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11. 发明申请

US20090186952A1 Process for the Preparation and Conversion of Synthesis Gas. 有权
标题翻译：合成气的制备和转化方法。
公开(公告)号：US20090186952A1
公开(公告)日：2009-07-23
申请号：US11922380
申请日：2006-06-14
申请人： Andre Peter Steynberg , Ib Dybkjaer , Kim Aasberg-Petersen
发明人： Andre Peter Steynberg , Ib Dybkjaer , Kim Aasberg-Petersen
IPC分类号： C07C27/00
CPC分类号： C01B3/384 , B01J23/755 , B01J37/0201 , C01B3/382 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/062 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C10G2/32 , C10G2/332 , C10G2300/4081 , C10K1/005 , C10K3/006 , Y02P20/52
摘要： A process (10) for the preparation and conversion of synthesis gas includes reforming a feed gas (34) comprising methane in a reforming stage (18) to produce synthesis gas (46) which includes hydrogen and carbon monoxide. Some of the hydrogen and carbon monoxide is converted to a Fischer-Tropsch product (48) in a Fischer-Tropsch hydrocarbon synthesis stage (24). A tail gas (52), including unreacted hydrogen and carbon monoxide, methane and carbon dioxide, is separated from the Fischer-Tropsch product (48). In a tail gas treatment stage (28,30), the tail gas (52) is treated by reforming the methane in the tail gas (52) with steam (66) and removing carbon dioxide to produce a hydrogen rich gas (56). The tail gas treatment stage (28,30) may be either a combined tail gas treatment stage (28,30) or a composite tail gas treatment stage. The carbon dioxide from the tail gas treatment stage (28,30) is fed to the reforming stage (18).
摘要翻译：用于制备和转化合成气的方法（10）包括在重整阶段（18）中重整包含甲烷的进料气体（34）以产生包括氢气和一氧化碳的合成气体（46）。在费 - 托烃合成阶段（24）中，一些氢和一氧化碳转化成费 - 托产物（48）。包含未反应的氢气和一氧化碳的甲烷和二氧化碳的尾气（52）从费 - 托产物（48）中分离出来。在尾气处理阶段（28,30）中，通过用蒸汽（66）重整尾气（52）中的甲烷并除去二氧化碳以产生富氢气体（56）来处理尾气（52）。尾气处理阶段（28,30）可以是组合尾气处理阶段（28,30）或复合尾气处理阶段。来自尾气处理阶段（28,30）的二氧化碳被供给到重整阶段（18）。

12. 发明授权

US06730285B2 Production of hydrogen and carbon monoxide containing synthesis gas by partial oxidation 失效
标题翻译：通过部分氧化生产含氢和一氧化碳的合成气
公开(公告)号：US06730285B2
公开(公告)日：2004-05-04
申请号：US09955455
申请日：2001-09-18
申请人： Kim Aasberg-Petersen , Thomas Sandahl Christensen
发明人： Kim Aasberg-Petersen , Thomas Sandahl Christensen
IPC分类号： C01B326
CPC分类号： C01B3/382 , C01B3/386 , C01B2203/0244 , C01B2203/0261 , C01B2203/0844 , C01B2203/1241 , C01B2203/143 , C01B2203/82
摘要： A process for the preparation of a synthesis gas containing hydrogen and carbon monoxide by a combination of catalytic partial oxidation and further an autothermal reforming process, comprising (a) providing separate streams of predetermined proportions of a hydrocarbon feedstock, an oxygen source and of process steam, (b) injecting said separate streams into a catalytic partial oxidation reaction zone to react, and to form a prereformed product stream, (c) introducing the prereformed product and a predetermined proportion of a second oxygen source into a further partial oxidation process step forming a further partially oxidised process stream by flame reactions, (d) reacting the further partially oxidised process stream in the reaction zone constituting a steam reforming process step to form a synthesis gas product stream, and (e) withdrawing the synthesis gas product stream from the further partial oxidation process step and the steam reforming process step, the two steps constituting the autothermal reforming process.
摘要翻译：一种通过催化部分氧化和进一步的自热重整方法的组合制备含有氢和一氧化碳的合成气的方法，包括（a）提供预定比例的烃原料，氧源和工艺蒸汽的单独流，（b）将所述分离的物流注入催化部分氧化反应区以进行反应，并形成预重整的产物流，（c）将预转化产物和预定比例的第二氧源引入另外的部分氧化工艺步骤中形成通过火焰反应进一步部分氧化的工艺流，（d）使构成蒸汽重整工艺步骤的反应区中的进一步部分氧化的工艺流反应以形成合成气产物流，和（e）从合成气产物流中取出合成气产物流进一步的部分氧化工艺步骤和蒸汽重整工艺步骤，两步构成 e自热重整过程。

