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11. 发明授权

US4939225A Polymeric hydridosilazanes, processes for the preparation thereof, silicon nitride-containing ceramic materials which can be prepared therefrom, and the preparation thereof 失效
标题翻译：聚合氢硅氮烷，其制备方法，可由其制备的含氮化硅的陶瓷材料及其制备方法
公开(公告)号：US4939225A
公开(公告)日：1990-07-03
申请号：US289901
申请日：1988-12-23
申请人： Tilo Vaahs , Thomas Gerdau , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Thomas Gerdau , Marcellus Peuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/48 , C08G77/62 , D01F9/10
CPC分类号： C08G77/62 , C04B35/589
摘要： Polymeric hydridosilazanes, processes for the preparation thereof, silicon nitride-containing ceramic materials which can be prepared therefrom, and the preparation thereof.The invention relates to novel polymeric hydridosilazanes, their preparation, their conversion into silicon nitride-containing ceramic material, and this material itself. To prepare the polymeric hydridosilazanes, polymeric hydridothiosilazanes are reacted with NH.sub.3. To prepare the silicon nitride-containing ceramic material, the polymeric hydridosilazanes are then pyrolyzed.
摘要翻译：聚合氢硅氮烷，其制备方法，可由其制备的含氮化硅的陶瓷材料及其制备方法。本发明涉及新颖的聚合物硅藻土，其制备方法，其转化为含氮化硅的陶瓷材料，以及该材料本身。为了制备聚合物硅藻土，聚合的硫代氨基硅烷与NH 3反应。为了制备含氮化硅的陶瓷材料，聚合物氢硅氮烷然后被热解。

12. 发明授权

US5081080A Polymeric hydridosilazanes, processes for the preparation thereof, silicon nitride-containing ceramic materials which can be prepared therefrom, and the preparation thereof 失效
标题翻译：聚合氢硅氮烷，其制备方法，可由其制备的含氮化硅的陶瓷材料及其制备方法
公开(公告)号：US5081080A
公开(公告)日：1992-01-14
申请号：US512732
申请日：1990-04-20
申请人： Tilo Vaahs , Thomas Gerdau , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Thomas Gerdau , Marcellus Peuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/62
CPC分类号： C08G77/62 , C04B35/589
摘要： The invention relates to novel polymeric hydridosilazanes, their preparation, their conversion into silicon nitride-containing ceramic material, and this material itself. To prepare the polymeric hydridosilazanes, polymeric hydridothiosilazanes are reacted with NH.sub.3. To prepare the silicon nitride-containing ceramic material, the polymeric hydridosilazanes are then pyrolyzed.
摘要翻译：本发明涉及新颖的聚合物硅藻土，其制备方法，其转化为含氮化硅的陶瓷材料，以及该材料本身。为了制备聚合物硅藻土，聚合的硫代氨基硅烷与NH 3反应。为了制备含氮化硅的陶瓷材料，聚合物氢硅氮烷然后被热解。

