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11. 发明授权

US08097669B2 Flame-retardant elastic block copolymer 失效
标题翻译：阻燃弹性嵌段共聚物
公开(公告)号：US08097669B2
公开(公告)日：2012-01-17
申请号：US12668286
申请日：2008-07-08
申请人： Konrad Knoll , Maarten Staal , Piyada Charoensirisomboon , Volker Warzelhan
发明人： Konrad Knoll , Maarten Staal , Piyada Charoensirisomboon , Volker Warzelhan
IPC分类号： C08K5/49 , C08K5/34
CPC分类号： C08L53/025 , C08K3/04 , C08K3/32 , C08K5/34928 , C08L53/02 , C08L2666/04 , C08L2666/02
摘要： The invention relates to a flameproofed resilient block polymer comprising polymerized units of at least one vinylaromatic monomer and at least one diene monomer with at least one flameproofing agent B) which comprises a compound comprising phosphorus, in particular a phosphorus-containing melamine compound, a process for the preparation and the use for the production of moldings.
摘要翻译：本发明涉及一种包含至少一种乙烯基芳族单体和至少一种二烯单体与至少一种二烯单体的聚合单元和至少一种防火剂B）的隔爆弹性嵌段聚合物，其包含含磷化合物，特别是含磷三聚氰胺化合物，用于制备和用于生产模制品。

12. 发明申请

US20110020575A1 TOUGH AND RIGID MIXTURES OF ALPHA-METHYLSTYRENE-ACRYLNITRILE COPOLYMERS AND OF BLOCK COPOLYMERS 失效
标题翻译： α-甲基苯乙烯 - 丙烯腈共聚物和嵌段共聚物的粗糙和刚性混合物
公开(公告)号：US20110020575A1
公开(公告)日：2011-01-27
申请号：US12921043
申请日：2009-03-04
申请人： Konrad Knoll , Koch Jürgen , Piyada Charoensirisomboon
发明人： Konrad Knoll , Koch Jürgen , Piyada Charoensirisomboon
IPC分类号： B32B1/08 , C08L53/00
CPC分类号： C08L25/16 , C08F297/02 , C08F297/04 , C08L25/06 , C08L53/00 , C08L53/02 , C08L2205/02 , Y10T428/139 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： Composition comprising at least one copolymer A composed of at least one alkylated styrene, of acrylonitrile, and, if appropriate, of at least one further monomer, at least one block copolymer B which has at least one block forming a hard phase and composed of at least one vinylaromatic monomer and has at least one block forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene, and at least one further copolymer C, and, if appropriate, one polymer D, where the copolymer C is at least one triblock copolymer composed of a first block composed of at least one vinylaromatic monomer, of a second block composed of at least one diene, and of a third block composed of at least one methyl methacrylate monomer, or comprising at least 50% by weight of methyl methacrylate, and the polymer D is at least one styrene polymer selected from glass-clear and impact-resistant polystyrene. The present invention moreover relates to a process for the preparation of the inventive compositions, to the use of the inventive compositions for the production of moldings, of foils, of fibers, or of foams, to moldings, foils, fibers, or foams comprising the inventive composition, and also to the use of the inventive composition as packaging for electronic components, such as integrated circuits (microchips) (“electronic packing”), for applications in chemical engineering, in household products, in bathroom items, e.g. toothbrush tumblers, cosmetics holders, etc., as housings, as tubes, as profiles, for medical items or medical devices, and in toys.
摘要翻译：组合物，其包含至少一种由至少一种烷基化苯乙烯，丙烯腈和（如果合适的话）至少一种另外的单体组成的共聚物A，至少一种嵌段共聚物B，其具有至少一个形成硬相的嵌段，至少一种乙烯基芳族单体，并且具有至少一个形成软相并由至少一种乙烯基芳族单体和至少一种二烯构成的嵌段和至少一种其它共聚物C，以及如果合适的话，一种聚合物D，其中共聚物C 是由至少一种乙烯基芳族单体组成的第一嵌段，至少由一种二烯构成的第二嵌段和由至少一种甲基丙烯酸甲酯单体组成的第三嵌段或至少包含至少50％的甲基丙烯酸甲酯，聚合物D是选自玻璃透明和耐冲击聚苯乙烯的至少一种苯乙烯聚合物。本发明还涉及制备本发明组合物的方法，本发明组合物用于生产模制品，箔，纤维或泡沫的用途，用于模制品，箔，纤维或泡沫，其包括本发明的组合物，以及本发明组合物用作电子部件的包装，例如集成电路（微芯片）（“电子包装”），用于化学工程，家用产品，浴室用品中的应用，例如牙刷滚筒，化妆品保持器等，作为外壳，作为管，用作医疗用品或医疗装置的型材，以及玩具。

