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11. 发明授权

US5889107A Polyvinyl ester dispersion with metal salt hydrosols as precipitation basis 失效
标题翻译：聚乙烯酯分散体与金属盐水溶胶作为沉淀基础
公开(公告)号：US5889107A
公开(公告)日：1999-03-30
申请号：US930096
申请日：1997-11-12
申请人： Martin Jakob , Heinz Hennemann , Volker Matz
发明人： Martin Jakob , Heinz Hennemann , Volker Matz
IPC分类号： C08F2/44 , C07C59/06 , C07C59/08 , C07C59/153 , C07C59/255 , C07C59/265 , C07C59/50 , C07F7/00 , C08F8/12 , C08F18/08 , C08K5/098 , C08L29/04 , C09D129/04 , C09D131/04 , C09J129/04 , C09J131/04 , C08K3/10
CPC分类号： C07C59/153 , C07C59/06 , C07C59/08 , C07C59/255 , C07C59/265 , C07C59/50 , C07F7/006
摘要： Polyvinyl ester dispersions comprising a hydrosol of a complex salt of a metal from subgroup 4 of the Periodic Table of the Elements with an organic .alpha.-hydroxy and/or .alpha.-oxo acid as seed base, which hydrosol comprises a surface-active substance, are suitable as adhesive and coating compositions.
摘要翻译： PCT No.PCT / EP96 / 01999 Sec。 371日期：1997年11月12日 102（e）日期1997年11月12日PCT提交1996年5月10日PCT公布。 WO96 / 36648 PCT出版物日期：1996年11月21日聚乙烯酯分散体包含元素周期表第4族金属络合盐的水溶胶和有机α-羟基和/或α-氧代酸作为种子基，该水溶胶包含表面活性物质适合作为粘合剂和涂料组合物。

12. 发明授权

US07585915B2 Water-resistant adhesives, their preparation and use 失效
标题翻译：防水胶粘剂，其制备和使用
公开(公告)号：US07585915B2
公开(公告)日：2009-09-08
申请号：US10899164
申请日：2004-07-26
申请人： Martin Jakob , Werner Prass
发明人： Martin Jakob , Werner Prass
IPC分类号： C08F8/30
CPC分类号： C08F8/30 , C08L29/04 , C09J131/04
摘要： A description is given of an aqueous dispersion adhesive based on an aqueous polymer dispersion comprising at least one emulsion polymer with small amounts of crosslinkable N-methylol groups, at least one protective colloid, and at least one crosslinking agent containing N-methylol groups, of which at least one is etherified with an alkanol, said crosslinking agent being selected from the group consisting of hydroxymethylated cyclic ethyleneureas, hydroxymethylated cyclic propyleneureas, hydroxymethylated bicyclic glyoxal diureas, hydroxymethylated bicyclic malonaldehyde diureas or combinations thereof.The aqueous dispersion adhesive can be employed in particular for adhesively bonding porous and semiporous substrates.
摘要翻译：给出了基于包含至少一种具有少量可交联的N-羟甲基的至少一种乳液聚合物，至少一种保护胶体和至少一种含有N-羟甲基交联剂的乳液聚合物的含水分散体粘合剂的描述，所述交联剂选自羟甲基化环状亚乙基脲，羟甲基化环丙烯脲，羟甲基化双环乙二醛二脲，羟甲基化双环丙二醛二脲或其组合中的至少一种。水性分散粘合剂可以特别用于粘合多孔和半孔基材。

13. 发明授权

US07312272B2 Food coating substance containing a softener-free aqueous copolymer poly(vinyl ester) dispersion, production and use thereof 有权
标题翻译：含有无软化剂的共聚物聚（乙烯基酯）分散体的食品包衣物质的生产和使用
公开(公告)号：US07312272B2
公开(公告)日：2007-12-25
申请号：US10499503
申请日：2002-12-23
申请人： Martin Jakob , Heinrich Harrer
发明人： Martin Jakob , Heinrich Harrer
IPC分类号： C08J3/00 , C08L33/00
CPC分类号： C08F218/04 , A23C19/163 , A23P20/19 , C08K5/06 , C08L29/04 , C08L2205/02 , C09D131/04 , C08L2666/04
摘要： A novel food coating substance comprising a plasticizer-free aqueous copolymer poly(vinyl ester) dispersion of emulsion polymer, emulsifier, protective colloid and optionally other stabilizers is outstandingly suitable for the surface treatment or surface coating of hard cheese or semi-hard cheese, but also of meat products, fruits, nuts or seed material.
摘要翻译：包含不含增塑剂的水性共聚物乳液聚合物，乳化剂，保护胶体和任选的其它稳定剂的聚（乙烯基酯）分散体的新型食品包衣物质显着地适用于硬干酪或半硬干酪的表面处理或表面涂层，但是还有肉制品，水果，坚果或种子材料。

