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    • 17. 发明授权
    • Oil-in-water capsule manufacture process and microcapsules produced by such process
    • 油包水胶囊制造工艺和通过这种方法生产的微胶囊
    • US07736695B2
    • 2010-06-15
    • US11436317
    • 2006-05-18
    • Todd Arlin SchwantesPeggy Dorothy Sands
    • Todd Arlin SchwantesPeggy Dorothy Sands
    • B01J13/02
    • B01J13/16Y10T428/2984Y10T428/2985
    • A novel method of forming oil in water process is disclosed. According to the invention process are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsification of the oil phase into the water phase (O/W) is controlled through the quantity of water employed. The emulsion is then UV exposed or heated for a time (and temperature) sufficient to decompose the free radical initiators in the oil and/or water phases; thereby forming microcapsule wall material at the interface of the water and oil phases.
    • 公开了一种在水中形成油的新方法。 根据本发明方法,通过以下步骤获得方法:包括将油溶性胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体与热或UV自由基引发剂(任选地包括在一种或两种油或水中) 相)和有机酸转化为内相油; 加热或UV曝光足以使胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体低聚的时间(和温度),形成预聚物。 此后,该方法包括向油相油中加入包含阴离子乳化剂(和任选的引发剂)的水分散体的水相,并加入乳化剂。 通过所用的水量控制油相进入水相(O / W)的乳化。 然后将乳液UV暴露或加热足以分解油和/或水相中的自由基引发剂的时间(和温度); 从而在水相和油相的界面处形成微胶囊壁材料。
    • 18. 发明授权
    • Water-in-oil capsule manufacture process and microcapsules produced by such process
    • 油包水胶囊制造工艺和通过这种方法生产的微胶囊
    • US07985445B2
    • 2011-07-26
    • US12855733
    • 2010-08-13
    • Todd Arlin SchwantesPeggy Dorothy Sands
    • Todd Arlin SchwantesPeggy Dorothy Sands
    • B01J13/02
    • B01J13/16Y10T428/1405Y10T428/2984Y10T428/2985Y10T428/2987
    • A novel method of forming water in oil microcapsules is disclosed. According to the invention microcapsules are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsifying the water phase into the oil phase (W/O) is controlled through the quantity of water employed. The emulsion is then UV exposed or heated for a time (and temperature) sufficient to decompose the free radical initiators in the oil and/or water phases; thereby forming microcapsule wall material at the interface of the water and oil phases.
    • 公开了一种在油微胶囊中形成水的新方法。 根据本发明,微胶囊通过以下步骤获得:包括将油溶性胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体与热或UV自由基引发剂(任选地包括在一种或两种油或水中) 相)和有机酸转化为内相油; 加热或UV曝光足以使胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体低聚的时间(和温度),形成预聚物。 此后,该方法包括向油相油中加入包含阴离子乳化剂(和任选的引发剂)的水分散体的水相,并加入乳化剂。 将水相乳化到油相(W / O)中通过所用的水量来控制。 然后将乳液UV暴露或加热足以分解油和/或水相中的自由基引发剂的时间(和温度); 从而在水相和油相的界面处形成微胶囊壁材料。
    • 19. 发明申请
    • WATER-IN-OIL CAPSULE MANUFACTURE PROCESS AND MICROCAPSULES PRODUCED BY SUCH PROCESS
    • 油封制造工艺和通过这种工艺生产的微生物
    • US20100304023A1
    • 2010-12-02
    • US12855733
    • 2010-08-13
    • Todd Arlin SchwantesPeggy Dorothy Sands
    • Todd Arlin SchwantesPeggy Dorothy Sands
    • B01J13/20
    • B01J13/16Y10T428/1405Y10T428/2984Y10T428/2985Y10T428/2987
    • A novel method of forming water in oil microcapsules is disclosed. According to the invention microcapsules are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsifying the water phase into the oil phase (W/O) is controlled through the quantity of water employed. The emulsion is then UV exposed or heated for a time (and temperature) sufficient to decompose the free radical initiators in the oil and/or water phases; thereby forming microcapsule wall material at the interface of the water and oil phases.
    • 公开了一种在油微胶囊中形成水的新方法。 根据本发明,微胶囊通过以下步骤获得:包括将油溶性胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体与热或UV自由基引发剂(任选地包括在一种或两种油或水中) 相)和有机酸转化为内相油; 加热或UV曝光足以使胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体低聚的时间(和温度),形成预聚物。 此后,该方法包括向油相油中加入包含阴离子乳化剂(和任选的引发剂)的水分散体的水相,并加入乳化剂。 将水相乳化到油相(W / O)中通过所用的水量来控制。 然后将乳液UV暴露或加热足以分解油和/或水相中的自由基引发剂的时间(和温度); 从而在水相和油相的界面处形成微胶囊壁材料。
    • 20. 发明授权
    • Water-in-oil capsule manufacture process and microcapsules produced by such process
    • 油包水胶囊制造工艺和通过这种方法生产的微胶囊
    • US07803422B2
    • 2010-09-28
    • US11436496
    • 2006-05-18
    • Todd Arlin SchwantesPeggy Dorothy Sands
    • Todd Arlin SchwantesPeggy Dorothy Sands
    • B01J13/02
    • B01J13/16Y10T428/2984Y10T428/2985
    • A novel method of forming water in oil microcapsules is disclosed. According to the invention microcapsules are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsifying the water phase into the oil phase (W/O) is controlled through the quantity of water employed. The emulsion is then UV exposed or heated for a time (and temperature) sufficient to decompose the free radical initiators in the oil and/or water phases; thereby forming microcapsule wall material at the interface of the water and oil phases.
    • 公开了一种在油微胶囊中形成水的新方法。 根据本发明,微胶囊通过以下步骤获得:包括将油溶性胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体与热或UV自由基引发剂(任选地包括在一种或两种油或水中) 相)和有机酸转化为内相油; 加热或UV曝光足以使胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体低聚的时间(和温度),形成预聚物。 此后,该方法包括向油相油中加入包含阴离子乳化剂(和任选的引发剂)的水分散体的水相,并加入乳化剂。 将水相乳化到油相(W / O)中通过所用的水量来控制。 然后将乳液UV暴露或加热足以分解油和/或水相中的自由基引发剂的时间(和温度); 从而在水相和油相的界面处形成微胶囊壁材料。