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11. 发明授权

US4859798A Oxidation of alkanes 失效
标题翻译：烷烃氧化
公开(公告)号：US4859798A
公开(公告)日：1989-08-22
申请号：US211008
申请日：1988-06-24
申请人： James E. Lyons , Paul E. Ellis, Jr. , Harry K. Myers, Jr. , George Suld , Wayne A. Langdale
发明人： James E. Lyons , Paul E. Ellis, Jr. , Harry K. Myers, Jr. , George Suld , Wayne A. Langdale
IPC分类号： B01J27/188 , B01J27/199 , C07C29/50 , C07C45/33
CPC分类号： B01J23/002 , B01J27/188 , B01J27/199 , C07C29/50 , C07C45/33 , B01J2523/00
摘要： Alkanes are oxidized in the liquid phase at relatively low temperatures using heteropolyacids or polyoxoanions promoted with azide or certain metals. Such azide catalysts are also part of the invention.
摘要翻译：在相对低的温度下，使用杂多酸或用叠氮化物或某些金属促进的聚氧阴离子，在液相中使烷烃氧化。这种叠氮化物催化剂也是本发明的一部分。

12. 发明授权

US4524142A Platinum (O) complex-based hydroformylation catalyst 失效
标题翻译：基于铂（O）络合物的加氢甲酰化催化剂
公开(公告)号：US4524142A
公开(公告)日：1985-06-18
申请号：US598931
申请日：1984-04-11
申请人： Chao-Yang Hsu , James E. Lyons , Paul E. Ellis, Jr.
发明人： Chao-Yang Hsu , James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： B01J31/18 , B01J31/24 , B01J31/26 , B01J31/30 , C07C45/50 , B01J31/12 , B01J31/22
CPC分类号： B01J31/26 , B01J31/24 , B01J31/2409 , C07C45/50 , B01J2231/321 , B01J2531/828 , B01J31/1895
摘要： Olefins are hydroformylated with syngas in the presence of a novel organometallic complex catalyst to form the corresponding aldehydes at high reaction rates and improved selectively of linear aldehydes over branched aldehydes.The novel catalyst comprises an organometallic complex formed from a mixture of(1) a platinum (O) complex containing two bidentate diphosphine, diarsine or distibine ligands; and(2) A Group IVB metal halide.
摘要翻译：在新型有机金属配合物催化剂的存在下，烯烃与合成气加氢甲酰化，以高反应速率形成相应的醛，并且在分支醛上选择性地改进线性醛。新型催化剂包含由（1）含有二齿二膦的铂（O）络合物，胂或二胺配体的混合物形成的有机金属络合物; 和（2）ⅣB族金属卤化物。

13. 发明授权

US5990363A Method for oxidizing alkanes using novel porphyrins synthesized from dipyrromethanes and aldehydes 失效
标题翻译：使用由二吡咯烷和醛合成的新卟啉氧化烷烃的方法
公开(公告)号：US5990363A
公开(公告)日：1999-11-23
申请号：US175057
申请日：1993-12-29
申请人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr.
发明人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： B01J27/24 , B01J31/18 , B01J31/22 , C07B61/00 , C07C27/00 , C07C29/132 , C07C29/50 , C07C31/02 , C07C31/10 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/265 , C07C409/16 , C07D487/22 , C07F15/02
CPC分类号： C07F15/025 , B01J27/24 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/252 , C07C51/265 , C07D487/22 , B01J2531/025 , B01J2531/72 , B01J2531/821 , B01J2531/842 , B01J2531/845
摘要： The invention comprises a method for the oxidation of alkanes to alcohols and for decomposition of hydroperoxides to alcohols utilizing new compositions of matter, which are metal complexes of porphyrins. Preferred complexes have hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. Other preferred complexes are ones in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also disclosed.
摘要翻译：本发明包括使用作为卟啉的金属络合物的物质的新组合物将烷烃氧化成醇并将氢过氧化物分解成醇的方法。优选的络合物在中间位置具有氢，卤代烷基或卤代芳基，两个相对的内消旋原子或基团是氢或卤代芳基，两个相对的内消旋原子或基团是氢或卤代烷基，但不是全部四个中子原子或基团是氢。其它优选的络合物是其中全部四个中间位置被卤代烷基取代并且β位被卤素原子取代的络合物。还公开了一种合成卟啉原体的新方法。