13. 发明申请

US20100261824A1 THERMOPLASTIC LINOLEUM 失效
标题翻译：热塑性LINOLEUM
公开(公告)号：US20100261824A1
公开(公告)日：2010-10-14
申请号：US12747369
申请日：2008-12-11
申请人： Konrad Knoll , Michel Pepers , Peter Wolf , Piyada Charoensirisomboon
发明人： Konrad Knoll , Michel Pepers , Peter Wolf , Piyada Charoensirisomboon
IPC分类号： C08K5/09
CPC分类号： D06N1/00
摘要： The present invention relates to a thermoplastic molding composition comprising (A) as component A, particles composed of at least one oxidatively crosslinked vegetable oil as core, encapsulated by at least one thermoplastic, (B) as component B, at least one further thermoplastic compatible with the at least one thermoplastic present in the shell of component A, (C) as component C, at least one resin compatible with the at least one thermoplastic present in the shell of component A, (D) as component D, at least one filler, and (E) as component E, if appropriate, further additives, and also to a process for the production of this thermoplastic molding composition.
摘要翻译：本发明涉及一种热塑性模塑组合物，其包含（A）作为组分A，由至少一种氧化交联的植物油作为芯组成的颗粒，由至少一种热塑性塑料包封，（B）作为组分B，至少一种另外的热塑性相容性存在于组分A的外壳中的至少一种热塑性材料（C）作为组分C，至少一种与组分A壳体中存在的至少一种热塑性塑料相容的树脂，（D）作为组分D，至少一种填充剂和（E）作为组分E，如果合适的话，还可使用其它添加剂，以及制备该热塑性模塑组合物的方法。

14. 发明申请

US20100184889A1 FLAME-RETARDANT ELASTIC BLOCK COPOLYMER 失效
标题翻译：阻燃弹性嵌段共聚物
公开(公告)号：US20100184889A1
公开(公告)日：2010-07-22
申请号：US12668286
申请日：2008-07-08
申请人： Konrad Knoll , Maarten Staal , Piyada Charoensirisomboon , Volker Warzelhan
发明人： Konrad Knoll , Maarten Staal , Piyada Charoensirisomboon , Volker Warzelhan
IPC分类号： C08K3/04 , C08K5/3492
CPC分类号： C08L53/025 , C08K3/04 , C08K3/32 , C08K5/34928 , C08L53/02 , C08L2666/04 , C08L2666/02
摘要： The invention relates to a flameproofed resilient block polymer comprising polymerized units of at least one vinylaromatic monomer and at least one diene monomer with at least one flameproofing agent B) which comprises a compound comprising phosphorus, in particular a phosphorus-containing melamine compound, a process for the preparation and the use for the production of moldings.
摘要翻译：本发明涉及一种包含至少一种乙烯基芳族单体和至少一种二烯单体与至少一种二烯单体的聚合单元和至少一种防火剂B）的隔爆弹性嵌段聚合物，其包含含磷化合物，特别是含磷三聚氰胺化合物，用于制备和用于生产模制品。

15. 发明授权

US06593430B1 Transparent, impact-resistant polystyrene on a styrene-butadiene block copolymer basis 有权
标题翻译：基于苯乙烯 - 丁二烯嵌段共聚物的透明耐冲击聚苯乙烯
公开(公告)号：US06593430B1
公开(公告)日：2003-07-15
申请号：US09936784
申请日：2001-09-18
申请人： Konrad Knoll , Wolfgang Fischer , Hermann Gausepohl , Jürgen Koch , Josef Wünsch , Paul Naegele
发明人： Konrad Knoll , Wolfgang Fischer , Hermann Gausepohl , Jürgen Koch , Josef Wünsch , Paul Naegele
IPC分类号： C08F29704
CPC分类号： C08F297/044 , C08F297/04 , C08L25/06 , C08L53/02 , C08L2666/24 , C08L2666/02
摘要： Block copolymers comprise at least two hard blocks S1 and S2 made from vinylaromatic monomers and, between these, at least one random soft block B/S made from vinylaromatic monomers and from dienes, where the proportion of the hard blocks is above 40% by weight, based on the total block copolymer.
摘要翻译：嵌段共聚物包括由乙烯基芳族单体制成的至少两个硬嵌段S1和S2，并且在它们之间，由乙烯基芳族单体和二烯制成的至少一个无规软嵌段B / S，其中硬嵌段的比例高于40重量％，基于总嵌段共聚物。

