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11. 发明授权

US08021786B2 Non-aqueous electrolyte secondary cell 失效
标题翻译：非水电解质二次电池
公开(公告)号：US08021786B2
公开(公告)日：2011-09-20
申请号：US12059196
申请日：2008-03-31
申请人： Atsushi Kaiduka , Masato Iwanaga , Yukihiro Oki
发明人： Atsushi Kaiduka , Masato Iwanaga , Yukihiro Oki
IPC分类号： H01M4/48
CPC分类号： H01M4/485 , H01M2/1653 , H01M4/525 , H01M4/5825 , H01M10/052 , H01M2010/4292
摘要： A non-aqueous electrolyte secondary cell superior in resistance against continuous charging at high potential is provided. The non-aqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material comprising lithium cobalt oxide containing at least one selected from Mg, Al, Ti, and Zr; and a separator having pores having an average diameter of 0.05 to 0.2 μm.
摘要翻译：提供了在高电位下耐连续充电性优异的非水电解质二次电池。非水电解质二次电池包括：具有磷酸锂的正极和包含选自Mg，Al，Ti和Zr中的至少一种的含有钴酸锂的正极活性物质; 以及具有平均直径为0.05〜0.2μm的孔的隔膜。

12. 发明申请

US20100248022A1 NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
标题翻译：非电解电解质二次电池
公开(公告)号：US20100248022A1
公开(公告)日：2010-09-30
申请号：US12721928
申请日：2010-03-11
申请人： Hironori Shirakata , Yasunobu Iwami , Masato Iwanaga
发明人： Hironori Shirakata , Yasunobu Iwami , Masato Iwanaga
IPC分类号： H01M6/14
CPC分类号： H01M10/0525 , H01M4/133 , H01M4/136 , H01M4/5825 , H01M4/587 , H01M10/0567 , Y02T10/7011
摘要： The nonaqueous electrolyte secondary battery having high output characteristics and excellent safety when overcharging as well as excellent charge and discharge cycle characteristics according to an aspect of the invention includes a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, a separator, and a nonaqueous electrolyte. The positive electrode active material includes lithium iron phosphate having an olivine crystal structure represented by General Formula LixFePO4 (where x is 0
摘要翻译：根据本发明的一个方面，当过充电以及充放电循环特性优异时，具有高输出特性和优异安全性的非水电解质二次电池包括具有正极活性材料的正极，具有负极活性物质的负极，隔膜和非水电解质。正极活性物质包括具有由通式LixFePO4（其中x为0

13. 发明授权

US08338030B2 Non-aqueous electrolyte secondary battery 失效
标题翻译：非水电解质二次电池
公开(公告)号：US08338030B2
公开(公告)日：2012-12-25
申请号：US11359965
申请日：2006-02-23
申请人： Masato Iwanaga , Nobumichi Nishida , Shuji Tsutsumi
发明人： Masato Iwanaga , Nobumichi Nishida , Shuji Tsutsumi
IPC分类号： H01M4/52
CPC分类号： H01M4/131 , H01M4/133 , H01M4/366 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0567 , H01M10/44 , H01M2300/004
摘要： A non-aqueous electrolyte secondary battery with excellent discharge cycle characteristics and a charging termination potential ranging from 4.4 to 4.6 V based on lithium, consisting of a positive electrode comprising a positive electrode active material, a negative electrode, and a non-aqueous electrolyte containing a non-aqueous solvent and an electrolyte salt, in which the positive electrode active material comprises a mixture of a lithium-cobalt composite oxide containing at least both zirconium and magnesium in LiCoO2, and a lithium-manganese-nickel composite oxide having a layered structure and containing at least both manganese and nickel, and the potential of the positive electrode active material ranges from 4.4 to 4.6 V based on lithium, and the non-aqueous electrolyte contains at least one of aromatic compounds selected from the group consisting at least of toluene derivatives, anisole derivatives, biphenyl, cyclohexyl benzene, tert-butyl benzene, tert-amyl benzene, and diphenyl ether.
摘要翻译：一种非水电解质二次电池，具有优异的放电循环特性和基于锂的4.4至4.6V的充电终止电位，由包含正极活性材料，负极和非水电解质的正极组成，所述正极包含非水溶剂和电解质盐，其中正极活性物质包含LiCoO 2中至少含有锆和镁两者的锂 - 钴复合氧化物的混合物和具有层状结构的锂 - 锰 - 镍复合氧化物并且至少包含锰和镍两者，并且所述正极活性物质的电位为基于锂的4.4至4.6V，并且所述非水电解质包含至少一种选自至少一种甲苯衍生物，苯甲醚衍生物，联苯，环己基苯，叔丁基苯，叔戊基苯和二苯基醚烯丙醚。