14. 发明授权

US07244812B2 Method for the production of aqueous polymer dispersions containing very few residual monomers and use thereof 有权
标题翻译：制备含有非常少的残留单体的聚合物水分散体的方法及其用途
公开(公告)号：US07244812B2
公开(公告)日：2007-07-17
申请号：US10527178
申请日：2003-07-26
申请人： Harmin Müller , Martin Jakob , Carsten Heldmann , Thomas Wirth
发明人： Harmin Müller , Martin Jakob , Carsten Heldmann , Thomas Wirth
IPC分类号： C08F6/00
CPC分类号： C08F6/006
摘要： The invention relates to a method for reducing the amount of residual monomers in aqueous polymer dispersions means of chemical post-treatment. Post-treatment in the aqueous polymer dispersion is carried out by adding a redox system which contains a) 0.005-5 wt. % of an oxidation agent which contains an organic peroxide. and b) 0.005-5 wt. % of a reduction agent which contains sulfinic acids or salts thereof. Additionally the redox system can, optionally, contain catalytic amounts of a polyvalent metallic ion which can be treated in several valent stages. Post-treatment can be carried out at a temperature ranging from 20-100.degree. C. and at a PH-value ranging from 2-9. The invention also relates to the use of the inventive post-treated polymer dispersion for producing adhesives, coatings, powders, constructive chemical products or for refining textiles or paper.
摘要翻译：本发明涉及减少聚合物水分散体中化学后处理方法中残余单体量的方法。在聚合物水分散体中的后处理是通过加入氧化还原体系进行的，所述氧化还原体系含有：a）0.005-5wt。含有有机过氧化物的氧化剂的％。和b）0.005-5wt。％的还原剂含有亚磺酸或其盐。此外，氧化还原体系可以任选地含有催化量的多价金属离子，其可以以数个阶段处理。后处理可以在20-100度的温度范围内进行。且PH值范围为2-9。本发明还涉及本发明的后处理聚合物分散体用于生产粘合剂，涂料，粉末，建构性化学产品或用于精制纺织品或纸的用途。

15. 发明授权

US6093766A Process for preparing polyvinyl alcohol stabilized solvent- and plastifier-free polyvinyl ester dispersions 失效
标题翻译：制备聚乙烯醇稳定的无溶剂和无增塑剂的聚乙烯酯分散体的方法
公开(公告)号：US6093766A
公开(公告)日：2000-07-25
申请号：US150594
申请日：1998-09-10
申请人： Martin Jakob , Werner Prass
发明人： Martin Jakob , Werner Prass
IPC分类号： C08F263/02 , C08J3/09 , C08L31/04
CPC分类号： C08F263/02
摘要： The present invention relates to the preparation of heterogeneous, water-resistant polyvinyl ester dispersions having a film-forming temperature of below 10.degree. C., comprising the formation of a homo- or copolymer A, having a glass transistion temperature of more that 20.degree. C., by seed polymerization of a monomer mixture comprising 85-100% by weight of a vinyl ester of carboxylic acids having 1 to 18 carbon atoms,0-10% by weight of an .alpha.,.beta.-unsaturated carboxylic acid and/or of an N-functional compound and0-5% by weight of a polyethylenically unsaturated monomer in the presence of a seed base comprising a copolymer B having a glass transition temperature of below 20.degree. C., comprising45-98% by weight of a vinyl ester of carboxylic acids having 1 to 18 carbon atoms,2-50% by weight of an .alpha.-olefin having 1 to 4 carbon atoms and0-5% by weight of a polyethylenically unsaturated monomer.
摘要翻译：本发明涉及成膜温度低于10℃的非均相防水聚乙烯酯分散体的制备，包括形成玻璃转移温度高于20℃的均聚物或共聚物A C.通过包含85-100重量％的具有1至18个碳原子的羧酸的乙烯基酯，0-10重量％的α，β-不饱和羧酸和/或 N-官能化合物和0-5重量％的多烯属不饱和单体在含有玻璃化转变温度低于20℃的共聚物B的种子基质存在下，包含45-98重量％的乙烯基具有1至18个碳原子的羧酸的酯，2-50重量％的具有1至4个碳原子的α-烯烃和0-5重量％的多烯属不饱和单体。

