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11. 发明授权

US5286370A Catalytic cracking using a layered cracking catalyst 失效
标题翻译：使用层状裂化催化剂进行催化裂化
公开(公告)号：US5286370A
公开(公告)日：1994-02-15
申请号：US808487
申请日：1991-12-17
申请人： Pochen Chu , Albin Huss, Jr. , Hartley Owen , Joseph A. Herbst , Garry W. Kirker , Paul H. Schipper
发明人： Pochen Chu , Albin Huss, Jr. , Hartley Owen , Joseph A. Herbst , Garry W. Kirker , Paul H. Schipper
IPC分类号： B01J33/00 , C10G11/05 , B01J29/06
CPC分类号： C10G11/05 , B01J33/00 , B01J2229/12 , B01J2229/42 , C10G2300/70
摘要： A layered catalyst contains a core of at least one, and preferably three, molecular sieve components within a shell layer of reduced molecular sieve content. A preferred catalyst consists of a core of a large pore molecular sieve, preferably a dealuminized Y-type zeolite, a shape selective paraffin cracking/isomerization component, preferably HZSM-5, and a shape selective aliphatic aromatization component, preferably gallium ZSM-5, within a shell of an alumina-rich, matrix. The shell can capture metals from the feeds being processed, it can act as a metals sink, and can remove metals form the unit by attrition. The catalyst is preferably prepared by forming the core and then coating or encapsulating the core with a shell having a reduced molecular sieve content. The shell may contain a pillared clay or other very large pore cracking component. The shell may be an attritable coating of an amorphous rare earth oxide, aluminum oxide and aluminum phosphate composite, which traps metals.
摘要翻译：层状催化剂在分子筛含量降低的壳层内含有至少一种，优选三种分子筛组分的核心。优选的催化剂由大孔分子筛的芯，优选脱铝的Y型沸石，形状选择性石蜡裂解/异构化组分，优选HZSM-5和形状选择性脂族芳构化组分，优选镓ZSM-5组成，在富含氧化铝的基体的壳内。外壳可以从正在加工的进料中捕获金属，它可以作为金属沉头，并可以通过磨损去除单元的金属。催化剂优选通过形成核心然后用具有降低的分子筛含量的壳体涂覆或包封核心来制备。壳可能含有柱状粘土或其他非常大的孔裂解组分。壳可以是非晶态稀土氧化物，氧化铝和磷酸铝复合物的可磨损涂层，其捕获金属。

12. 发明授权

US5037530A Catalytic cracking with layered silicates 失效
标题翻译：层状硅酸盐催化裂化
公开(公告)号：US5037530A
公开(公告)日：1991-08-06
申请号：US396712
申请日：1989-08-22
申请人： Garry W. Kirker , Thomas F. Degnan, Jr. , Albin Huss, Jr. , Michael E. Landis
发明人： Garry W. Kirker , Thomas F. Degnan, Jr. , Albin Huss, Jr. , Michael E. Landis
IPC分类号： B01J29/04 , C10G11/05 , C10G11/18
CPC分类号： B01J29/049 , C10G11/05
摘要： There is provided a process for cracking hydrocarbon feedstocks which include large hydrocarbon molecules. Examples of such feedstocks are those which include a large proportion of resids. The catalyst used in this process comprises a layered silicate, such as magadiite, containing interspathic polymeric silica which serves to prop open the layers.
摘要翻译：提供了一种用于裂解烃原料的方法，其包括大的烃分子。这些原料的实例是包括大量残留物的那些。在该方法中使用的催化剂包括层状硅酸盐，例如马来半晶硅，其包含用于支撑开放层的层间聚合物二氧化硅。