13. 发明授权

US5187252A Silazane polymers containing SiCl groups, process for their preparation, silicon nitride-containing ceramic materials which can be prepared from them, and their preparation 失效
标题翻译：含有SICL组的SILAZANE聚合物，其制备方法，可以制备的含有硝酸硅的陶瓷材料及其制备
公开(公告)号：US5187252A
公开(公告)日：1993-02-16
申请号：US645264
申请日：1991-01-24
申请人： Tilo Vaahs , Hans-Jerg Kleiner , Martin Bruck
发明人： Tilo Vaahs , Hans-Jerg Kleiner , Martin Bruck
IPC分类号： C04B35/589 , C08G77/22 , C08G77/24 , C08G77/48 , C08G77/60 , C08G77/62
CPC分类号： C01B21/068 , C04B35/589 , C04B35/62295 , C08G77/24 , C08G77/62 , C04B2235/465 , C04B2235/5264 , C04B2235/721
摘要： The invention relates to novel silazane polymers containing SiCl groups, to their preparation, to their conversion into silicon nitride-containing ceramic material, and to this material itself. In order to prepare the silazane polymers containing SiCl groups, .alpha.,.omega.-chlorosilazanes of the formula I ##STR1## in which m has a value of from 1 to 12 and --(Si) is a silyl radical of the formula --SiHR.sup.1 Cl, --SiR.sup.2 R.sup.3 Cl, --SiR.sup.4 Cl.sub.2, --SiR.sup.5 Cl-CH.sub.2 CH.sub.2 -SiR.sup.5 Cl.sub.2 or --SiCl.sub.2 -CH.sub.2 CH.sub.2 -SiR.sup.6 Cl.sub.2, and R is C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl and, independently of one another, R.sup.1 -R.sup.6 are H, C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl, to a temperature of from 100.degree. C. to 400.degree. C.The silazane polymers according to the invention containing in SiCl groups can be reacted with ammonia to give polysilazanes, which can themselves be pyrolyzed to give silicon nitride-containing ceramic materials.
摘要翻译：本发明涉及含有SiCl基团的新型硅氮烷聚合物，其制备方法，其转化为含氮化硅的陶瓷材料以及该材料本身。为了制备含有SiCl基团的硅氮烷聚合物，其中m具有1至12的值的式I（α）的α，ω-氯代硅氮烷和 - （Si）是具有下式的甲硅烷基 - SiHR1Cl，-SiR2R3Cl，-SiR4Cl2，-SiR5Cl-CH2CH2-SiR5Cl2或-SiCl2-CH2CH2-SiR6Cl2，R是C1-C6-烷基或C2-C6-烯基，并且彼此独立地是R1-R6是H，C1 -C 1-6 - 烷基或C 2 -C 6 - 链烯基，其温度为100℃至400℃。含有SiCl基团的根据本发明的硅氮烷聚合物可以与氨反应，得到聚硅氮烷，其本身可被热解得到含氮化硅的陶瓷材料。

14. 发明授权

US5030702A Polysilazanes, processes for their preparation, ceramic materials which contain silicon nitride and can be prepared from them, and preparation thereof 失效
标题翻译：聚硅氮烷，其制备方法，含有氮化硅的陶瓷材料并可由它们制备，以及其制备
公开(公告)号：US5030702A
公开(公告)日：1991-07-09
申请号：US496856
申请日：1990-03-21
申请人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Feuckert , Martin Bruck
发明人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Feuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/62
CPC分类号： C04B35/589 , C08G77/62
摘要： The invention relates to novel polysilazanes, their preparation, their further processing to ceramic material containing silicon nitride and this material itself. To prepare the polysilazanes, Si,Si'-diorganyl-N-alkyltetrachloro-disilazanes of the formula RSiCl.sub.2 -NR'-SiCl.sub.2 R are reacted with ammonia. The polysilazanes can then be pyrolyzed to ceramic material containing silicon nitride. The polysilazanes according to the invention dissolve in the customary aprotic solvents.
摘要翻译：本发明涉及新型聚硅氮烷，其制备方法，它们进一步加工含有氮化硅的陶瓷材料及其本身。为了制备聚硅氮烷，式RSiCl2-NR'-SiCl2R的Si，Si'-二有机基-N-烷基四氯二硅氮与氨反应。然后可以将聚硅氮烷热解成含有氮化硅的陶瓷材料。根据本发明的聚硅氮烷溶于常规非质子溶剂中。

