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    • 13. 发明授权
    • Photographic products employing novel nondiffusible metal complexes of
azo dyes
    • 使用偶氮染料的新型非扩散金属络合物的摄影产品
    • US4598030A
    • 1986-07-01
    • US761932
    • 1985-08-02
    • James A. Reczek
    • James A. Reczek
    • C09B45/14G03C8/10G03C1/40C09B45/00
    • G03C8/10C09B45/14
    • Photographic elements, diffusion transfer assemblages and coordination complexes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible dye moiety having the formula: ##STR1## wherein: (a) D.sup.1, D.sup.2 and D.sup.3 each independently represents the atoms necessary to complete an aromatic heterocyclic nucleus having at least one ring of 5 to 7 atoms;(b) Z.sup.1 and Z.sup.2 each independently represents the atoms necessary to complete an aromatic carbocyclic or heterocyclic nucleus having at least one ring of 5 to 7 atoms or a ketomethine group;(c) G.sup.1 and G.sup.2 each independently represents a metal chelating group;(d) Me is a polyvalent, hexacoordinate metal ion,(e) CAR represents a ballasted carrier moiety capable of releasing the diffusible dye moiety as a function of development of the silver halide emulsion layer under alkaline conditions; and(f) n is 1, 2 or 3.
    • 描述了摄影元件,扩散转移组合物和配位络合物,其使用能够释放具有下式的至少一个可扩散染料部分的新型不扩散化合物:其中:(a)D1,D2和D3各自独立地表示 完成具有至少一个5至7个原子的环的芳族杂环核; (b)Z1和Z2各自独立地表示完成具有至少一个5至7个环的酮或酮基苯基的芳族碳环或杂环核所必需的原子; (c)G1和G2各自独立地表示金属螯合基团; (d)Me是多价六价金属离子,(e)CAR表示在碱性条件下能够释放可扩散染料部分作为卤化银乳剂层的功能的压载载体部分; 和(f)n为1,2或3。
    • 14. 发明授权
    • Photographic elements and processes utilizing imagewise reduction of
ferric ions
    • 利用成像还原铁离子的照相元件和工艺
    • US4568633A
    • 1986-02-04
    • US688477
    • 1985-01-02
    • Frank V. LovecchioJames A. ReczekRobert C. Stewart
    • Frank V. LovecchioJames A. ReczekRobert C. Stewart
    • G03C5/00G03C1/64G03C5/40G03C7/26G03C1/40
    • G03C7/26G03C5/40
    • A process for obtaining highly stable color photographic images utilizes a silver halide photographic element comprising an essentially colorless, immobile compound which is capable of complexing with ferrous ions to form a dye. The complexing compound contains a complexing moiety which is represented by the formula: ##STR1## wherein m is zero or a positive integer 1 to 3, n and p are independently 0 or 1 and represents a single or double bond. Z is R.sup.1 --N.dbd., O.dbd., S.dbd., R.sup.1 --P.dbd., (R.sup.1).sub.2 P-- or (R.sup.1).sub.3 P.dbd., and when Z is (R.sup.1).sub.2 P--, n is 1, otherwise n is 0. R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently hydrogen, amino, hydroxy, mercapto, alkoxy, alkyl, aryl or a heterocyclic moiety. When R.sup.6 is so defined, p is 1 and is a single bond. If m is 0, R.sup.1 and R.sup.2, R.sup.2 and R.sup.3, and R.sup.3 and R.sup.4 taken together can independently represent the carbon and heteroatoms necessary to complete a substituted or unsubstituted carbocyclic or heterocyclic nucleus, or if m is 1 to 3, R.sup.1 and R.sup.2, R.sup.5 and R.sup.6, and R.sup.3 and R.sup.4 can independently represent the carbon and heteroatoms necessary to complete a substituted or unsubstituted heterocyclic nucleus. When R.sup.5 and R.sup.6 are so defined, p is 0 when is a double bond, and p is 1 when is a single bond.