13. 发明授权

US5001096A Metal passivating agents 失效
标题翻译：金属钝化剂
公开(公告)号：US5001096A
公开(公告)日：1991-03-19
申请号：US335068
申请日：1989-04-07
申请人： Pochen Chu , Albin Huss, Jr. , Garry W. Kirker
发明人： Pochen Chu , Albin Huss, Jr. , Garry W. Kirker
IPC分类号： B01J33/00 , C10G11/05
CPC分类号： C10G11/05 , B01J33/00 , B01J2229/12 , B01J2229/42 , C10G2300/70 , Y10S502/516 , Y10S502/521
摘要： The invention describes the preparation of novel cracking catalysts by surface coating conventional cracking catalysts with passivators that act as metals traps. The coating of passivators is weakly bound to the catalyst so as to permit the coating to continuously attrit off during catalytic cracking. The continuous flaking off of the coating exposes a new surface of the coating.
摘要翻译：本发明描述了通过用作为金属阱的钝化剂表面涂覆常规裂化催化剂来制备新的裂化催化剂。钝化剂的涂层与催化剂弱结合，从而允许涂层在催化裂化过程中持续磨损。涂层的连续剥落暴露了涂层的新表面。

14. 发明授权

US4992615A Isoparaffin-olefin alkylation process 失效
标题翻译：异链烷烃烯烃烷基化方法
公开(公告)号：US4992615A
公开(公告)日：1991-02-12
申请号：US470014
申请日：1990-01-25
申请人： Albin Huss, Jr. , Garry W. Kirker , Kathleen M. Keville , Robert T. Thomson
发明人： Albin Huss, Jr. , Garry W. Kirker , Kathleen M. Keville , Robert T. Thomson
IPC分类号： C07C2/58
CPC分类号： C07C2/58 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/12 , C07C2529/06
摘要： The alkylation of isoparaffin with olefin to provide alkylate is carried out in the presence of, as catalyst, a porous crystalline material characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译：异链烷烃与烯烃的烷基化以提供烷基化物在作为催化剂存在的多孔结晶材料的存在下进行，其特征在于X射线衍射图包括12.36 +/- 0.4,11.03 +/- 0.2的面间d-间距， 8.83 +/- 0.14，6.18 +/- 0.12，6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。

15. 发明授权

US5063038A Zeolite synthesis using an alcohol or like molecule 失效
标题翻译：使用醇或类似分子的沸石合成
公开(公告)号：US5063038A
公开(公告)日：1991-11-05
申请号：US91612
申请日：1987-08-31
申请人： Garry W. Kirker , Donald J. Klocke , James C. Vartuli , Pochen Chu , David O. Marler , John P. McWilliams
发明人： Garry W. Kirker , Donald J. Klocke , James C. Vartuli , Pochen Chu , David O. Marler , John P. McWilliams
IPC分类号： B01J29/40 , B01J29/65 , B01J29/70 , C01B39/48 , C07C2/66 , C07C4/18
CPC分类号： C07C4/18 , B01J29/40 , B01J29/65 , B01J29/7046 , C01B39/48 , C07C2/66 , B01J2229/20 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/65 , C07C2529/70 , Y10S423/35 , Y10S423/36
摘要： There is provided a method for preparing a zeolite other than ZSM-5 from a reaction mixture comprising a mixed organic directing agent which is a combination of (a) an organic nitrogen containing compound such as an amine or a quaternary ammonium compound and (b) an alcohol and/or diol. Particular zeolites synthesized by this method include ZSM-22 and ZSM-23. The use of an alcohol or a diol may inhibit the coformation of ZSM-5. Especially when used to prepare ZSM-23, this method enables the preparation of more catalytically active ZSM-23 of reduced crystallite size and also enables the use of lower crystallization temperatures. Particular mixed organic directing agents for the preparation of ZSM-23 are combination of (a) pyrrolidine and (b) ethanol or ethylene glycol. Other factors which enhance the activity of ZSM-23 include the use of the following in the reaction mixtures for preparing ZSM-23: potassium ions; precipitated silica particles as sources of silica; and spray dried precipitated silica/alumina particles as sources of silica and alumina. The catalytic stability of alumina bound ZSM-23 catalysts is especially enhanced by steaming. Particular reactions which can be catalyzed by ZSM-23 made according to methods described herein include the dealkylation of ethylbenzene and the alkylation of benzene with ethylene.
摘要翻译：提供了一种从含有（a）有机氮化合物如胺或季铵化合物的组合的混合有机导向剂的反应混合物制备ZSM-5以外的沸石的方法，（b）醇和/或二醇。通过该方法合成的特定沸石包括ZSM-22和ZSM-23。使用醇或二醇可能会抑制ZSM-5的共形。特别是当用于制备ZSM-23时，该方法能够制备更小的微晶尺寸的更具催化活性的ZSM-23，并且还能够使用较低的结晶温度。用于制备ZSM-23的特殊混合有机导向剂是（a）吡咯烷和（b）乙醇或乙二醇的组合。提高ZSM-23活性的其他因素包括在制备ZSM-23：钾离子的反应混合物中使用以下物质：沉淀二氧化硅颗粒作为二氧化硅来源; 和喷雾干燥的沉淀二氧化硅/氧化铝颗粒作为二氧化硅和氧化铝的来源。氧化铝结合的ZSM-23催化剂的催化稳定性通过蒸汽特别提高。根据本文所述方法制备的可以由ZSM-23催化的特定反应包括乙苯的脱烷基化和苯与乙烯的烷基化。