14. 发明授权

US5705685A Conversion of alkanes to unsaturated carboxylic acids 失效
标题翻译：烷烃转化为不饱和羧酸
公开(公告)号：US5705685A
公开(公告)日：1998-01-06
申请号：US565206
申请日：1995-10-31
申请人： James E. Lyons , Paul E. Ellis, Jr. , Swati Karmakar , Shahid N. Shaikh
发明人： James E. Lyons , Paul E. Ellis, Jr. , Swati Karmakar , Shahid N. Shaikh
IPC分类号： B01J27/186 , B01J23/24 , B01J27/188 , C07B61/00 , C07C51/215 , C07C51/225 , C07C57/05 , C07C51/16
CPC分类号： B01J27/188 , B01J23/24 , C07C51/215
摘要： Alkanes are converted to unsaturated carboxylic acids by contacting an alkane with an oxidizing agent and a heteropolyacid or polyoxoanion comprising (1) at least 9 atoms of a first framework metal or metals comprising molybdenum, tungsten or vanadium or combinations thereof and (2) 1 to 3 atoms of a second framework metal or metals comprising zinc or a transition metal different from the first framework metal.
摘要翻译：烷烃通过使烷烃与氧化剂和杂多酸或多氧阴离子接触而转化为不饱和羧酸，所述烷烃包含（1）至少9个原子的第一骨架金属或包含钼，钨或钒的金属或其组合，和（2）1至 3原子的第二骨架金属或包含不同于第一骨架金属的锌或过渡金属的金属。

15. 发明授权

US5663328A Haloporphyrins and their preparation and use as catalysts 失效
标题翻译：卤卟啉及其制备和用作催化剂
公开(公告)号：US5663328A
公开(公告)日：1997-09-02
申请号：US672202
申请日：1996-06-27
申请人： Paul E. Ellis, Jr. , James E. Lyons
发明人： Paul E. Ellis, Jr. , James E. Lyons
IPC分类号： B01J31/18 , C07D487/22 , C07C29/50 , C07C31/12
CPC分类号： B01J31/1815 , B01J2231/70 , B01J2531/025 , B01J2531/16 , B01J2531/26
摘要： The invention provides novel catalyst compositions, useful in the oxidation of hydrocarbons with air or oxygen to form hydroxy-group containing compounds and in the decomposition of hydroperoxides to form hydroxy-group containing compounds. The catalysts comprise transition metal complexes of a porphyrin ring having 1 to 12 halogen substituents on the porphyrin ring, at least one of said halogens being in a meso position and/or the catalyst containing no aryl group in a meso position. The compositions are prepared by halogenating a transition metal complex of a porphyrin. In one embodiment, a complex of a porphyrin with a metal whose porphyrin complexes are not active for oxidation of hydrocarbons is halogenated, thereby to obtain a haloporphyrin complex of that metal, the metal is removed from the haloporphyrin complex to obtain the free base form of the haloporphyrin, and a metal such as iron whose porphyrin complexes are active for oxidation of hydrocarbons and for the decomposition of alkyl hydroperoxides is complexed with the free base to obtain an active catalyst for oxidation of hydrocarbons and decomposition of alkyl hydroperoxides.
摘要翻译：本发明提供了新的催化剂组合物，其可用于用空气或氧气氧化烃以形成含羟基化合物，并在氢过氧化物的分解中形成含羟基化合物。催化剂包括在卟啉环上具有1至12个卤素取代基的卟啉环的过渡金属络合物，所述卤素中的至少一个在中间位置和/或在中间位置不含芳基的催化剂。通过卤化卟啉的过渡金属络合物制备组合物。在一个实施方案中，卟啉与卟啉络合物对于烃的氧化不起作用的金属的络合物被卤化，从而获得该金属的卤卟啉络合物，从卤卟啉络合物中除去金属，得到游离碱形式卤卟啉和卟啉配合物对烃的氧化和烷基氢过氧化物的分解具有活性的金属如铁，与游离碱络合，得到烃的氧化和烷基氢过氧化物的分解的活性催化剂。

