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11. 发明授权

US4762905A Aromatic thermoplastic polyphosphonatocarbonate 失效
标题翻译：芳香族热塑性聚磷酸酯
公开(公告)号：US4762905A
公开(公告)日：1988-08-09
申请号：US735635
申请日：1985-05-20
申请人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag , Werner Nouvertne
发明人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag , Werner Nouvertne
IPC分类号： C08G63/00 , C08G64/00 , C08G79/02 , C08G79/04 , C08G63/62
CPC分类号： C08G79/04 , C08G64/083
摘要： Thermoplastic polyphosphonatocarbonate prepared by polycondensing at least one aromatic dihydroxy compound with a diaryl carbonate and a phosphonic acid diaryl ester in the presence of a basic polycondensation catalyst at a temperature of from 80.degree. to 340.degree. C. and under a pressure of 600 to 0.1 mm Hg in an inert gaseous atmosphere, the molar ratio of diaryl carbonate to phosphonic diaryl ester being from 5:95 to 95:5 and the molar ratio of aromatic dihydroxy compound to the sum of diaryl carbonate and phosphonic acid diaryl ester being from 0.91:1 to 0.99:1, and following polycondensation, neutralizing said basic catalyst.
摘要翻译：在碱性缩聚催化剂存在下，在80〜340℃的温度和600〜0.1mm的压力下，使至少一种芳族二羟基化合物与碳酸二芳基酯和膦酸二芳基酯缩聚制备的热塑性聚膦酸酯 Hg在惰性气体气氛中，碳酸二芳酯与膦酸二芳基酯的摩尔比为5:95至95:5，芳族二羟基化合物与碳酸二芳酯和膦酸二芳基酯的摩尔比为0.91:1 至0.99:1，并进行缩聚后中和所述碱性催化剂。

12. 发明授权

US4415719A Thermoplastic, branched aromatic polyphosphonates, and a process for their production 失效
标题翻译：热塑性支链芳族聚磷酸酯及其制备方法
公开(公告)号：US4415719A
公开(公告)日：1983-11-15
申请号：US328383
申请日：1981-12-07
申请人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag , Klaus Reinking , Harry Rohr , Hans-Dieter Block
发明人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag , Klaus Reinking , Harry Rohr , Hans-Dieter Block
IPC分类号： C08G79/00 , C08G79/02 , C08G79/04
CPC分类号： C08G79/04
摘要： Thermoplastic, branched aromatic polyphosphonates with average molecular weights (number average M.sub.n) of from 11,000 to more than 200,000, obtainable by transesterifying (a) from 97 to 100 moles of at least one diaryl phosphonate, and (b) from 0 to 3 moles of at least one triaryl phosphate--the sum of the moles of (a) and (b) being 100--with (c) from 90 to 99 moles of at least one aromatic dihydroxy compound, and (d) from 0 to 3 moles of at least one aromatic trihydroxy or tetradhydroxy compound--with the proviso that at least one of the components (b) and (d) is present in a quantity of at least 0.001 mole and that, where (b) and (d) are used, the maximum limit on the moles is 3.0.
摘要翻译：平均分子量（数均Mn）为11,000至大于200,000的热塑性支链芳族聚膦酸酯，可通过（a）97-100摩尔的至少一种二芳基膦酸酯和（b）0-3摩尔的至少一种磷酸三芳基酯（a）和（b）的摩尔数的总和为100-（c）90至99摩尔的至少一种芳族二羟基化合物，和（d）0至3摩尔的至少一种芳族三羟基或四羟基化合物 - 条件是组分（b）和（d）中的至少一种以至少0.001摩尔的量存在，并且使用（b）和（d）时，摩尔数的最大限度为3.0。

13. 发明授权

US4382041A Process for the production of aromatic carboxylic acid chlorides 失效
标题翻译：芳香族羧酸氯化物的制备方法
公开(公告)号：US4382041A
公开(公告)日：1983-05-03
申请号：US312223
申请日：1981-10-19
申请人： Udo Rudolph , Manfred Schmidt , Dieter Freitag , Ludwig Bottenbruch
发明人： Udo Rudolph , Manfred Schmidt , Dieter Freitag , Ludwig Bottenbruch
IPC分类号： C07C63/00 , B01J31/02 , C07B61/00 , C07C51/60 , C07C65/34
CPC分类号： C07C51/60
摘要： A single-stage process for the production of pure aromatic carboxylic acid chlorides by reacting an aromatic carboxylic acid or an aromatic carboxylic acid mixture with thionylchloride in the presence of tert. phosphine as the catalyst.
摘要翻译：通过使芳族羧酸或芳族羧酸混合物与亚硫酰氯在叔叔存在下反应，生产纯芳族羧酸氯化物的单阶段方法。膦作为催化剂。