13. 发明授权

US09162886B2 Process for reforming hydrocarbons 有权
标题翻译：烃类重整方法
公开(公告)号：US09162886B2
公开(公告)日：2015-10-20
申请号：US14129244
申请日：2012-06-20
申请人： Kim Aasberg-Petersen , Peter Seier Christensen , Thomas Sandahl Christensen
发明人： Kim Aasberg-Petersen , Peter Seier Christensen , Thomas Sandahl Christensen
IPC分类号： C01B3/24 , C01B3/38 , C07C1/04 , C10G2/00 , C10K3/02
CPC分类号： C10K3/02 , B01D53/72 , C01B3/24 , C01B3/34 , C01B3/36 , C01B3/38 , C01B3/382 , C01B3/386 , C01B2203/0227 , C01B2203/0233 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/062 , C01B2203/1235 , C01B2203/1258 , C01B2203/1276 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C07C1/0485 , C10G2/30 , C10G2/31 , C10G2/32 , C10G2300/4075
摘要： The invention relates to a process for the production of synthesis gas by the use of autothermal reforming in which tail gas from downstream Fischer-Tropsh synthesis is hydrogenated and then added to the autothermal reforming stage.
摘要翻译：本发明涉及一种通过使用自热重整制备合成气的方法，其中将来自下游费 - 托罗普合成的尾气氢化，然后加入到自热重整阶段。

14. 发明授权

US08106102B2 Process for the preparation and conversion of synthesis gas 有权
标题翻译：合成气的制备和转化方法
公开(公告)号：US08106102B2
公开(公告)日：2012-01-31
申请号：US11922380
申请日：2006-06-14
申请人： Andre Peter Steynberg , Ib Dybkjaer , Kim Aasberg-Petersen
发明人： Andre Peter Steynberg , Ib Dybkjaer , Kim Aasberg-Petersen
IPC分类号： C07C27/00
CPC分类号： C01B3/384 , B01J23/755 , B01J37/0201 , C01B3/382 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/062 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C10G2/32 , C10G2/332 , C10G2300/4081 , C10K1/005 , C10K3/006 , Y02P20/52
摘要： A process (10) for the preparation and conversion of synthesis gas includes reforming a feed gas (34) comprising methane in a reforming stage (18) to produce synthesis gas (46) which includes hydrogen and carbon monoxide. Some of the hydrogen and carbon monoxide is converted to a Fischer-Tropsch product (48) in a Fischer-Tropsch hydrocarbon synthesis stage (24). A tail gas (52), including unreacted hydrogen and carbon monoxide, methane and carbon dioxide, is separated from the Fischer-Tropsch product (48). In a tail gas treatment stage (28,30), the tail gas (52) is treated by reforming the methane in the tail gas (52) with steam (66) and removing carbon dioxide to produce a hydrogen rich gas (56). The tail gas treatment stage (28,30) may be either a combined tail gas treatment stage (28,30) or a composite tail gas treatment stage. The carbon dioxide from the tail gas treatment stage (28,30) is fed to the reforming stage (18).
摘要翻译：用于制备和转化合成气的方法（10）包括在重整阶段（18）中重整包含甲烷的进料气体（34）以产生包括氢气和一氧化碳的合成气体（46）。在费 - 托烃合成阶段（24）中，一些氢和一氧化碳转化成费 - 托产物（48）。包含未反应的氢气和一氧化碳的甲烷和二氧化碳的尾气（52）从费 - 托产物（48）中分离出来。在尾气处理阶段（28,30）中，通过用蒸汽（66）重整尾气（52）中的甲烷并除去二氧化碳以产生富氢气体（56）来处理尾气（52）。尾气处理阶段（28,30）可以是组合尾气处理阶段（28,30）或复合尾气处理阶段。来自尾气处理阶段（28,30）的二氧化碳被供给到重整阶段（18）。