14. 发明授权

US08119293B2 Non-aqueous electrolyte secondary cell 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08119293B2
公开(公告)日：2012-02-21
申请号：US12710659
申请日：2010-02-23
申请人： Masato Iwanaga , Noriko Yamashita
发明人： Masato Iwanaga , Noriko Yamashita
IPC分类号： H01M6/16
CPC分类号： H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M2300/0042
摘要： A non-aqueous electrolyte secondary cell can be charged at a high voltage of 4.3V or more and has excellent cycle characteristics and excellent high-temperature storage characteristics. The cell includes positive and negative electrodes capable of inserting and extracting lithium, and a non-aqueous electrolyte. The non-aqueous electrolyte contains a non-aqueous solvent, 1,3-dioxane and a dinitrile compound additives, and an electrolyte salt. The non-aqueous solvent contains ethylene carbonate in the range of 25% to 40% by volume under the conditions of 25° C. and 1 atm.
摘要翻译：非水电解质二次电池可以在4.3V以上的高电压下充电，具有优异的循环特性和优异的高温保存特性。电池包括能够插入和提取锂的正极和负极以及非水电解质。非水电解质含有非水溶剂，1,3-二恶烷和二腈化合物添加剂，以及电解质盐。非水溶剂在25℃和1atm的条件下含有25〜40体积％的碳酸亚乙酯。

15. 发明授权

US08018233B2 Evaluation method of separator for nonaqueous electrolyte battery, and nonaqueous electrolyte battery 失效
标题翻译：非水电解质电池用隔膜和非水电解质电池的评价方法
公开(公告)号：US08018233B2
公开(公告)日：2011-09-13
申请号：US12145664
申请日：2008-06-25
申请人： Masato Iwanaga , Noriko Yamashita
发明人： Masato Iwanaga , Noriko Yamashita
IPC分类号： G01N27/416
CPC分类号： H01M10/4207 , H01M6/16 , H01M6/50 , H01M10/0525 , Y10T29/53 , Y10T29/53135
摘要： The evaluation method of a separator for a nonaqueous electrolyte battery according to the present invention includes: placing opposite an upper jig 21 serving also as a conductive electrode and a lower jig 23 serving also as a conductive electrode in both sides of the separator sample 22; and measuring the relationship between an applied voltage and a passed current between the upper jig 21 and the lower jig 23 while applying a pressure to between the upper jig 21 and the lower jig 23 to evaluate the separator. At this time, by fitting a foreign material 28 in any shape between the separator sample 22 and one of the upper jig 21 and the lower jig 23, an evaluation of the separator simulating the presence of a foreign material affecting adversely the separator can be performed.
摘要翻译：根据本发明的非水电解质电池用隔膜的评价方法包括：在分离器样品22的两面中与用作导电电极的上部夹具21以及也用作导电电极的下部夹具23相对放置; 并且在上夹具21和下夹具23之间施加压力同时测量施加电压和上夹具21与下夹具23之间的通过电流之间的关系，以评估隔板。此时，通过将分离器样品22与上夹具21和下夹具23之一之间的任何形状的异物28接合，可以进行模拟对隔膜产生不利影响的异物的存在的隔膜的评价。

16. 发明申请

US20070172730A1 Nonaqueous electrolyte secondary battery, nonaqueous electrolyte, and charging method therefor 有权
标题翻译：非水电解质二次电池，非水电解质及其充电方法
公开(公告)号：US20070172730A1
公开(公告)日：2007-07-26
申请号：US11656486
申请日：2007-01-23
申请人： Masato Iwanaga , Yukihiro Oki , Koji Abe , Kazuhiro Miyoshi
发明人： Masato Iwanaga , Yukihiro Oki , Koji Abe , Kazuhiro Miyoshi
IPC分类号： H01M10/40 , H01M4/50 , H01M4/52
CPC分类号： H01M10/0567 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/0569 , H01M2300/004
摘要： A nonaqueous electrolyte secondary battery of the invention has a positive electrode having a positive electrode active material, a negative electrode, and a nonaqueous electrolyte having electrolyte salt in a nonaqueous solvent. The electric potential of the positive electrode active material is 4.4 to 4.6 V relative to lithium, and the nonaqueous electrolyte contains a compound expressed by structural formula (I) below. The quantity of compound added is preferably 0.1% to 2% by mass. Also, the positive electrode active material preferably comprises a mixture of a lithium-cobalt composite oxide which is LiCoO2 containing at least both zirconium and magnesium and a lithium-manganese-nickel composite oxide that has a layer structure and contains at least both manganese and nickel. Thanks to such structure, a nonaqueous electrolyte secondary battery can be provided that is charged to charging termination potential of 4.4 to 4.6 V relative to lithium and that has enhanced overcharging safety.[Chemical Formula 1]
摘要翻译：本发明的非水电解质二次电池具有正极，具有正极活性物质，负极和非水电解质，在非水溶剂中具有电解质盐。正极活性物质的电位相对于锂为4.4〜4.6V，非水电解质含有下述结构式（I）表示的化合物。化合物的添加量优选为0.1质量％〜2质量％。此外，正极活性物质优选含有至少含有锆和镁两者的LiCoO 2 2的锂 - 钴复合氧化物和具有层结构的锂 - 锰 - 镍复合氧化物的混合物并且至少含有锰和镍。由于这样的结构，可以提供非水电解质二次电池，其相对于锂充电至4.4至4.6V的充电终止电位，并且具有增强的过充电安全性。 [化学式1]