16. 发明授权

US5212300A Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation 失效
标题翻译：作为烷基氧化催化剂的氰基和聚碳酸亚戊基
公开(公告)号：US5212300A
公开(公告)日：1993-05-18
申请号：US892107
申请日：1992-06-02
申请人： Paul E. Ellis, Jr. , James E. Lyons
发明人： Paul E. Ellis, Jr. , James E. Lyons
IPC分类号： B01J31/22 , B01J31/18 , C07C27/12 , C07C29/50 , C07C45/33 , C07C45/34
CPC分类号： C07C45/34 , B01J31/1815 , C07C29/50 , C07C45/33 , B01J2531/025 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/842 , B01J2531/845
摘要： New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.

17. 发明授权

US4542242A Platinum (O) complex-based hydroformylation catalyst 失效
公开(公告)号：US4542242A
公开(公告)日：1985-09-17
申请号：US696384
申请日：1985-01-30
申请人： Chao-Yang Hsu , James E. Lyons , Paul E. Ellis, Jr.
发明人： Chao-Yang Hsu , James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： B01J31/18 , B01J31/24 , B01J31/30 , C07C45/50
CPC分类号： B01J31/2409 , B01J31/24 , B01J31/30 , C07C45/50 , B01J2231/321 , B01J2531/828 , B01J31/1895
摘要： Olefins are hydroformylated with syngas in the presence of a novel organometallic complex catalyst to form the corresponding aldehydes at high reaction rates and improved selectively of linear aldehydes over branched aldehydes.The novel catalyst comprises an organometallic complex formed from a mixture of(1) a platinum (O) complex containing two bidentate diphosphine, diarsine or distibine ligands; and(2) A Group IVB metal halide.

18. 发明授权

US5760217A Porphyrins and their synthesis from dipyrromethanes and aldehydes 失效
标题翻译：卟啉及其由二吡咯烷和醛的合成
公开(公告)号：US5760217A
公开(公告)日：1998-06-02
申请号：US672524
申请日：1996-06-25
申请人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr.
发明人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： B01J27/24 , B01J31/18 , B01J31/22 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/265 , C07C409/16 , C07D487/22 , C07F9/572 , C07F15/02
CPC分类号： C07F15/025 , B01J27/24 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C407/00 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/252 , C07C51/265 , C07D487/22 , B01J2531/025 , B01J2531/72 , B01J2531/821 , B01J2531/842 , B01J2531/845
摘要： The invention comprises new compositions of matter, which are iron, manganese, cobalt or ruthenium complexes of porphyrins having hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. The invention also comprises new compositions of matter in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also provided.
摘要翻译：本发明包括物质的新组合物，其是在中间位置具有氢，卤代烷基或卤代芳基的卟啉的铁，锰，钴或钌络合物，两个相对的内消旋原子或基团是氢或卤代芳基，以及两个相对的内消旋原子或基团是氢或卤代烷基，但不是全部四个内消旋原子或基团都是氢。本发明还包括其中全部四个中间位置被卤代烷基取代并且β位被卤素原子取代的物质的新组合物。还提供了一种合成卟啉原体的新方法。

