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    • 13. 发明申请
    • Cyclic compounds and the use thereof as light absorbers, light emitters, or complex ligands
    • 环化合物及其作为光吸收剂,光发射体或复合配体的用途
    • US20050167637A1
    • 2005-08-04
    • US10509944
    • 2003-04-04
    • Martin KonemannThomas GessnerRudiger SensChristian LennartzGunther Seybold
    • Martin KonemannThomas GessnerRudiger SensChristian LennartzGunther Seybold
    • A61K8/00A61K8/49A61Q17/04B01J31/02B01J31/18B01J31/22C07B61/00C07D487/22C07D498/22C07D513/22C08K5/3417C09B57/00C09B67/46C09D7/12C09D201/00C09K11/06C09K15/16
    • C09B67/0085A61K8/19A61K8/49A61K8/4946A61K2800/58A61Q17/04B01J31/0235B01J31/183B01J2231/70B01J2531/62B01J2531/821B01J2531/842B01J2531/845B01J2531/98C07D487/22C07D498/22C07D513/22
    • The use of cyclic compounds of the formula (I) where n is a number in the range from 1 to 7, X-Y-Z, in each case independently of one another, is O—C═N, N═C—O, NR5—C═N, N═C—NR5, N+R52—C═N, N═C—N+R52, O—C═N+R5, N+R5═C—O, S—C═N+R5, N+R5═C—S, S—C═N, N═C—S, R1, R2 and R3 each independently are, for example, H or a substituent or corresponding heterocyclic compounds in which at least one group —CR1═, —CR2═, CR3═ is replaced by —N, R5 in each case independently are, for example, H or a substituent R7, in each case independently of one another, are H, C1-12-alkyl or C6-12-aryl, or metal complexes of the cyclic compounds or complexes of the cyclic compounds with mineral acids, chloride, sulfate, bisulfate, phosphate, hydrogen phosphate, nitrate, BF4− or methanesulfonate being present as opposite ions X− in the case of cationic cyclic structures, as light absorbers, materials for hole injection layers in OLEDs, light-emitting compounds in OLED, phase-transfer catalysts or synergistic agents for the dispersing of pigments or for optical data storage, is described.
    • 使用式(I)的环状化合物,其中n为1至7的数,XYZ在每种情况下彼此独立地为OCN,NCO,NR 5 -CN ,NC-NR 5,N + 5,...,5,...,...,N N + > 5 5 2,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... > 5-CO,SCN +,...,5,...,...,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ,NCS,R 1,R 2和R 3各自独立地为例如H或取代基或相应的杂环化合物,其中在 至少一个基团-CR 1, - CR 2 - , - CR 3 - 被-N,R 5, 在每种情况下,各自独立地是H或取代基R 7,在每种情况下彼此独立地为H,C 1-12 - 烷基或 C 6-12芳基或环状化合物的金属络合物或环状化合物与无机酸,氯化物,硫酸盐,硫酸氢盐,磷酸盐的络合物 在阳离子环状结构的情况下,作为阳离子环状结构存在,作为相反离子存在的磷酸根,硝酸根,BF 4 - 或 - 甲磺酸盐作为光 吸收剂,OLED中的空穴注入层的材料,OLED中的发光化合物,相转移催化剂或用于颜料分散或光学数据存储的协同剂。
    • 15. 发明授权
    • Multiple chromophores based on rylene
    • 基于二烯的多发色团
    • US08501948B2
    • 2013-08-06
    • US11996074
    • 2006-07-27
    • Martin Konemann
    • Martin Konemann
    • C07D221/18C07D471/22
    • C09K11/06C09B5/62C09K19/60C09K19/606C09K2211/1007C09K2211/1011C09K2211/1014C09K2211/1029C09K2211/1044C09K2211/1416C09K2211/1433C09K2211/1466
    • A rylene-based polychromophore of the general formula I in which the variables are each defined as follows: rylene is a radical of the formula which has been functionalized by at least one imide group, ester group or amide group and which may additionally be substituted by aryloxy, arylthio, hetaryloxy and/or hetarylthio; X is a rylenedicarboximide radical which absorbs at a different wavelength from the rylene radical, is bonded to the X radical in the peri-position via Y via a moiety —Y′-A-Y—, is bonded to the rylene radical and may likewise be substituted by aryloxy, arylthio, hetaryloxy and/or hetarylthio; A is a bridging member having at least one aromatic or heteroaromatic radical, the Y or Y and Y′ groups being bonded to the aromatic or heteroaromatic radical; Y is a moiety Y′ is a moiety where the moieties (i) and (ii) may be part of the ester groups of the rylene radical and the moieties (iii) are part of the imide groups of the rylene radical and the moieties (iv) are part of the amide groups of the rylene radical; R1 is hydrogen or C1-C18-alkyl, where the R1 radicals may be the same or different when they occur repeatedly; n is 1, 2 or 3; x is from 1 to 7.