17. 发明申请

US20060199077A1 Non-aqueous electrolyte secondary battery 失效
标题翻译：非水电解质二次电池
公开(公告)号：US20060199077A1
公开(公告)日：2006-09-07
申请号：US11359965
申请日：2006-02-23
申请人： Masato Iwanaga , Nobumichi Nishida , Shuji Tsutsumi
发明人： Masato Iwanaga , Nobumichi Nishida , Shuji Tsutsumi
IPC分类号： H01M4/52 , H01M4/50 , H01M10/40
CPC分类号： H01M4/131 , H01M4/133 , H01M4/366 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0567 , H01M10/44 , H01M2300/004
摘要： A non-aqueous electrolyte secondary battery with excellent discharge cycle characteristics and a charging termination potential ranging from 4.4 to 4.6 V based on lithium, consisting of a positive electrode comprising a positive electrode active material, a negative electrode, and a non-aqueous electrolyte containing a non-aqueous solvent and an electrolyte salt, in which the positive electrode active material comprises a mixture of a lithium-cobalt composite oxide containing at least both zirconium and magnesium in LiCoO2, and a lithium-manganese-nickel composite oxide having a layered structure and containing at least both manganese and nickel, and the potential of the positive electrode active material ranges from 4.4 to 4.6 V based on lithium, and the non-aqueous electrolyte contains at least one of aromatic compounds selected from the group consisting at least of toluene derivatives, anisole derivatives, biphenyl, cyclohexyl benzene, tert-butyl benzene, tert-amyl benzene, and diphenyl ether.
摘要翻译：一种非水电解质二次电池，具有优异的放电循环特性和基于锂的4.4至4.6V的充电终止电位，由包含正极活性材料，负极和非水电解质的正极组成，所述正极包含非水溶剂和电解质盐，其中正极活性物质包含在LiCoO 2 2中至少含有锆和镁两者的锂 - 钴复合氧化物的混合物和锂 - 锰具有层状结构并且至少含有锰和镍的镍 - 镍复合氧化物，并且正极活性物质的电位基于锂为4.4-4.6V，非水电解质包含至少一种所选择的芳族化合物由至少甲苯衍生物，苯甲醚衍生物，联苯，环己基苯，叔丁基苯，叔戊基苯 e和二苯醚。

18. 发明申请

US20140017526A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY SYSTEM 审中-公开
标题翻译：非水电解质二次电池系统
公开(公告)号：US20140017526A1
公开(公告)日：2014-01-16
申请号：US14005954
申请日：2012-03-21
申请人： Masato Iwanaga , Atsushi Kaiduka , Shun Nomura , Kota Ogawa , Naoya Tsukamoto
发明人： Masato Iwanaga , Atsushi Kaiduka , Shun Nomura , Kota Ogawa , Naoya Tsukamoto
IPC分类号： H01M2/34 , H01M10/0569
CPC分类号： H01M2/34 , H01M4/587 , H01M10/052 , H01M10/0567 , H01M10/0569 , H01M10/44 , H01M10/48 , H01M2300/0028 , Y02T10/7011
摘要： A non-aqueous electrolyte secondary battery system includes a non-aqueous electrolyte secondary battery and a charging control system which has a function of detecting the voltage of the non-aqueous electrolyte secondary battery and disconnecting a charging circuit. The non-aqueous electrolytic solution contains a non-aqueous solvent having a viscosity of 0.6 cP or less at 25° C. in an amount of 35 to 80 vol % inclusive as a non-aqueous solvent and also contains hexamethylene diisocyanate, and the charging control system stops charging when the potential of the positive electrode of the non-aqueous electrolyte secondary battery is 4.35 to 4.6 V inclusive based on lithium. Thus the non-aqueous electrolyte secondary battery system equipped with the non-aqueous electrolyte secondary battery having high charging potential and excellent high-temperature cycling characteristics can be provided.
摘要翻译：非水电解质二次电池系统包括非水电解质二次电池和具有检测非水电解质二次电池的电压并断开充电电路的功能的充电控制系统。非水电解液含有25℃下的粘度为0.6cP以下的非水系溶剂，含量为35〜80体积％以外，作为非水系溶剂，还含有六亚甲基二异氰酸酯，当非水电解质二次电池的正极的电位为4.35〜4.6V（以锂计）时，控制系统停止充电。因此，可以提供配备有具有高充电电位和优异的高温循环特性的非水电解质二次电池的非水电解质二次电池系统。