16. 发明授权

US06521712B1 Glass-clear impact-modified polystyrene based on styrene-butadiene block copolymers 有权
标题翻译：基于苯乙烯 - 丁二烯嵌段共聚物的透明抗冲改性聚苯乙烯
公开(公告)号：US06521712B1
公开(公告)日：2003-02-18
申请号：US09471288
申请日：1999-12-23
申请人： Konrad Knoll , Herrmann Gausepohl , Wolfgang Fischer , Josef Wünsch , Paul Naegele , Jürgen Koch
发明人： Konrad Knoll , Herrmann Gausepohl , Wolfgang Fischer , Josef Wünsch , Paul Naegele , Jürgen Koch
IPC分类号： C08F29300
CPC分类号： C08F293/00 , C08F293/005 , C08F297/04 , C08L25/06 , C08L51/003 , C08L53/02 , C08L2666/24 , C08L2666/02
摘要： Block copolymers comprise at least two hard blocks S1 and S2 made from vinyl aromatic monomers and, between these, at least ore random soft block B/S made from vinyl aromatic monomers and from dienes, where the proportion of the hard blocks is above 40% by weight, based on the total block copolymer, wherein the 1,2-vinyl content in the soft block B/S is less than 20%.
摘要翻译：嵌段共聚物包含由乙烯基芳族单体制成的至少两个硬嵌段S1和S2，并且在这些之间，至少是由乙烯基芳族单体制成的矿石随机软嵌段B / S和二烯，其中硬嵌段的比例高于40％，基于总嵌段共聚物，其中软嵌段B / S中的1,2-乙烯基含量小于20％。

17. 发明授权

US06916885B2 Method for breaking a chain during anionic polymerisation 失效
标题翻译：在阴离子聚合过程中断链的方法
公开(公告)号：US06916885B2
公开(公告)日：2005-07-12
申请号：US10399228
申请日：2001-10-26
申请人： Konrad Knoll , Hermann Gausepohl , Josef Richard Wünsch , Paul Naegele , Jürgen Koch
发明人： Konrad Knoll , Hermann Gausepohl , Josef Richard Wünsch , Paul Naegele , Jürgen Koch
IPC分类号： C08F2/38 , C08F12/00 , C08F12/08
CPC分类号： C08F12/08 , C08F2/42
摘要： A process for the preparation of linear polymers or block copolymers of styrene by anionic polymerization comprises carrying out the chain termination with an n-alkyl glycidyl ether or a dialkyl ketone.
摘要翻译：通过阴离子聚合制备苯乙烯的线性聚合物或嵌段共聚物的方法包括用正烷基缩水甘油醚或二烷基酮进行链终止。

18. 发明申请

US20080269414A1 Styrol/Butadiene Block Copolymer Mixtures for Shrink Films 有权
标题翻译：用于收缩膜的苯乙烯/丁二烯嵌段共聚物混合物
公开(公告)号：US20080269414A1
公开(公告)日：2008-10-30
申请号：US11813742
申请日：2005-12-31
申请人： Konrad Knoll , Helmut Steininger , Michael Schuster , Daniel Wagner , Peter Merkel
发明人： Konrad Knoll , Helmut Steininger , Michael Schuster , Daniel Wagner , Peter Merkel
IPC分类号： C08L53/02
CPC分类号： C08L53/02 , C08L2666/24
摘要： A mixture which comprises a) from 5 to 50% by weight of a block copolymer A which comprises one or more oopolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transtion temperature TgA in the range from 40° to 90° C. b) from 95 to 50% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0°C. c) from 0 to 45% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer, and its use for production of shrink films.
摘要翻译：一种混合物，其包含a）5至50重量％的嵌段共聚物A，其包含一种或多种聚合物嵌段（B / S）A A，各自由65至95重量％的乙烯基芳族单体和35至5重量％的二烯，玻璃化转变温度Tg A A在40℃至90℃的范围内。b）95至50重量％的嵌段共聚物 B，其包含至少一个由乙烯基芳族单体组成的硬块S，并且包含一个或多个共聚物嵌段（B / S）B，每个由20至60重量％的乙烯基芳族单体组成，80至 40重量％的二烯和玻璃化转变温度Tg B 在-70℃至0℃的范围内。 c）0至45重量％的聚苯乙烯或除A和B之外的嵌段共聚物C，以及d）0至6重量％的增塑剂，以及其用于生产收缩膜的用途。

