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    • 13. 发明授权
    • Electro-chemical measuring sensor with a potential-free sensor element
and method for producing it
    • 具有无电位传感器元件的电化学测量传感器及其制造方法
    • US5670032A
    • 1997-09-23
    • US592381
    • 1996-01-25
    • Karl-Hermann FrieseHelmut WeylSiegfried NeesHans-Martin Wiedenmann
    • Karl-Hermann FrieseHelmut WeylSiegfried NeesHans-Martin Wiedenmann
    • G01N27/409G01N27/407G01N27/26
    • G01N27/407G01N27/4078
    • An electro-chemical measuring sensor (10) for determining the oxygen content of gases, in particular for determining the oxygen content in exhaust gases of internal combustion engines, with a potential-free disposed sensor element (14). The sensor element (14) has an oxygen-ion-conducting solid electrolyte body (23), preferably in the shape of a pipe or tube closed at one end, which has an exterior electrode (25) disposed on the exterior surface with a strip conductor (27) on the side toward the contact and also extending on the exterior surface, and which is inserted by means of a sealing ring (20) in a metal housing (11). The sensor element (14) has an electrically insulating layer (21) at least in the area of the sealing ring (20), which covers at least the strip conductor (27) in the direction toward the housing (11). The insulating layer (21) is formed from a mixture of a crystalline, non-metallic material and a glass-forming material. In the course of production the insulating layer (21) is subjected to a thermal treatment above the melting temperature of the glass-forming material, in the course of which the insulating layer (21) forms a glaze filled with the crystalline, non-metallic material.
    • PCT No.PCT / DE94 / 00791 Sec。 371日期:1996年1月25日 102(e)日期1996年1月25日PCT 1994年7月9日PCT公布。 公开号WO95 / 04273 日期1995年2月9日,一种用于确定气体氧含量的电化学测量传感器(10),特别是用于确定内燃机排气中氧含量的电化学测量传感器(10)。 传感器元件(14)具有氧离子传导固体电解质体(23),优选地为在一端封闭的管或管的形状,其具有设置在外表面上的外部电极(25) 导体(27),并且还在外表面上延伸,并且通过密封环(20)插入到金属外壳(11)中。 传感器元件(14)至少在密封环(20)的区域中具有电绝缘层(21),其至少在朝向壳体(11)的方向上覆盖带状导体(27)。 绝缘层(21)由结晶,非金属材料和玻璃形成材料的混合物形成。 在制造过程中,将绝缘层(21)进行高于玻璃形成材料的熔化温度的热处理,其中绝缘层(21)形成填充有结晶非金属的釉料 材料。
    • 16. 发明授权
    • Exhaust gas sensor and method of producing the same
    • 废气传感器及其制造方法
    • US5423973A
    • 1995-06-13
    • US211083
    • 1994-06-20
    • Karl-Hermann FrieseHans-Martin WiedenmannHelmut Weyl
    • Karl-Hermann FrieseHans-Martin WiedenmannHelmut Weyl
    • G01N27/12G01N27/407G01N27/409G01N27/41G01N27/26
    • G01N27/4075
    • An exhaust gas sensor which is exposed to exhaust gas, includes a measuring electrode; and a porous ceramic coating provided on the measuring electrode and comprised of at least two layers, a first porous ceramic layer which is provided on the measuring electrode and at least a second porous ceramic layer which is provided on the first porous ceramic layer and which is directly exposed to the exhaust gas, wherein the first porous ceramic layer contains getter substances for removal of substances that are harmful to the measuring electrode, and wherein the second porous ceramic layer is provided with one of a diffusion resistance or a catalytic effect relative to exhaust gas constituents such that, at the boundary of the first and second porous ceramic layers, a gas composition is present in use which is comprised of one of oxidizable or reducible gas constituents and which sets a control position for the exhaust gas sensor.
    • PCT No.PCT / DE92 / 00714 Sec。 371日期:1994年6月20日 102(e)日期1994年6月20日PCT提交1992年8月27日PCT公布。 公开号WO93 / 06472 日本1997年4月1日。一种暴露于废气的排气传感器,包括测量电极; 以及设置在所述测量电极上并且包括至少两层的多孔陶瓷涂层,设置在所述测量电极上的第一多孔陶瓷层和设置在所述第一多孔陶瓷层上的至少第二多孔陶瓷层, 直接暴露于废气中,其中第一多孔陶瓷层含有用于除去对测量电极有害的物质的吸气剂物质,并且其中第二多孔陶瓷层具有相对于排气的扩散阻力或催化作用之一 气体成分,使得在第一和第二多孔陶瓷层的边界处,存在使用中的气体组合物,其由可氧化或可还原的气体成分之一组成,并且设置用于排气传感器的控制位置。