16. 发明授权

US5043512A Alkylaromatic isomerization process 失效
标题翻译：烷基芳族异构化过程
公开(公告)号：US5043512A
公开(公告)日：1991-08-27
申请号：US576566
申请日：1990-08-31
申请人： Pochen Chu , Garry W. Kirker , John D. Kushnerick , David O. Marler
发明人： Pochen Chu , Garry W. Kirker , John D. Kushnerick , David O. Marler
IPC分类号： B01J29/86 , B01J29/04 , B01J29/70 , B01J29/87 , B01J29/88 , C07B61/00 , C07C2/12 , C07C5/27 , C07C15/02 , C07C15/08
CPC分类号： C07C5/2708 , B01J29/04 , C07C2/12 , C07C5/2737 , C07C2529/70
摘要： A process is provided for converting feedstock alkylaromatic compounds by isomerization over a catalyst comprising MCM-22.
摘要翻译：提供了通过在包含MCM-22的催化剂上异构化来转化原料烷基芳族化合物的方法。

17. 发明授权

US5236681A Layered silicate 失效
标题翻译：层状硅酸盐
公开(公告)号：US5236681A
公开(公告)日：1993-08-17
申请号：US443692
申请日：1989-11-30
申请人： Pochen Chu , Garry W. Kirker , Sowmithri Krishnamurthy , James C. Vartuli
发明人： Pochen Chu , Garry W. Kirker , Sowmithri Krishnamurthy , James C. Vartuli
IPC分类号： C01B33/38
CPC分类号： C01B33/38
摘要： There is provided a method for synthesizing layered silicates such as magadiite and kenyaite. The source of silica used in this method is freshly precipitated from a silicate solution. For example, this silica source may be obtained by treating an aqueous solution of sodium silicate with sulfuric acid to form an amorphous silica precipitate. This silica precipitate is not dried to reduce its activity prior to use.
摘要翻译：提供了一种合成层状硅酸盐的方法，例如magadiite和kenyaite。在这种方法中使用的二氧化硅源从硅酸盐溶液中新鲜沉淀出来。例如，可以通过用硫酸处理硅酸钠水溶液以形成无定形二氧化硅沉淀物来获得该二氧化硅源。该二氧化硅沉淀物在使用前不被干燥以降低其活性。