19. 发明授权

US08759445B2 Styrene butadiene block copolymer mixtures for shrink-wrap films 有权
标题翻译：用于收缩膜的苯乙烯丁二烯嵌段共聚物混合物
公开(公告)号：US08759445B2
公开(公告)日：2014-06-24
申请号：US13000817
申请日：2009-06-23
申请人： Matthias Müller , Konrad Knoll , Christof Mehler , Helmut Steininger , Norbert Güntherberg , Daniel Wagner , Michael Schuster , Geert Verlinden , Florian Greger
发明人： Matthias Müller , Konrad Knoll , Christof Mehler , Helmut Steininger , Norbert Güntherberg , Daniel Wagner , Michael Schuster , Geert Verlinden , Florian Greger
IPC分类号： C08L53/02 , C08F297/04
CPC分类号： C08L53/02 , C08F297/04 , C08L2666/02 , C08L2666/24
摘要： A mixture which comprises a) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C., c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, and d) from 0 to 6% by weight of processing aids D, where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.
摘要翻译：一种混合物，其包含a）5至95重量％的共聚物A，其包含一种或多种共聚物嵌段（B / S）A，每个共聚物嵌段（B / S）A由65至95重量％的乙烯基芳族单体和35至5重量％二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内，b）95至5重量％的嵌段共聚物B，其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯，并且包含一种或多种共聚物嵌段（B / S）A，各自由65至95重量％的乙烯基芳族单体和35至5重量％的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA，并且包含一种或多种共聚物嵌段（B / S）B，各自由20至60重量％的乙烯基芳族单体组成， 80〜40重量％的二烯，玻璃化转变温度TgB在-70℃〜0℃的范围内，c）0〜45％的重量除了A和B之外的热塑性聚合物C，以及d）0至6重量％的加工助剂D，其中A至D的总量为100重量％，以及其用于生产收缩膜的用途。

20. 发明申请

US20120107540A1 ELASTOMERIC BLOCK COPOLYMERS HAVING STAR-SHAPED MOLECULAR ARCHITECTURE, WHERE THE STAR-SHAPED MOLECULAR ARCHITECTURE HAS AT LEAST TWO DIFFERENT ARMS IN THE STAR 有权
标题翻译：具有星型分子结构的弹性体嵌段共聚物，星型分子结构在星形中至少有两种不同的结构
公开(公告)号：US20120107540A1
公开(公告)日：2012-05-03
申请号：US13283275
申请日：2011-10-27
申请人： Konrad Knoll , Daniel Wagner , Andrea Colmbo , Geert Verlinden
发明人： Konrad Knoll , Daniel Wagner , Andrea Colmbo , Geert Verlinden
IPC分类号： B32B1/08 , C08F8/00 , C08F8/42 , C08F297/00
CPC分类号： B32B7/12 , C08F8/04 , C08F297/044 , Y10T428/139
摘要： Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.
摘要翻译：具有星形分子结构的弹性嵌段共聚物，其中星形分子结构具有至少两个不同的星形臂，制备弹性体嵌段共聚物的方法，弹性体嵌段共聚物用于生产模制品或粘合剂多层箔; 作为密封; 作为木塑复合材料中的粘合促进剂或热塑性组分; 作为热熔胶组件; 用于冲击改性热塑性塑料或弹性体，或用于增容，以及由至少一种弹性体嵌段共聚物组成的箔，泡沫，热塑性塑料，注射成形品，柔性管或型材挤出物。

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