14. 发明授权

US4328174A Aromatic polyester phosphonates 失效
标题翻译：芳香族聚酯膦酸酯
公开(公告)号：US4328174A
公开(公告)日：1982-05-04
申请号：US160957
申请日：1980-06-19
申请人： Manfred Schmidt , Dieter Freitag , Ludwig Bottenbruch , Klaus Reinking , Harry Rohr , Harald Medem
发明人： Manfred Schmidt , Dieter Freitag , Ludwig Bottenbruch , Klaus Reinking , Harry Rohr , Harald Medem
IPC分类号： C08G63/00 , C08G63/68 , C08G63/682 , C08G63/692 , C08G79/00 , C08G79/02 , C08G79/04 , C07F9/40
CPC分类号： C08G79/04 , C08G63/6926
摘要： Polyester phosphonates based on aromatic dicarboxylic acids and aromatic dihydroxy compounds exhibit a low flammability and surprisingly improved mechanical characteristics, particularly an excellent dimensional heat stability.
摘要翻译：基于芳族二羧酸和芳族二羟基化合物的聚酯膦酸酯显示出低的可燃性和惊人的改善的机械特性，特别是优异的尺寸热稳定性。

15. 发明授权

US4362864A Process for the preparation of polyarylene sulphides 失效
标题翻译：聚亚芳基硫醚的制备方法
公开(公告)号：US4362864A
公开(公告)日：1982-12-07
申请号：US263421
申请日：1981-05-14
申请人： Karsten Idel , Dieter Freitag , Ludwig Bottenbruch , Josef Merten
发明人： Karsten Idel , Dieter Freitag , Ludwig Bottenbruch , Josef Merten
IPC分类号： C08G75/02 , C08G75/06 , C08L81/02 , C08G75/14
CPC分类号： C08G75/0254 , C08G75/0231
摘要： A process for preparing a polyarylene sulphide which comprises reacting(a) dihalogenobenzene consisting of 50 to 100 mol % of a compound of the formula ##STR1## or a compound of the formula ##STR2## or a mixture thereof and of 0 to 50 mol % of a compound of the formula ##STR3## wherein X is halogen and each R is selected from the group consisting of hydrogen, alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 20 carbon atoms, aryl having 6 to 24 carbon atoms, alkaryl having 7 to 24 carbon atoms and aralkyl having 7 to 24 carbon atoms with the proviso that at least one R is other than hydrogen and(b) 0 to 3.0 mol % based on the dihalogenobenzene content of a polyhalogeno aromatic of the formulaArX.sub.n (IV) wherein Ar is an aromatic or heterocyclic radical with 6 to 24 carbon atoms having at least 3 free valencies, X is halogen and n is .gtoreq. 3 with(c) an alkyl metal sulphide in(d) a polar solvent in the presence of(e) 0.05-2.0 mol of alkali metal fluoride per mol of alkali metal sulphide,for a polycondensation time of up to 30 hours and at a polycondensation temperature of between 160.degree. and 295.degree. C., the molar ratio of (a) to (c) being in the range from 0.85:1 to 1.15:1 and the molar ratio of (c) to (d) being in the range of from 1:2 to 1:15.
摘要翻译：一种制备聚亚芳基硫醚的方法，其包括使（a）由50至100mol％的式（I）化合物或式IIa化合物或其混合物组成的二卤代苯和 0至50摩尔％的式（III）化合物，其中X为卤素且每个R选自氢，具有1至20个碳原子的烷基，具有5至20个碳原子的环烷基，具有6至24个碳原子的芳基，具有7至24个碳原子的烷芳基和具有7至24个碳原子的芳烷基，条件是至少一个R不是氢，和（b）基于二卤代苯含量为0-3.0mol％式ArXn（IV）的多卤代芳族化合物，其中Ar是具有至少3个自由价的6至24个碳原子的芳族或杂环基，X是卤素，n是≥3，（c）烷基金属硫化物（d）在（e）0.05-2.0mol碱金属氟化物存在下，每摩尔的极性溶剂碱金属硫化物，缩聚时间长达30小时，缩聚温度在160〜295℃之间，（a）与（c）的摩尔比在0.85:1-1.15:1的范围内， 1和（c）至（d）的摩尔比在1:2至1:15的范围内。