16. 发明授权

US5907011A Heterogeneous polyvinyl ester dispersions and powders 失效
标题翻译：不均匀的聚乙烯酯分散体和粉末
公开(公告)号：US5907011A
公开(公告)日：1999-05-25
申请号：US828557
申请日：1997-03-31
申请人： Martin Jakob , Detlev Seip , Volker Matz , Stefan Hess
发明人： Martin Jakob , Detlev Seip , Volker Matz , Stefan Hess
IPC分类号： C08J3/00 , C08J3/03 , C08J3/16 , C08L31/02 , C09J131/02 , C08L31/04
CPC分类号： C08J3/005 , C08J3/03 , C08J3/16 , C08L31/02 , C09J131/02 , C08J2331/02 , C08J2331/04 , C08L2201/50 , C08L2205/02
摘要： Heterogeneous, solvent- and plasticizer-free polyvinyl ester dispersions which are stabilized by protective colloids and which have a minimum filming temperature of below 10.degree. C. are disclosed. These dispersions are made of a mixture of(a) a homopolymer or copolymer A having a glass transition temperature of above 20.degree. C., whereby homopolymer or copolymer A includes(i) from 85 to 100% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 0 to 5% by weight of at least one .alpha., .beta.-unsaturated carboxylic acid;(iii) from 0 to 5% by weight of at least one mono-olefinically unsaturated compound (a3) having at least one amino or amido group, and(iv) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer, and(b) a copolymer B having a glass transition temperature of below 20.degree. C., whereby copolymer B includes(i) from 45 to 98% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 2 to 50% by weight of at least on .alpha.-mono-olefin having 1 to 4 carbon atoms and(iii) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer. Also disclosed are powders obtained from these dispersions by spray-drying, and dispersion prepared by redispersing the spray-drying powders. These materials are suitable as adhesives for bonding porous and semiporous substrates.
摘要翻译：公开了由保护胶体稳定并且具有低于10℃的最低成膜温度的不均匀，无溶剂和不增塑剂的聚乙烯酯分散体。这些分散体由（a）玻璃化转变温度高于20℃的均聚物或共聚物A的混合物制成，其中均聚物或共聚物A包括（i）85至100重量％的至少一种乙烯基酯具有1至18个碳原子的羧酸; （ii）0至5重量％的至少一种α，β-不饱和羧酸; （iii）0至5重量％的至少一种具有至少一个氨基或酰胺基的单烯属不饱和化合物（a3），和（iv）0至5重量％的至少一种多烯属不饱和单体，和（b）玻璃化转变温度低于20℃的共聚物B，其中共聚物B包含（i）45至98重量％的至少一种具有1至18个碳原子的羧酸乙烯基酯; （ii）2-50重量％的至少一个具有1-4个碳原子的α-单烯烃和（iii）0-5重量％的至少一种多烯属不饱和单体。还公开了通过喷雾干燥从这些分散体获得的粉末和通过再分散喷雾干燥粉末制备的分散体。这些材料适用于粘合多孔和半孔基材的粘合剂。