15. 发明申请

US20060057058A1 Process for reforming ethanol 有权
标题翻译：乙醇改性方法
公开(公告)号：US20060057058A1
公开(公告)日：2006-03-16
申请号：US10940762
申请日：2004-09-15
申请人： Soren Dahl , Charlotte Nielsen , Poul Erik Nielsen , Kim Aasberg-Petersen
发明人： Soren Dahl , Charlotte Nielsen , Poul Erik Nielsen , Kim Aasberg-Petersen
IPC分类号： C01B3/02
CPC分类号： C01B3/382 , C01B2203/0233 , C01B2203/066 , C01B2203/1241 , C01B2203/1264 , C01B2203/142
摘要： Process for selectively reforming ethanol to a hydrogen-rich product in the presence of at least one catalyst comprising a catalytically active material supported on a carrier, the process comprising the following steps in which the at least one catalyst is active: transferring a stream of ethanol and steam and a hydrogen-comprising stream, the molar ratio of ethanol to hydrogen being 0.2-1, to a dehydration/hydrogenation reactor for dehydrating ethanol to ethylene and for hydrogenating ethylene to produce an ethane-containing stream, adiabatically pre-reforming the ethane-comprising stream to a stream comprising methane, steam reforming the stream comprising methane to produce a mixture comprising hydrogen and carbon monoxide, converting the mixture comprising hydrogen and carbon monoxide from the steam reforming step under water gas shift conditions to produce a hydrogen-rich product stream.
摘要翻译：在至少一种包含负载在载体上的催化活性物质的催化剂存在下，将乙醇选择性地重整成富氢产物的方法，所述方法包括以下步骤：其中所述至少一种催化剂是有活性的：将乙醇流和蒸汽和含氢气流，乙醇与氢气的摩尔比为0.2-1，用于脱乙醇/氢化反应器，用于将乙醇脱水成乙烯和氢化乙烯以产生含乙烷的流，绝热地重整乙烷包含甲烷的流，对包含甲烷的流进行蒸汽重整以产生包含氢气和一氧化碳的混合物，在水煤气变换条件下将来自蒸汽重整步骤的氢和一氧化碳的混合物转化，以产生富氢产物流。

16. 发明授权

US5705916A Process for the generation of electrical power 失效
标题翻译：发电的过程
公开(公告)号：US5705916A
公开(公告)日：1998-01-06
申请号：US587581
申请日：1996-01-17
申请人： Poul Rudbeck , Kim Aasberg-Petersen , Susanne L.oe butted.gsgaard J.o slashed.rgensen , Poul Erik H.o slashed.jlund Nielsen
发明人： Poul Rudbeck , Kim Aasberg-Petersen , Susanne L.oe butted.gsgaard J.o slashed.rgensen , Poul Erik H.o slashed.jlund Nielsen
IPC分类号： F01K23/16 , C01B3/38 , C01B3/50 , F01K23/10 , F02C3/20 , F02C3/28 , F02C6/00 , F02C6/02 , F02C6/18 , F02C9/40 , H01M8/06 , H02N3/00
CPC分类号： C01B3/505 , C01B3/384 , F01K23/10 , F02C3/20 , F02C6/003 , C01B2203/0233 , C01B2203/041 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/06 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1058 , C01B2203/1241 , Y02P20/128
摘要： A process for generating electrical power in a gas turbine cycle including an air compression stage, first and second gas combustion stages, and a series of first and second gas expansion stages. Mechanical power is provided for the generation of electrical power in a rotating power generator. The first combustion stage is operated on hydrogen-depleted fuel gas at high pressure using air from the air compression stage. The hydrogen-depleted fuel gas is obtained by endothermic catalytic steam reforming of a hydrocarbon feed gas. Heat for the endothermic steam reforming is supplied by indirect heat exchange with heat from hot exhaust gas from the second expansion stage. The second combustion stage is operated at lower pressure than the first combustion stage on exhaust gas from the first expansion stage and the hydrogen-enriched gas separated form the hydrogen depleted gas. The hydrogen-enriched gas is separated from the hydrogen-depleted fuel gas during the catalytic steam reforming of the feed gas.
摘要翻译：一种用于在包括空气压缩级，第一和第二气体燃烧级以及一系列第一和第二气体膨胀级的燃气轮机循环中产生电力的过程。提供了用于在旋转发电机中产生电力的机械功率。第一燃烧阶段使用来自空气压缩级的空气在高压下在贫氢燃料气体下运行。通过烃进料气体的吸热催化蒸汽重整获得贫氢燃料气体。用于吸热蒸汽重整的热量通过来自第二膨胀级的热废气的热量的间接热交换而提供。第二燃烧阶段在比来自第一膨胀级的废气的第一燃烧阶段低的压力下工作，并且富氢气体从贫氢气体分离。在进料气体的催化蒸汽重整期间，富氢气体与贫氢燃料气体分离。