    • 用于获得高度稳定的彩色照相图像的方法使用包含基本上无色的固定化合物的卤化银照相元件,其能够与亚铁离子络合以形成染料。 络合化合物包含由下式表示的络合部分:其中m为0或正整数1至3,n和p独立地为0或1,并且表示单键或双键。 Z为R1-N =,O =,S =,R1-P =,(R1)2P-或(R1)3P =,当Z为(R1)2P-时,n为1,否则n为0. R1 ,R2,R3,R4,R5和R6独立地是氢,氨基,羟基,巯基,烷氧基,烷基,芳基或杂环部分。 当R6如此定义时,p是1并且是单键。 如果m为0,则R 1和R 2,R 2和R 3以及R 3和R 4一起可以独立地表示完成取代或未取代的碳环或杂环核所需的碳和杂原子,或者如果m为1至3,则R1和R2, R 5和R 6,并且R 3和R 4可以独立地表示完成取代或未取代的杂环核所必需的碳和杂原子。 当R5和R6如此定义时,当双键时p为0,当单键为p时,p为1。
    • 15. 发明授权
    • Photographic products and processes employing novel nondiffusible cyan
dye-releasing compounds and precursors thereof
    • 使用新型不溶性青色染料释放化合物及其前体的摄影产品和方法
    • US4476207A
    • 1984-10-09
    • US578720
    • 1984-02-09
    • James A. ReczekJames K. Elwood
    • James A. ReczekJames K. Elwood
    • C09B27/00G03C8/10G03C1/40C09B45/00G03C1/84G03C7/40
    • C09B27/00G03C8/10
    • Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible cyan dye moiety comprising a 6-heterocyclylazo-3-pyridinol, the compound having the formula: ##STR1## wherein: (a) Y represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible cyan dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(c) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(d) n is 0, 1 or 2 with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.
    • 描述了摄影元件,扩散转移组合物,配位络合物和方法,其使用能够释放包含6-杂环基偶氮-3-吡啶酚的至少一种可扩散的青色染料部分的新型非扩散性化合物,该化合物具有下式:其中: (a)Y表示完成5-或6-元芳族杂环稠环所必需的原子; (b)CAR表示在碱性条件下能够释放可扩散青色染料部分作为卤化银乳剂层的功能的压载载体部分; (c)R表示羟基,其盐或其可水解的前体,或通过其上的氧原子与染料部分连接的CAR; 和(d)n为0,1或2,条件是当n为0时,R为通过其上的氧原子与染料部分连接的CAR。
    • 18. 发明申请
    • METHOD OF PRINTING WITH ANTI-CURL SOLUTION
    • 用反式溶液印刷的方法
    • US20120127226A1
    • 2012-05-24
    • US12949960
    • 2010-11-19
    • Huijuan D. ChenJames A. ReczekRichard P. SzajewskiDouglas W. CouwenhovenRichard C. ReemRichard A. Dibiase
    • Huijuan D. ChenJames A. ReczekRichard P. SzajewskiDouglas W. CouwenhovenRichard C. ReemRichard A. Dibiase
    • B41J29/38
    • B41J11/0015B41J2/2114B41J2/2132
    • A method of printing with an inkjet printer, the method includes a) providing a printhead including at least first drop ejector array and a second drop ejector array; b) providing a carriage for moving the printhead along a printing region of the inkjet printer; c) providing an ink supply that is fluidically connected to the first drop ejector array; d) providing an anti-curl solution supply that is fluidically connected to the second drop ejector array; e) providing a controller for controlling the printing operations of the printer; f) advancing a portion of recording medium into the printing region; g) moving the carriage along a first carriage scan direction while the second drop ejector array ejects drops of anti-curl solution onto the portion of recording medium that is in the printing region; h) providing a delay time that is greater than 15 milliseconds after the second drop ejector ejects drops of anti-curl solution at a given location on the portion of recording medium; i) moving the carriage along a second carriage scan direction while the first drop ejector array ejects drops of ink in an image-wise fashion onto the given location of the portion of recording medium according to control by the controller to form a swath of image; and j) repeating steps f) through i) to form an image swath by swath on the recording medium.
    • 一种使用喷墨打印机进行打印的方法,所述方法包括:a)提供包括至少第一液滴喷射器阵列和第二液滴喷射器阵列的打印头; b)提供用于沿着喷墨打印机的打印区域移动打印头的滑架; c)提供流体连接到第一滴液喷射器阵列的墨水供应; d)提供流体连接到第二液滴喷射器阵列的抗卷曲溶液供应; e)提供用于控制打印机的打印操作的控制器; f)将一部分记录介质推入打印区域; g)沿着第一滑架扫描方向移动托架,同时第二液滴喷射器阵列将抗卷曲溶液滴喷射到在打印区域中的记录介质的部分上; h)提供在第二滴液喷射器在记录介质部分上的给定位置喷射抗卷曲溶液滴之后大于15毫秒的延迟时间; i)沿着第二滑架扫描方向移动滑架,同时第一液滴喷射器阵列根据控制器的控制将成像方式的墨水滴喷射到记录介质部分的给定位置上以形成一幅图像; 和j)重复步骤f)至i)以在记录介质上通过条纹形成图像条。