17. 发明授权

US5777015A Dispersion powders for water-resistant adhesives 失效
标题翻译：防水粘合剂分散粉
公开(公告)号：US5777015A
公开(公告)日：1998-07-07
申请号：US760074
申请日：1996-12-04
申请人： Martin Jakob , Volker Matz , Hermann Schindler
发明人： Martin Jakob , Volker Matz , Hermann Schindler
IPC分类号： C08K3/16 , C04B24/26 , C08J3/12 , C08K3/24 , C08K3/32 , C08K3/34 , C08K5/07 , C08L29/04 , C08L31/00 , C08L31/02 , C08L31/04 , C09J129/04 , C09J131/00 , C09J131/04
CPC分类号： C08J3/12 , C04B24/26 , C04B24/2623 , C08L31/02 , C04B2103/0057 , C08J2331/02 , C08L29/04
摘要： A redispersible dispersion powder comprising: a) a base polymer selected from the group consisting of vinyl ester homo- and copolymers, b) from 2 to 20% by weight, based on the overall mass of the base polymer a), of polyvinyl alcohol, said polyvinyl alcohol having a degree of hydrolysis of from 70 to 100 mol-% and a viscosity in a 4% aqueous solution of from 2 to 70 mPa.s, c) from 0 to 50% by weight, based on the overall mass of the components a) and b), of anticaking agent, d) from 0.001 to 5% by weight, based on the overall mass of the components a) and b), of water- soluble, at least bifunctional, masked aldehydes having at least 3 carbon atoms, said masked aldehydes being capable of controllably releasing aldehyde groups in an acidic medium, e) from 0 to 25% by weight, based on the overall mass of the base polymer a), of additives selected from the group consisting of film-forming auxiliaries and plasticizers, and f) from 0 to 10% by weight, based on the overall mass of the components a) and b), of free Bronsted or Lewis acids which are present as solids or adsorbed on a carrier material.
摘要翻译：一种可再分散的分散体粉末，其包含：a）选自乙烯基酯均聚物和共聚物的基础聚合物，b）基于聚合物的基础聚合物a）的总质量为2至20重量％的聚乙烯醇，所述聚乙烯醇的水解度为70至100摩尔％，4％水溶液中的粘度为2至70mPa.s，c）为0至50重量％，基于基于组分a）和b）的组分a）和b），d）基于组分a）和b）的总质量为0.001至5重量％的水溶性至少双功能的掩蔽的醛，其具有至少 3个碳原子，所述掩蔽的醛能够在酸性介质中可控制地释放醛基，e）基于基础聚合物a）的总质量为0至25重量％的选自以下的添加剂：膜成型助剂和增塑剂，以及f）基于组分的总质量为0至10重量％ a）和b），其以固体存在或吸附在载体材料上的游离Br + E，矾土+ EE nsted或路易斯酸。

18. 发明授权

US07776938B2 Food coating composition comprising protective colloid-stabilized polyacrylate dispersions, use thereof and coated foods produced therewith 失效
标题翻译：食品涂料组合物包含保护性胶体稳定的聚丙烯酸酯分散体，其用途和由其生产的包衣食品
公开(公告)号：US07776938B2
公开(公告)日：2010-08-17
申请号：US11159785
申请日：2005-06-23
申请人： Martin Jakob , Heinrich Harrer , Ivan Cabrera
发明人： Martin Jakob , Heinrich Harrer , Ivan Cabrera
IPC分类号： A23C19/16 , A23B4/10 , A23B7/16 , C09D131/04 , C09D133/10
CPC分类号： A22C13/0013
摘要： A description is given of food coating compositions comprising a) a plastics dispersion or a mixture of plastics dispersions comprising at least one homo- or copolymer poly(meth)acrylate having at least 55% by weight (meth)acrylate monomer units and also 0.1 to 30% by weight of at least one protective colloid, and also b) aids and/or additives used for producing food coatings. The coatings are distinguished by sufficiently high water vapor transmission rates, low water absorption capacity and also low reemulsification capacity and have good mechanical properties in the moist state.
摘要翻译：描述了食品涂料组合物，其包括a）塑料分散体或塑料分散体的混合物，其包含至少一种具有至少55重量％（甲基）丙烯酸酯单体单元的均聚物或共聚物聚（甲基）丙烯酸酯，并且还包含0.1至 30重量％的至少一种保护胶体，以及b）用于生产食品涂料的助剂和/或添加剂。涂层的特征在于足够高的水蒸气透过率，低吸水能力和低再乳化能力，并且在潮湿状态下具有良好的机械性能。