15. 发明授权

US5032663A Chlorine-containing silazane polymers, process for their preparation, ceramic materials containing silicon nitride which can be prepared from them, and their preparation 失效
标题翻译：含氯硅氮烷聚合物，其制备方法，可由其制备的含有氮化硅的陶瓷材料及其制备
公开(公告)号：US5032663A
公开(公告)日：1991-07-16
申请号：US444025
申请日：1989-11-30
申请人： Tilo Vaahs , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Marcellus Peuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/48 , C08G77/60 , C08G77/62 , D01F9/10
CPC分类号： C04B35/589 , C08G77/60
摘要： The invention relates to novel chlorine-containing silazane polymers, to their preparation, their further processing to ceramic material containing silicon nitride, and this material itself. In order to prepare the chlorine-containing silazane polymers, oligosilazanes of the formula (I) ##STR1## in which a>0, b.gtoreq.0 and n is about 2 to about 12, are reacted with at least one of the chlorosilanes Cl.sub.2 R.sup.4 Si--CH.sub.2 --CH.sub.2 --SiR.sup.4 Cl.sub.2, Cl.sub.3 Si--CH.sub.2 --CH.sub.2 --Sir.sup.5 Cl.sub.2, R.sup.6 SiCl.sub.3 or R.sup.7 SiHCl.sub.2 at 30.degree. C. to 300.degree. C., where, independently of one another,R.sup.1 and R.sup.2 =H, C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl,R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 =C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl and where if b=0 the reaction with R.sup.7 SiHCl.sub.2, if R.sup.7 =C.sub.1 -C.sub.6 -alkyl and none of the other chlorosilanes is present, is to be excluded.The chlorine-containing silazane polymers according to the invention can be converted by reaction with ammonia into polysilazanes, which in their turn can be pyrolyzed to form ceramic materials containing silicon nitride.
摘要翻译：本发明涉及新颖的含氯硅氮烷聚合物，用于制备它们对含有氮化硅的陶瓷材料的进一步加工，以及该材料本身。为了制备含氯的硅氮烷聚合物，其中a> 0，b> / = 0和n为约2至约12的式（I）的低聚硅氮烷与至少一种氯硅烷 Cl 2 R 4 Si-CH 2 -CH 2 -SiR 4 Cl 2，Cl 3 Si-CH 2 -CH 2 -Sr 5 Cl 2，R 6 SiCl 3或R 7 SiHCl 3，其中彼此独立地为R 1和R 2 = H，C 1 -C 6 - 烷基或C 2 -C 6 - 烯基，R 3，R 4，R 5，R 6和R 7 = C 1 -C 6 - 烷基或C 2 -C 6 - 烯基，如果b = 0，则与R 7 SiHCl 2反应，如果R 7 = C 1 -C 6烷基，存在氯硅烷，应被排除。根据本发明的含氯硅氮烷聚合物可以通过与氨的反应转化成聚硅氮烷，聚硅氮烷又可以被热解以形成含有氮化硅的陶瓷材料。

16. 发明授权

US5196556A Polysubstituted chlorine-containing silazane polymers, process for their preparation, ceramic materials containing silicon nitride which can be manufactured therefrom, and their manufacture 失效
标题翻译：聚硅氧烷聚硅氧烷聚合物，其制备方法，含有可制造的硅酸钠的陶瓷材料及其制造方法
公开(公告)号：US5196556A
公开(公告)日：1993-03-23
申请号：US444012
申请日：1989-11-30
申请人： Tilo Vaahs , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Marcellus Peuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/48 , C08G77/62 , D01F9/10
CPC分类号： C08G77/62 , C04B35/589
摘要： The invention relates to novel polysubstituted chlorine-containing silazane polymers, to their preparation, to their processing to form ceramic material containing silicon nitride, and to said material itself. The chlorine-containing silazane polymers are prepared by reating oligosilazanes of formula (I) ##STR1## in which at least one of the indices a or b and at least one of the indices c or d are not equal to 0 and n is about 2 to about 12, with at least one of the chlorosilanes Cl.sub.2 R.sup.6 Si--CH.sub.2 CH.sub.2 --SiR.sup.6 Cl.sub.2, Cl.sub.3 Si--CH.sub.2 CH.sub.2 --SiR.sup.7 Cl.sub.2, R.sup.8 SiCl.sub.3 or R.sup.9 SiHCl.sub.2 at 30.degree. C. to 300.degree. C., where the radicals independently of one another have the following meanings: R.sup.1, R.sup.2, R.sup.4 =H, C.sub.1 -C.sub.6 alkyl or C.sub.2 -C.sub.6 alkenyl and R.sup.3, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9 =C.sub.1 -C.sub.6 alkyl or C.sub.2 -C.sub.6 alkenyl.The polysubstituted chlorine-containing silazane polymers according to the invention can be converted into polysilazanes by reaction with ammonia, and these in turn can be pyrolyzed to form ceramic materials containing silicon nitride.
摘要翻译：本发明涉及新型多取代含氯硅氮烷聚合物，用于制备它们的加工以形成含有氮化硅的陶瓷材料，以及所述材料本身。含氯的硅氮烷聚合物是通过将式（I）的寡硅氮烷反应制备的，其中指数a或b中的至少一个和指数c或d中的至少一个不等于0，n为约2 至约12个，其中至少一种氯硅烷Cl 2 R 6 Si-CH 2 CH 2 -SiR 6 Cl 2，Cl 3 Si-CH 2 CH 2 -SiR 7 Cl 2，R 8 SiCl 3或R 9 SiHCl 2在30℃至300℃，其中基团彼此独立地具有以下含义：R 1 ，R2，R4 = H，C1-C6烷基或C2-C6烯基，R3，R5，R6，R7，R8，R9 = C1-C6烷基或C2-C6链烯基。根据本发明的多取代的含氯硅氮烷聚合物可以通过与氨的反应转化成聚硅氮烷，并且这些可以热解，形成含有氮化硅的陶瓷材料。