17. 发明授权

US08889089B2 Process for a reduction in the amount of sulphur compounds, hydrogen cyanide, and formic acid in synthesis gas 有权
标题翻译：合成气中硫化合物，氰化氢和甲酸的量减少的方法
公开(公告)号：US08889089B2
公开(公告)日：2014-11-18
申请号：US12739677
申请日：2008-10-23
申请人： Kim Aasberg-Petersen , Ib Dybkjaer , Poul Erik Højlund Nielsen
发明人： Kim Aasberg-Petersen , Ib Dybkjaer , Poul Erik Højlund Nielsen
IPC分类号： B01D47/00 , B01D53/46 , B01D53/56 , B01J8/00 , C01B21/00 , B01D53/14 , C01C3/00 , B01D53/86 , B01D53/52 , C01B17/00 , C01B7/00 , C01B3/58 , C01B3/56 , B01D53/04
CPC分类号： B01D53/04 , B01D53/8603 , B01D2253/104 , B01D2253/112 , B01D2255/1021 , B01D2255/1023 , B01D2255/104 , B01D2255/106 , B01D2257/30 , C01B3/56 , C01B3/58 , C01B2203/0425 , C01B2203/0435 , C01B2203/0465 , C01B2203/0475 , C01B2203/048 , C01B2203/0485
摘要： A process for a reduction in the amount of sulphur compounds, hydrogen cyanide, formic acid and formic acid derivatives in synthesis gas comprising these compounds, the process comprising contacting the synthesis gas with a sulphur absorbent comprising material and thereafter with a catalyst comprising one or more metals selected from the group consisting of silver, gold, copper, palladium, platinum and their mixtures and supported on a carrier comprising at least one of the oxides of scandium, yttrium, lanthanum, cerium, titanium, zirconium, aluminum, zinc, chromium and molybdenum.
摘要翻译：包含这些化合物的合成气中的硫化合物，氰化氢，甲酸和甲酸衍生物的量的减少的方法，该方法包括使合成气与含硫吸收剂的材料接触，然后与含有一种或多种选自银，金，铜，钯，铂及其混合物的金属，并负载在包含钪，钇，镧，铈，钛，锆，铝，锌，铬中的至少一种氧化物的载体上，钼。

18. 发明授权

US08765019B2 Process for the preparation of synthesis gas 有权
标题翻译：合成气的制备方法
公开(公告)号：US08765019B2
公开(公告)日：2014-07-01
申请号：US13701488
申请日：2011-05-13
申请人： Kim Aasberg-Petersen , Poul Erik Højlund Nielsen , Peter Seier Christensen , Charlotte Stub Nielsen , Burcin Temel
发明人： Kim Aasberg-Petersen , Poul Erik Højlund Nielsen , Peter Seier Christensen , Charlotte Stub Nielsen , Burcin Temel
IPC分类号： C01B3/48
CPC分类号： C01B3/48 , C01B3/16 , C01B3/36 , C01B3/382 , C01B3/386 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/0283 , C01B2203/062 , C01B2203/1264 , C10G2/32 , C10G2300/1022 , C10G2300/807 , C10G2400/02
摘要： Process for the preparation of synthesis gas from an essentially dry hydrocarbon feedstock (1) comprising olefins, hydrogen and carbon monoxide, the process comprising the steps: (a) selectively hydrogenating the olefins in the hydrocarbon feedstock at a temperature between 60 to 190° C. (2) to obtain a hydrogenated hydrocarbon feedstock comprising hydrogen, carbon monoxide and saturated hydrocarbons (3; (b) adding steam (4) to the hydrogenated hydrocarbon feedstock; (c) performing a water gas shift reaction in the presence of steam on the hydrogenated hydrocarbon feedstock (6) to obtain a shifted, hydrogenated hydrocarbon mixture; (d) converting the shifted, hydrogenated hydrocarbon mixture (8) to obtain a synthesis gas.
摘要翻译：用于从包含烯烃，氢气和一氧化碳的基本上干的烃原料（1）制备合成气的方法，该方法包括以下步骤：（a）在60至190℃的温度下选择性氢化烃原料中的烯烃（2）获得包含氢气，一氧化碳和饱和烃的氢化烃原料（3;（b）向氢化烃原料中加入蒸汽（4）;（c）在蒸汽存在下进行水煤气变换反应氢化烃原料（6）以获得偏移的氢化烃混合物;（d）转化转移的氢化烃混合物（8）以获得合成气。