19. 发明授权

US07491777B2 Polymer dispersions having improved water-vapor barrier action, their production and use for food coating 失效
标题翻译：具有改善的水蒸气屏障作用的聚合物分散体，它们的生产和用于食品涂层
公开(公告)号：US07491777B2
公开(公告)日：2009-02-17
申请号：US11000406
申请日：2004-11-30
申请人： Martin Jakob , Heinrich Harrer
发明人： Martin Jakob , Heinrich Harrer
IPC分类号： C08F218/08 , C08F222/14 , C09D131/04 , A23C19/16
CPC分类号： A23C19/16 , A22C13/0013 , A22C2013/004 , A23P20/19 , C08F218/04 , C08F222/14 , C08L29/04 , C08L33/04 , C08L71/02 , C09D131/04 , C08L2666/02
摘要： A decsription is given of an aqueous copolymer poly(vinyl ester) dispersion comprising A) 100 parts by weight of a copolymer derived from A1) from 34.9 to 95% by weight of vinyl esters of aliphatic, saturated carboxylic acids, A2) from 4.9 to 65% by weight of maleic esters and/or fumaric esters of monohydric aliphatic alcohols having a chain length of C1-C18 and/or alpha-olefins having from 2 to 8 carbon atoms, A3) from 0.1 to 10% of at least one comonomer having at least one stabilizing nonionic or ionic group, and also A4) if appropriate, other comonomers, the sum of components A1, A2 and A3 and if appropriate A4 giving 100% by weight, B) from 0.1 to 4.5 parts by weight, based on the total amount of the monomers used, preferably from 0.5 to 3.5 parts by weight of at least one protecting colloid, preferably poly(vinyl alcohol), C) from 0.1 to 10 parts by weight, based on the total amount of the monomers used, preferably from 0.5 to 5.0 parts by weight, of a nonionic emulsifier, and D) if appropriate, further additives suitable for coating foods. The dispersion is produced by free-radical emulsion polymerization and is suitable for coating foods. The films formed from these dispersions are distinguished by a low water-vapor transmission rate.
摘要翻译：给出了一种含水共聚物聚（乙烯基酯）分散体的分解物，其包含A）100重量份的衍生自A1）的共聚物，34.9-95重量％的脂肪族饱和羧酸的乙烯基酯，A2）为4.9〜 65重量％的链长为C1-C18和/或具有2至8个碳原子的α-烯烃的一元脂肪醇的马来酸酯和/或富马酸酯，A3）0.1至10％的至少一种共聚单体具有至少一个稳定的非离子或离子基团，以及A4），如果合适的话，其它共聚单体，组分A1，A2和A3的总和，如果合适的话A4给出100重量％，B）0.1至4.5重量份相对于使用的单体的总量，优选为0.5〜3.5重量份的至少一种保护胶体，优选聚（乙烯醇），C）为0.1〜10重量份，基于所用单体的总量，优选0.5-5.0重量份的非离子乳化剂，和D）如果合适，还可以添加适合涂层食品的其他添加剂。分散体是通过自由基乳液聚合生产的，适用于涂层食品。由这些分散体形成的薄膜的特征在于低的水蒸气透过率。

20. 发明申请

US20080139650A1 Fungicidally Active Polymer Dispersions And Use Thereof 审中-公开
标题翻译：杀真菌活性聚合物分散体及其用途
公开(公告)号：US20080139650A1
公开(公告)日：2008-06-12
申请号：US11576124
申请日：2005-08-26
申请人： Martin Jakob , Heinrich Harrer
发明人： Martin Jakob , Heinrich Harrer
IPC分类号： A01N25/10 , C08K5/01 , C08K5/09 , A01N37/06 , A01P3/00 , C08K5/16 , C08K5/05
CPC分类号： A01N31/16 , A01N31/08 , A01N37/02 , A01N43/90 , A01N43/50 , A01N37/06 , A01N25/30 , A01N25/10 , A01N25/04 , A01N2300/00
摘要： A description is given of an aqueous polymer dispersion comprising A) a polymer dispersion produced by free-radical polymerization of ethylenically unsaturated monomers, B) stabilizers suitable for carrying out the free-radical polymerization, and also C) 0.01 to 20 000 ppm by weight, based on the mass of the total dispersion, of at least one compound of the formula Ia and/or Ib where R1, R2, R13 and R14 independently of one another are hydrogen, C1-C6-alkyl, C1-C6-alkoxy, carboxyl, nitrile, isonitrile, cyano or halogen, R3 to R12 and R15 to R24 independently of one another are hydrogen and selected organic radicals, and at least one of the substituents R3 to R12, or R15 to R24, being hydroxyl and/or alkoxy and/or alkanoyloxy. The aqueous polymer dispersion may be used for coating foods, as color, or as adhesive, and the resultant films are distinguished by high fungicidal resistance.
摘要翻译：描述了一种含水聚合物分散体，其包括A）通过烯属不饱和单体的自由基聚合制备的聚合物分散体，B）适用于进行自由基聚合的稳定剂，以及C）0.01至20,000ppm重量基于总分散体的质量，至少一种式Ia和/或Ib的化合物，其中R 1，R 2，R 13， R 1和R 2彼此独立地是氢，C 1 -C 6 - C 6 - 烷基，C 1〜 C 6 -C 6 - 烷氧基，羧基，腈，异腈，氰基或卤素，R 3至R 12和R 15，彼此独立的R 24和R 24彼此是氢和选择的有机基团，并且至少一个取代基R 3至R 12的取代基或R 15至R 24为羟基和/或烷氧基和/或烷酰氧基。聚合物水分散体可以用于涂覆食品，如颜色或粘合剂，并且所得到的膜具有高的杀真菌性。

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