17. 发明授权

US5182411A Polymeric chlorosilazanes, process for their preparation, ceramic materials containing silicon nitride which can be manufactured therefrom, and their manufacture 失效
标题翻译：聚合氯化铝，其制备方法，含有可制造的硝酸硅的陶瓷材料及其制造方法
公开(公告)号：US5182411A
公开(公告)日：1993-01-26
申请号：US444681
申请日：1989-11-30
申请人： Tilo Vaahs , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Marcellus Peuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/48 , C08G77/62 , D01F9/10
CPC分类号： C08G77/62 , C04B35/589
摘要： The invention relates to novel polymeric chlorosilazanes, to their preparation, to their processing to form ceramic material containing silicon nitride, and to said material itself. The polymeric chlorosilazanes are prepared by reacting a mixture of oligosilazanes of formula (I) ##STR1## in which n is about 2 to about 12, and oligosilazanes of formula (II), (RSiHNH).sub.m, in which m is about 3 to about 12, with at least one of the chlorosilanes Cl.sub.2 R.sup.2 Si--CH.sup.2 --CH.sub.2 --SiR.sup.2 Cl.sub.2, Cl.sub.3 Si--CH.sub.2 --CH.sub.2 --SiR.sup.3 Cl.sub.2, R.sup.4 SiCl.sup.3 or R.sup.5 SiHCl.sub.2 at 30.degree. C. to 300.degree. C., where R and R.sup.1 to R.sup.5 are C.sub.1 -C.sub.6 alkyl or C.sub.2 -C.sub.6 alkenyl groups which can be identical or different.The polymeric chlorosilazanes according to the invention can be converted into polysilazanes by reaction with ammonia, and these in turn can be pyrolyzed to form ceramic materials containing silicon nitride.
摘要翻译：本发明涉及新型聚合氯硅氮烷，用于制备它们的加工以形成含有氮化硅的陶瓷材料，以及所述材料本身。聚合氯硅氮烷通过使式（I）的寡硅氮烷（其中n为约2至约12）和式（II）的低聚硅氮烷（RSiHNH）m的混合物（其中m为约 3至约12，其中至少一种氯硅烷Cl 2 R 2 Si-CH 2 -CH 2 -Si 2 Cl 2 Cl 2，Cl 3 Si-CH 2 -SiR 3 Cl 2，R 4 SiCl 3或R 5 SiHCl 2在30℃至300℃，其中R和R 1至R 5为C 1 -C 1-6烷基或可以相同或不同的C 2 -C 6烯基。根据本发明的聚合氯硅氮烷可以通过与氨的反应转化成聚硅氮烷，并且它们又可以被热解以形成含有氮化硅的陶瓷材料。

18. 发明授权

US5358746A Optical moldings made from silicon nitride, and a process for their production 失效
标题翻译：由氮化硅制成的光学模制品及其生产工艺
公开(公告)号：US5358746A
公开(公告)日：1994-10-25
申请号：US127987
申请日：1993-09-27
申请人： Martin Bruck , Tilo Vaahs , Marcellus Peuckert , Ude Scheunemann , Thomas Stehlin , Jurgen Theis
发明人： Martin Bruck , Tilo Vaahs , Marcellus Peuckert , Ude Scheunemann , Thomas Stehlin , Jurgen Theis
IPC分类号： C04B35/589 , C03C13/04 , C04B35/584 , C04B41/50 , C04B41/87 , D01F9/10 , D06M11/00 , D06M11/60 , D06M101/00 , G02B1/00 , B05D3/02
CPC分类号： C04B41/009 , C03C13/041 , C04B41/5035 , C04B41/87 , G02B1/00
摘要： A process for the preparation of optical materials from silicon nitride by pyrolysis of polymeric silazanes, by pressing the pulverulent polymeric silazanes to give moldings before the pyrolysis or first dissolving the polymeric silazanes in an organic solvent, drawing fibers from this solution and pyrolyzing these fibers after evaporation of the solvent, or by melting polymeric silazanes, casting, injection-molding or extruding this melt to give moldings and subsequently pyrolyzing the moldings. An oxidic coating is produced on the silicon nitride molding in an oxygen-containing atmosphere during or after the pyrolysis. The pyrolysis can be carried out at 800.degree.-1000.degree. C. in an atmosphere containing ammonia or an ammonia/inert gas mixture.
摘要翻译：通过热分解聚硅氮烷，通过挤压粉状聚合硅氮烷以在热解或首先将聚合硅氮烷溶解在有机溶剂中之前得到成型物，从该溶液中拉伸纤维并在这种溶液中热解这些纤维之后，将这些纤维热解后，从氮化硅制备光学材料的方法蒸发溶剂，或通过熔融聚合硅氮烷，铸造，注射成型或挤出该熔体以得到模制品，随后热解模制品。在热分解期间或之后，在含氧气氛中的氮化硅模制品上产生氧化涂层。热解可以在含有氨或氨/惰性气体混合物的气氛中在800°-1000℃进行。