    • 通式I的亚芳基多色荧光团,其中各变量各自定义如下:亚芳基是已经被至少一个酰亚胺基,酯基或酰胺基官能化并且可以另外被 芳氧基,芳硫基,杂芳氧基和/或杂芳硫基; X是在不同波长下从二芳基吸收的二甲酰亚胺基自由基通过Y经由Y-A'-AY-的键合在X位上的X基团键合到二芳基并且同样可以被取代 芳氧基,芳硫基,杂芳氧基和/或杂芳硫基; A是具有至少一个芳族或杂芳族基团的桥连构件,Y或Y和Y'基团键合到芳族或杂芳族基团; Y是部分Y'是其中部分(i)和(ii)可以是亚芳基的酯基的一部分的部分,并且部分(iii)是亚芳基的酰亚胺基团和部分( iv)是亚芳基的酰胺基团的一部分; R 1是氢或C 1 -C 18 - 烷基,其中当它们重复发生时,R 1基团可以相同或不同; n为1,2或3; x为1至7。
    • 18. 发明申请
    • Terrylene and Quaterrylene Derivatives
    • US20080255357A1
    • 2008-10-16
    • US11913333
    • 2006-05-03
    • Neil Gregory PschirerJianqiang QuMartin Konemann
    • Neil Gregory PschirerJianqiang QuMartin Konemann
    • C07D221/18C07D487/06C07D235/02
    • C07D493/06C07C1/2078C07D221/18C07D311/78C07D491/06C07F5/025C09B3/14C09B5/62C07C13/62
    • Rylene derivatives of the general formula I in which the variables are each defined as follows: X are joined to one another with formation of a six-membered ring to give a radical of the formula (a), (b) or (c) are both a —COOM radical; are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) Y are joined to one another with formation of a six-membered ring to give a radical of the formula (a) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or together are a radical of the formula (a), (b) or (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (b) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (c) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c) which may be arranged in the cis or trans position to the other (c) radical; are both a —COOM radical when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical, M being different from hydrogen in the case that one X radical is a radical of the formula (d); are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) when both X radicals are hydrogen or one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d); R are identical or different radicals: substituted or unsubstituted aryloxy, arylthio, hetaryloxy or hetarylthio; R′ is hydrogen; substituted or unsubstituted alkyl, cycloalkyl, aryl or hetaryl; A are each independently substituted or unsubstituted phenylene, naphthylene or pyridylene; M is hydrogen, ammonium or alkali metal cation; R″ are each independently hydrogen, alkyl, cycloalkyl, aryl or hetaryl, or are joined together with formation of a 5- to 7-membered, fused or unfused and substituted or unsubstituted ring comprising the two oxygen atoms and also the boron atom; R1 is hydrogen or alkyl, where the R1 radicals may be the same or different when they occur more than once; R2, R3 are each independently hydrogen; substituted or unsubstituted alkyl, aryl or hetaryl; m is 1 or 2; n is from 3 to 6 where m=1; is from 2 to 8 where m=2, and mixtures thereof.