16. 发明授权

US4338429A Process for working up polycarbonates 失效
标题翻译：加工聚碳酸酯的工艺
公开(公告)号：US4338429A
公开(公告)日：1982-07-06
申请号：US166015
申请日：1980-07-07
申请人： Volker Serini , John Goossens , Ludwig Bottenbruch , Dieter Freitag
发明人： Volker Serini , John Goossens , Ludwig Bottenbruch , Dieter Freitag
IPC分类号： C08G63/00 , C08G64/24 , C08G64/40 , C08J3/10
CPC分类号： C08G64/24 , C08G64/406
摘要： The present invention relates to a process for working up alkaline two-phase mixtures which have been obtained in the synthesis of polycarbonates by the two-phase boundary process, characterized in that for the separation of the alkaline two-phase mixture into an organic phase and an aqueous phase, the mixture is supplied with shearing energy and/or added are one or more cationic emulsifying agents and/or dispersing agents and/or in that, for the separation of the acidified two-phase mixture into an organic phase and an aqueous phase, the mixture is supplied with shearing energy and/or added are one or more cationic emulsifying agents and/or dispersing agents and/or in that the organic phase which was separated off after the acidification is washed with water to which one or more water-soluble, organic anionic compounds have been added.
摘要翻译：本发明涉及一种在两相边界过程合成聚碳酸酯中获得的碱性二相混合物的处理方法，其特征在于将碱性两相混合物分离成有机相，水相中，混合物被供应剪切能量和/或添加一种或多种阳离子乳化剂和/或分散剂和/或为了将酸化的两相混合物分离成有机相和水相提供剪切能量和/或添加的是一种或多种阳离子乳化剂和/或分散剂，和/或在酸化后分离的有机相用水洗涤，向其中加入一种或多种水已经添加了可溶性有机阴离子化合物。

17. 发明授权

US4617368A Process for the production of colorless aromatic polyester and polyester carbonates 失效
标题翻译：生产无色芳香聚酯和聚碳酸酯的方法
公开(公告)号：US4617368A
公开(公告)日：1986-10-14
申请号：US680158
申请日：1984-12-10
申请人： Dieter Freitag , Ludwig Bottenbruch , Uwe Hucks
发明人： Dieter Freitag , Ludwig Bottenbruch , Uwe Hucks
IPC分类号： C08G63/00 , C08G63/19 , C08G63/64 , C08G64/20 , C08G8/02
CPC分类号： C08G63/64 , C08G63/19
摘要： The invention relates to a process for the production of colorless, heat-stable and hydrolysis-stable aromatic polyesters and polyester carbonates by conventional interfacial polycondensation of aromatic dicarboxylic acid dichlorides and diphenolates in which dicarboxylic acid dichlorides are used which have been obtained by chlorination from the dimethyl esters of the corresponding acids, and tertiary cycloaliphatic amines are used as catalysts.
摘要翻译：本发明涉及通过芳族二羧酸二氯化物和二酚盐的常规界面缩聚生产无色，热稳定和水解稳定的芳族聚酯和聚酯碳酸酯的方法，其中使用二羧酸二氯化物，其通过氯化从使用相应酸的二甲酯和叔脂环族胺作为催化剂。