19. 发明授权

US5011801A Polymeric ethylene-bridged chlorosilazanes, process for their preparation, ceramic materials which can be prepared from them containing silicon nitride, and their preparation 失效
标题翻译：聚合乙烯桥接氯硅氮烷，其制备方法，可由其制备含有氮化硅的陶瓷材料及其制备方法
公开(公告)号：US5011801A
公开(公告)日：1991-04-30
申请号：US444816
申请日：1989-11-30
申请人： Tilo Vaahs , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Marcellus Peuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/48 , C08G77/60 , C08G77/62 , D01F9/10
CPC分类号： C08G77/60 , C04B35/589
摘要： Polymeric ethylene-bridged chlorosilazanes, process for their preparation, ceramic materials which can be prepared from them containing silicon nitride, and their preparationThe invention relates to novel polymeric ethylene-bridged chlorosilazanes, their preparation, their further processing to a ceramic material containing silicon nitride, and this material itself. In order to prepare the polymeric chlorosilazanes, oligosilazanes of the formula (I) ##STR1## are reacted with at least one of the chlorosilanes ##STR2## in which R.sup.1 to R.sup.5 are C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl groups, which may be identical or different.The polymeric chlorosilazanes according to the invention can be converted by reaction with ammonia into polysilazanes, which in their turn can be pyrolysed to ceramic materials containing silicon nitride.
摘要翻译：聚合乙烯桥接的氯硅氮烷，其制备方法，可由它们制备的含氮化硅的陶瓷材料及其制备本发明涉及新型聚合物乙烯桥连氯硅氮烷，其制备方法，它们进一步加工成含有氮化硅的陶瓷材料，这个材料本身。为了制备聚合氯硅氮烷，式（I）的寡硅氮烷（I）与至少一种氯代硅烷（IMAGE）反应，其中R 1至R 5为C 1 -C 6 - 烷基或C 2 -C 6 - 烯基组可以相同或不同。根据本发明的聚合氯硅氮烷可以通过与氨的反应转化成聚硅氮烷，聚硅氮烷又可以热解成含有氮化硅的陶瓷材料。

20. 发明授权

US5483614A Optical waveguide moldings made from silicon nitride and a method of detecting optical wavelengths using same 失效
标题翻译：由氮化硅制成的光波导模制品以及使用其检测光波长的方法
公开(公告)号：US5483614A
公开(公告)日：1996-01-09
申请号：US278391
申请日：1994-07-21
申请人： Martin Bruck , Tilo Vaahs , Marcellus Peuckert , Ude Scheunemann , Thomas Stehlin , Jurgen Theis
发明人： Martin Bruck , Tilo Vaahs , Marcellus Peuckert , Ude Scheunemann , Thomas Stehlin , Jurgen Theis
IPC分类号： C04B35/589 , C03C13/04 , C04B35/584 , C04B41/50 , C04B41/87 , D01F9/10 , D06M11/00 , D06M11/60 , D06M101/00 , G02B1/00 , G02B6/02 , B05D3/02 , B29D11/00
CPC分类号： C04B41/009 , C03C13/041 , C04B41/5035 , C04B41/87 , G02B1/00
摘要： A transparent molded article for optical applications made from silicon nitride and a coating thereon of oxidic silicon nitride formed by chemical reaction of the silicon nitride with oxygen. The moldings can be shaped, depending on the area of application, to give various articles, for example optical waveguides, prisms, sensor elements or lenses, and are used in all areas where high optical demands are made.
摘要翻译：由氮化硅制成的用于光学应用的透明模制品以及通过氮化硅与氧的化学反应形成的氧化氮化硅的涂层。根据应用领域，成形品可以成型，以形成各种制品，例如光波导，棱镜，传感器元件或透镜，并且用于制造高光学要求的所有区域。

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