19. 发明申请

US20140135409A1 PROCESS FOR REFORMING HYDROCARBONS 有权
标题翻译：改造石油烃的方法
公开(公告)号：US20140135409A1
公开(公告)日：2014-05-15
申请号：US14129244
申请日：2012-06-20
申请人： Kim Aasberg-Petersen , Peter Seier Cristensen , Thomas Sandahl Christensen
发明人： Kim Aasberg-Petersen , Peter Seier Cristensen , Thomas Sandahl Christensen
IPC分类号： C01B3/24 , C07C1/04
CPC分类号： C10K3/02 , B01D53/72 , C01B3/24 , C01B3/34 , C01B3/36 , C01B3/38 , C01B3/382 , C01B3/386 , C01B2203/0227 , C01B2203/0233 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/062 , C01B2203/1235 , C01B2203/1258 , C01B2203/1276 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C07C1/0485 , C10G2/30 , C10G2/31 , C10G2/32 , C10G2300/4075
摘要： The invention relates to a process for the production of synthesis gas by the use of autothermal reforming in which tail gas from downstream Fischer-Tropsh synthesis is hydrogenated and then added to the autothermal reforming stage.
摘要翻译：本发明涉及一种通过使用自热重整制备合成气的方法，其中将来自下游费 - 托罗普合成的尾气氢化，然后加入到自热重整阶段。

20. 发明授权

US07585339B2 Process for reforming ethanol to hydrogen-rich products 有权
标题翻译：将乙醇重整成富氢产品的方法
公开(公告)号：US07585339B2
公开(公告)日：2009-09-08
申请号：US10940762
申请日：2004-09-15
申请人： Søren Dahl , Charlotte Stub Nielsen , Poul Erik Højlund Nielsen , Kim Aasberg-Petersen
发明人： Søren Dahl , Charlotte Stub Nielsen , Poul Erik Højlund Nielsen , Kim Aasberg-Petersen
IPC分类号： C01B3/02
CPC分类号： C01B3/382 , C01B2203/0233 , C01B2203/066 , C01B2203/1241 , C01B2203/1264 , C01B2203/142
摘要： Process for selectively reforming ethanol to a hydrogen-rich product in the presence of at least one catalyst comprising a catalytically active material supported on a carrier, the process comprising the following steps in which the at least one catalyst is active: transferring a stream of ethanol and steam and a hydrogen-comprising stream, the molar ratio of ethanol to hydrogen being 0.2-1, to a dehydration/hydrogenation reactor for dehydrating ethanol to ethylene and for hydrogenating ethylene to produce an ethane-containing stream, adiabatically pre-reforming the ethane-comprising stream to a stream comprising methane, steam reforming the stream comprising methane to produce a mixture comprising hydrogen and carbon monoxide, converting the mixture comprising hydrogen and carbon monoxide from the steam reforming step under water gas shift conditions to produce a hydrogen-rich product stream.
摘要翻译：在至少一种包含负载在载体上的催化活性物质的催化剂存在下，将乙醇选择性地重整成富氢产物的方法，所述方法包括以下步骤：其中所述至少一种催化剂是有活性的：将乙醇流和蒸汽和含氢气流，乙醇与氢气的摩尔比为0.2-1，用于脱乙醇/氢化反应器，用于将乙醇脱水成乙烯和氢化乙烯以产生含乙烷的流，绝热地重整乙烷包含甲烷的流，对包含甲烷的流进行蒸汽重整以产生包含氢气和一氧化碳的混合物，在水煤气变换条件下将来自蒸汽重整步骤的氢和一氧化碳的混合物转化，以产生富氢产物流。

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