18. 发明授权

US4433138A Process for the preparation of polyarylene sulphides 失效
标题翻译：聚亚芳基硫醚的制备方法
公开(公告)号：US4433138A
公开(公告)日：1984-02-21
申请号：US379036
申请日：1982-05-17
申请人： Karsten Idel , Dieter Freitag , Ludwig Bottenbruch , Otto Neuner
发明人： Karsten Idel , Dieter Freitag , Ludwig Bottenbruch , Otto Neuner
IPC分类号： C08G75/02 , C08G75/06 , C08G75/14
CPC分类号： C08G75/0254 , C08G75/0231
摘要： High molecular weight p-polyarylensulfides having a high melt viscosity, capable of being processed thermoplastically, and have good mechanical properties are produced by reacting components (a), (b), and (c) in a polar solvent with a molar ratio of (a):(c) in the range of 0.85:1 to 1.15:1 and a molar ratio of (c): solvent in the range of 1:2 to 1:15, for a time of up to 10 hours at a temperature of from 160.degree. C. to 300.degree. C., and in the presence of from 2 to 100 mole percent, relative to (c), of an N,N-dialkylcarboxamide;wherein component (a) is dihalogenobenzene with 50 to 100 mole percent of the formula ##STR1## and 0 to 50 mole percent of the formula ##STR2## wherein X is fluoro, chloro, bromo or iodo, and R is the same or different and each is selected from the group consisting of hydrogen, alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 20 carbon atoms, aryl having 6 to 24 carbon atoms, alkaryl having 7 to 24 carbon atoms, aralkyl having 7 to 24 carbon atoms, and two R moieties linked together forming aryl having 6 to 24 carbon atoms or a heterocyclic moiety having an oxygen, nitrogen or sulphur hetero-atom and having 6 to 24 carbon atoms; with the proviso that at least one R is not hydrogen;component (b) is 0.1 to 2.4 mole percent, relative to the dihalogenobenzene, of a polyhalogenoaromatic of the formulaArX.sub.nwherein Ar is aryl or a heterocyclic moiety having an oxygen, nitrogen or sulphur heteroatom with said aryl and said heterocyclic each having from 6 to 24 carbon atoms;X is fluoro, chloro, bromo or iodo; andn is 3 or 4;and component (c) is alkali metal sulphide.
摘要翻译：通过使组分（a），（b）和（c）在极性溶剂中以摩尔比为（（a），（b）和（c））反应，可以通过热塑性地热处理和具有良好的机械性能而具有高熔体粘度的高分子量对聚芳基硫化物 a）：（c）在0.85:1至1.15:1的范围内，（c）：溶剂的摩尔比在1:2至1:15的范围内，在温度下达10小时相对于（c）为2〜100摩尔％的N，N-二烷基甲酰胺; 其中组分（a）是二卤代苯，其具有50-100摩尔％的式“IMAGE”和0至50摩尔％的式“IMAGE”，其中X是氟，氯，溴或碘，R是相同或不同的，各自选自氢，具有1至20个碳原子的烷基，具有5至20个碳原子的环烷基，具有6至24个碳原子的芳基，具有7至24个碳原子的烷芳基，具有7至24个碳原子的芳烷基，和两个连接在一起的R部分形成具有6至24个碳原子的芳基或具有氧，氮或硫杂原子并具有6至24个碳原子的杂环部分; 条件是至少一个R不是氢; 组分（b）相对于二卤代苯，为式ArXn的多卤代芳族化合物的0.1至2.4摩尔％，其中Ar为芳基或具有氧，氮或硫杂原子的杂环部分，所述芳基和所述杂环各自具有6至 24个碳原子; X是氟，氯，溴或碘; n为3或4; 组分（c）是碱金属硫化物。

19. 发明授权

US4424339A Process for the preparation of polyarylene sulphides 失效
标题翻译：聚亚芳基硫醚的制备方法
公开(公告)号：US4424339A
公开(公告)日：1984-01-03
申请号：US417048
申请日：1982-09-13
申请人： Karsten Idel , Edgar Ostlinning , Dieter Freitag , Ludwig Bottenbruch
发明人： Karsten Idel , Edgar Ostlinning , Dieter Freitag , Ludwig Bottenbruch
IPC分类号： C08G75/02 , C08G75/14
CPC分类号： C08G75/0254 , C08G75/0231
摘要： Process for preparing polyarylensulfides by reacting dihalogenobenzenes, optionally substituted with polyhalogenoaromatic compounds with 3 or 4 halogeno substituents, and alkali metal sulfide in polar solvents using alkali metal sulfites and/or alkaline earth metal sulfites as catalysts.
摘要翻译：通过使用碱金属亚硫酸盐和/或碱土金属亚硫酸盐作为催化剂，将极性溶剂中任选被多卤代芳族化合物与3或4个卤代取代基取代的二卤代苯和碱金属硫化物反应来制备聚芳基硫化物的方法。

20. 发明授权

US5288848A Process for preparation of high molecular weight, optionally branched polyarylene sulphides 失效
标题翻译：制备高分子量，任意支化聚亚芳基硫化物的方法
公开(公告)号：US5288848A
公开(公告)日：1994-02-22
申请号：US978174
申请日：1992-11-17
申请人： Karsten Idel , Wolfgang Ebert , Ludwig Bottenbruch , Dieter Freitag , Rolf-Volker Meyer
发明人： Karsten Idel , Wolfgang Ebert , Ludwig Bottenbruch , Dieter Freitag , Rolf-Volker Meyer
IPC分类号： C08G75/02 , C08G75/14
CPC分类号： C08G75/0231 , C08G75/0254
摘要： The invention relates to a process for the preparation of optionally branched, high molecular weight polyarylene sulphides with melt viscosities which can be established at defined values and low corrosion.These polyarylene sulphides are obtained by reacting alkali metal sulphides, if appropriate mixed with alkali metal bisulphides and reaction accelerators, with dihalogenoaromatics and, if appropriate, polyhalogenoaromatics, with the addition of particular monohalogenoaromatics as chain stoppers.
摘要翻译：本发明涉及一种制备任选支化的高分子量聚亚芳基硫醚的方法，其熔融粘度可以在确定的值和低腐蚀下确定。这些聚亚芳基硫化物是通过使碱金属硫化物（如果适用的话）与碱金属二硫化物和反应促进剂混合，与二卤代芳族化合物反应，如果合适的话，通过加入特定的一卤代芳族化合物作为连锁停止剂。

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