18. 发明授权

US5015360A Production of hydrocarbon fractions by hydrocracking 失效
$Production of hydrocarbon fractions by hydrocracking$
标题翻译：通过加氢裂化生产烃馏分
公开(公告)号：US5015360A
公开(公告)日：1991-05-14
申请号：US459216
申请日：1989-12-29
申请人： Thomas F. Degnan , Garry W. Kirker , Richard F. Socha , Michael R. Stapleton , Ivy D. Johnson
发明人： Thomas F. Degnan , Garry W. Kirker , Richard F. Socha , Michael R. Stapleton , Ivy D. Johnson
IPC分类号： B01J21/06 , B01J29/04 , C01B13/14 , C01B17/20 , C01B17/42 , C01B19/00 , C01G23/00 , C07C2/08 , C07C2/10 , C10G45/04 , C10G47/02 , C10G49/04 , C10G49/08
CPC分类号： B01J29/049 , C01B13/145 , C01B17/20 , C01B17/42 , C01B19/007 , C01G23/003 , C07C2/08 , C07C2/10 , C10G45/04 , C01P2002/02 , C01P2002/22 , C01P2002/70 , C01P2002/72 , C01P2002/74 , C01P2002/78 , C01P2006/12 , C01P2006/42 , C01P2006/80 , C07C2521/06 , C07C2521/08 , C07C2521/12 , Y10S502/525
摘要： A process for hydrocracking 343.degree. C..sup.+ feedstock is disclosed. The process employs a catalyst which comprises a layered silicate, such as magadiite or kenyaite, which contains interspathic polymeric silica. The catalyst also contains at least one base metal, i.e., Cr, Mo, W, Fe, Co, and Ni.
摘要翻译：公开了加氢裂化343℃+原料的方法。该方法使用包含层状硅酸盐的催化剂，例如含有岩浆聚合物二氧化硅的岩浆岩或肯尼亚岩。催化剂还含有至少一种贱金属，即Cr，Mo，W，Fe，Co和Ni。

19. 发明授权

US4834869A Resid upgrading process 失效
标题翻译：残库升级过程
公开(公告)号：US4834869A
公开(公告)日：1989-05-30
申请号：US161693
申请日：1988-02-29
申请人： Philip J. Angevine , Pochen Chu , Thomas F. Degnan , Garry W. Kirker
发明人： Philip J. Angevine , Pochen Chu , Thomas F. Degnan , Garry W. Kirker
IPC分类号： B01J27/18 , B01J27/16 , B01J27/185 , B01J32/00 , B01J35/10 , B01J37/03 , C10G45/04 , C10G47/10
CPC分类号： B01J37/03 , B01J29/84 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/108
摘要： This invention relates to a method of preparing a metal-containing amorphous magnesia-alumina-aluminum phosphate catalyst support involving the admixture of an organic cation having a size equal to or greater than 2 Angstroms, the organic cation preferably being a tertiary or a tetraalkylammonium or phosphonium cation. The method permits recovery of a catalyst support having a controlled pore size distribution. The invention also relates to an improved catalytic support as well as an improved petroleum residua upgrading process comprising hydrotreating residua in the presence of the improved catalyst support.
摘要翻译：本发明涉及一种制备含金属的无定形氧化镁 - 氧化铝 - 磷酸铝催化剂载体的方法，该催化剂载体包括大小等于或大于2埃的有机阳离子的混合物，有机阳离子优选为叔烷基铵或四烷基铵或鏻阳离子。该方法允许回收具有可控孔径分布的催化剂载体。本发明还涉及改进的催化剂载体以及改进的石油渣油改质方法，其包括在改进的催化剂载体存在下加氢处理残余物。

20. 发明授权

US4810361A Resid hydrotreating process using lanthana-alumina-aluminum phosphate catalyst 失效
标题翻译：使用镧 - 氧化铝 - 磷酸铝催化剂的残余加氢处理工艺
公开(公告)号：US4810361A
公开(公告)日：1989-03-07
申请号：US50446
申请日：1987-05-18
申请人： Robert P. L. Absil , Philip J. Angevine , Arthur W. Chester , Garry W. Kirker
发明人： Robert P. L. Absil , Philip J. Angevine , Arthur W. Chester , Garry W. Kirker
IPC分类号： B01J27/18 , B01J35/10 , C10G45/04
CPC分类号： B01J27/1804 , B01J35/0026 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G2300/107
摘要： This invention relates to a new and useful improvement in a process for upgrading petroleum residua. The process comprises contacting a vacuum or atmospheric resid feed with a metal-containing lanthana-alumina-aluminum phosphate catalyst whereby the resid feedstock is simultaneously demetallized and desulfurized.
摘要翻译：本发明涉及一种用于升级石油渣的方法的新的和有用的改进。该方法包括使真空或常压残留物与含金属的氧化镧 - 铝 - 磷酸铝催化剂接触，由此将残留物同时脱金属脱硫。

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