19. 发明申请

US20120231344A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
标题翻译：非水电解质二次电池
公开(公告)号：US20120231344A1
公开(公告)日：2012-09-13
申请号：US13512431
申请日：2010-11-29
申请人： Koji Okushi , Yukihiro Oki , Masato Iwanaga
发明人： Koji Okushi , Yukihiro Oki , Masato Iwanaga
IPC分类号： H01M4/13 , H01M4/583 , H01M4/48
CPC分类号： H01M2/18 , H01M4/13 , H01M4/366 , H01M10/052 , Y02T10/7011
摘要： The present invention provides a nonaqueous electrolyte secondary battery that can be charged at high voltage and suppress capacity deterioration after charged storage in a high temperature environment.A nonaqueous electrolyte secondary battery 10 includes a positive electrode sheet 11, a negative electrode sheet 12, a nonaqueous electrolyte, and a separator 13, and the positive electrode active material has a potential of 4.35 to 4.60 V based on lithium. The positive electrode sheet 11 has a surface provided with an inorganic particle layer. The separator 13 has an average pore size of 0.15 μm or more and 0.3 μm or less. It is preferable that the inorganic particle layer provided to the surface of the positive electrode sheet 11 contain titanium oxide or aluminum oxide.
摘要翻译：本发明提供一种可在高电压下充电并抑制在高温环境下充电保存后的容量劣化的非水电解质二次电池。非水电解质二次电池10包括正极片11，负极片12，非水电解质和隔膜13，正极活性物质的电位为锂的4.35〜4.60V。正极片11具有设置无机粒子层的面。隔板13的平均孔径为0.15μm以上且0.3μm以下。设置在正极片11的表面的无机粒子层优选含有氧化钛或氧化铝。

20. 发明申请

US20110223489A1 NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
标题翻译：非电解电解质二次电池
公开(公告)号：US20110223489A1
公开(公告)日：2011-09-15
申请号：US13042552
申请日：2011-03-08
申请人： Masato Iwanaga , Noriko Yamashita , Atsushi Kaiduka , Koji Abe , Kazuhiro Miyoshi , Masahide Kondo
发明人： Masato Iwanaga , Noriko Yamashita , Atsushi Kaiduka , Koji Abe , Kazuhiro Miyoshi , Masahide Kondo
IPC分类号： H01M10/056
CPC分类号： H01M10/0567 , H01M4/525 , H01M10/052 , H01M10/4235 , H01M2300/0025 , Y02T10/7011
摘要： A positive electrode active material of a nonaqueous electrolyte secondary battery is composed of lithium-cobalt composite oxide containing at least one of zirconium, titanium, aluminum, and erbium, and the nonaqueous electrolyte includes an additive expressed by General Formula (1) having an acetylene group and a methylsulfonyl group at each end of the molecule. It has the effect of forming an SEI surface film as with the case of VC or the like, as well as having a higher oxidation resistance than that of VC or the like. Thus the nonaqueous electrolyte secondary battery employing as positive electrode active material a lithium-cobalt composite oxide with a particular dissimilar metallic element added, in which decomposition of the nonaqueous electrolytic solution during storage at high temperature in a charged state is suppressed, and there is little battery swelling is provided.
摘要翻译：非水电解质二次电池的正极活性物质由含有锆，钛，铝，铒中的至少一种的锂钴复合氧化物构成，非水电解质含有通式（1）表示的添加剂，其具有乙炔基团和分子的每个末端的甲基磺酰基。与VC等的情况相同，具有形成SEI表面膜的效果，并且具有比VC等更高的抗氧化性。因此，作为正极活性物质使用添加了特定的异种金属元素的锂 - 钴复合氧化物的非水电解质二次电池，其中抑制了在高温下在充电状态下储存期间非水电解液的分解，并且几乎没有提供电池膨胀。

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