrocarbons such as tetrachloraethane, trichloro ethylene, etc. Autorefrigerative solvent dewaxing processes employing low boiling point, normally gaseous hydrocarbons, such as propane, propylene, butane, butene and mixtures of such solvents, with the aforesaid ketones, e.g., propane/MEK, are also benefited by use of the present dewaxing aid combination.Use of the combination dewaxing aid results in an improvement in feed filter rate and liquids/solids. ratio in the dewaxing process.
    • 通过使用甲基丙烯酸聚(n-C24)烷基酯聚合物脱蜡助剂与较低熔点重量的聚(C 8 -C 20)甲基丙烯酸烷基酯聚合物脱蜡助剂组合来改善蜡质烃油的溶剂脱蜡。 使用该组合脱蜡助剂的溶剂脱蜡方法得到改进,是使用表面冷冻间接换热器装置或使用冷溶剂进行直接冷却的增量式和全部预稀释溶剂型方法。 溶剂脱蜡方法是使用通常液体脱蜡溶剂的那些方法,例如甲基乙基酮,甲基异丁基酮及其混合物,例如甲基乙基酮,甲基异丁基酮及其混合物,酮与芳族化合物如MEK /甲苯的混合物,卤代C 2 -C 4烃 作为四氯乙烷,三氯乙烯等。使用低沸点(通常为气态的烃,例如丙烷,丙烯,丁烷,丁烯和这些溶剂的混合物)与上述酮(例如丙烷/ MEK)的自动制冷溶剂脱蜡方法也受益匪浅 通过使用目前的脱蜡助剂组合。 使用组合脱蜡助剂可提高进料过滤速率和液体/固体。 脱蜡过程中的比例。
    • 18. 发明授权
    • Carboxylate-vinyl ester copolymer blend compositions for lubricating oil flow improvement
    • 用于润滑油流动改进的羧酸酯 - 乙烯酯共聚物共混物组合物
    • US06475963B1
    • 2002-11-05
    • US09846469
    • 2001-05-01
    • Ricardo A. BlochDavid J. Martella
    • Ricardo A. BlochDavid J. Martella
    • C10M14516
    • C10M169/041C10M145/16
    • Compositions for improving at least the low temperature flow properties of high viscosity index, high saturates, low sulfur lubricating oils (also known as American Petroleum Institute Group II and Group III oils). The compositions comprise a mixture of lubricating oil flow improvers (LOFIs) that are specified first and second component copolymers of unsaturated dicarboxy esters, including a first component which is a polymer or copolymer of a carboxylate containing pendent ester groups wherein the average side chain carbon number is between 11.0 and 12.4, such as dialkyl fumarate/vinyl acetate copolymer, and a second component which also is a polymer or copolymer such as dialkyl fumarate/vinyl acetate copolymer, but wherein the average side chain carbon number is between 12.7 and 15.0. Alternatively, each of the polymers or copolymers can be esterified styrene/maleic anhydride copolymer, or esterified olefin/maleic anhydride copolymer provided that each of the two components has the specified, different average side chain carbon numbers.
    • 用于改善高粘度指数,高饱和度,低硫润滑油(也称为美国石油研究所II类和III类油)的低温流动性的组合物。 组合物包含润滑油流动改进剂(LOFI)的混合物,其是不饱和二羧基酯的第一和第二组分共聚物,包括第一组分,其是含有侧链酯基的羧酸酯的聚合物或共聚物,其中平均侧链碳数 例如富马酸二烷基酯/乙酸乙烯酯共聚物,也是富马酸二烷基酯/乙酸乙烯酯共聚物等聚合物或共聚物的第二成分,平均侧链碳数为12.7〜15.0。 或者,每种聚合物或共聚物可以是酯化苯乙烯/马来酸酐共聚物或酯化的烯烃/马来酸酐共聚物,只要两种组分中的每一种具有指定的不同的平均侧链碳数。