19. 发明授权

US5571908A Porphyrins 失效
标题翻译：卟啉
公开(公告)号：US5571908A
公开(公告)日：1996-11-05
申请号：US174732
申请日：1993-12-29
申请人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr.
发明人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： B01J27/24 , B01J31/18 , B01J31/22 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/265 , C07C409/16 , C07D487/22 , C07F9/572 , C07F15/02
CPC分类号： C07F15/025 , B01J27/24 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C407/00 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/252 , C07C51/265 , C07D487/22 , B01J2531/025 , B01J2531/72 , B01J2531/821 , B01J2531/842 , B01J2531/845
摘要： The invention comprises new compositions of matter, which are iron, manganese, cobalt or ruthenium complexes of porphyrins having hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. The invention also comprises new compositions of matter in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also provided.The novel compositions and others made according to the process of the invention are useful as hydrocarbon conversion catalysts; for example, for the oxidation of alkanes and the decomposition of hydroperoxides.
摘要翻译：本发明包括物质的新组合物，其是在中间位置具有氢，卤代烷基或卤代芳基的卟啉的铁，锰，钴或钌络合物，两个相对的内消旋原子或基团是氢或卤代芳基，以及两个相对的内消旋原子或基团是氢或卤代烷基，但不是全部四个内消旋原子或基团都是氢。本发明还包括其中全部四个中间位置被卤代烷基取代并且β位被卤素原子取代的物质的新组合物。还提供了一种合成卟啉原体的新方法。根据本发明方法制备的新型组合物和其它物质可用作烃转化催化剂; 例如，用于烷烃的氧化和氢过氧化物的分解。

20. 发明授权

US5489716A Reactions catalyzed by haloporphyrins 失效
标题翻译：由卟啉催化的反应
公开(公告)号：US5489716A
公开(公告)日：1996-02-06
申请号：US303105
申请日：1994-09-07
申请人： Paul E. Ellis, Jr. , James E. Lyons
发明人： Paul E. Ellis, Jr. , James E. Lyons
IPC分类号： B01J31/22 , B01J27/24 , B01J31/18 , C07B61/00 , C07C27/00 , C07C27/12 , C07C29/132 , C07C29/50 , C07C31/12 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/265 , C07C409/16 , C07D487/22 , C07F15/02
CPC分类号： C07D487/22 , B01J27/24 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/252 , C07C51/265 , C07F15/025 , B01J2231/482 , B01J2531/025 , B01J2531/842
摘要： The invention provides novel methods for the oxidation of hydrocarbons with oxygen-containing gas to form hydroxy-group containing compounds and for the decomposition of hydroperoxides to form hydroxygroup containing compounds. The catalysts used in the methods of the invention comprise transition metal complexes of a porphyrin ring having 1 to 12 halogen substituents on the porphyrin ring, at least one of said halogens being in a meso position and/or the catalyst containing no aryl group in a meso position. The catalyst compositions are prepared by halogenating a transition metal complex of a porphyrin. In one embodiment, a complex of a porphyrin with a metal whose porphyrin complexes are not active for oxidation of alkanes is halogenated, thereby to obtain a haloporphyrin complex of that metal, the metal is removed from the haloporphyrin complex to obtain the free base form of the haloporphyrin, and a metal such as iron whose porphyrin complexes are active for oxidation of alkanes and for the decomposition of alkyl hydroperoxides is complexed with the free base to obtain an active catalyst for oxidation of alkanes and decomposition of alkyl hydroperoxides.
摘要翻译：本发明提供了用含氧气体氧化烃类以形成含羟基化合物和氢过氧化物分解形成含羟基化合物的新方法。用于本发明方法的催化剂包括在卟啉环上具有1至12个卤素取代基的卟啉环的过渡金属络合物，所述卤素中的至少一个位于中间位置和/或不含芳基的催化剂中观位置。通过卤化卟啉的过渡金属络合物制备催化剂组合物。在一个实施方案中，卟啉与卟啉络合物对于烷烃氧化不起作用的金属的络合物被卤化，从而获得该金属的卤卟啉络合物，从卤卟啉络合物中除去金属，得到游离碱形式卤卟啉和卟啉配合物对烷烃氧化和烷基氢过氧化物的分解具有活性的金属如铁，与游离碱络合，得到烷烃氧化和烷基氢过氧化物分解的活性催化剂。

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