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    • 11. 发明申请
    • Compounds which can be activated by actinic radiation and contain urethane groups, method for the production thereof and use of the same
    • 可通过光化辐射活化并含有氨基甲酸酯基团的化合物,其制备方法和用途
    • US20060205837A1
    • 2006-09-14
    • US10533112
    • 2003-10-27
    • Uwe MeisenburgHeinz-Peter RinkDaniel CouturierIsabelle Couturier-Verlhac
    • Uwe MeisenburgHeinz-Peter RinkDaniel CouturierIsabelle Couturier-Verlhac
    • C03C25/10
    • C09D175/16C08G18/8116C08G71/04
    • Compounds which can be activated by actinic radiation, contain at least one urethane group, and have the general formula I: X[N(R)—C(O)—O—C(R1R2)—C(R3R4)—Y-Z]n  (I), in which the index and the variables have the following meanings: n is an integer from 1 to 5; X is an at least n-valent, substituted or unsubstituted organic radical; R is a hydrogen atom or a monovalent substituted or unsubstituted organic radical; R1-R4 independently of one another are a hydrogen atom, halogen atom or monovalent, substituted or unsubstituted organic radical, it being possible for at least two radicals to be cyclically linked to one another; Y is a divalent, linking functional group containing at least one oxygen atom; and Z is an organic radical containing at least one group which can be activated by actinic radiation; with the proviso that at least for n=1 the radical R and/or the radical X are/is substituted by at least one substituent of the general formula II: Z—Y—  (II), in which the variables Z and Y are as defined above; processes for preparing them, and their use.
    • 可以通过光化辐射活化的化合物含有至少一个氨基甲酸酯基团,并且具有通式I:<?in-line-formula description =“In-line Formulas”end =“lead”?> X [N(R )-C(O)-OC(R 1,R 2) - C(R 3 R 4) -YZ] (I),<?in-line-formula description =“In-line Formulas”end =“tail”?>其中索引和变量具有以下含义:n 是从1到5的整数; X是至少n价的取代或未取代的有机基团; R是氢原子或一价取代或未取代的有机基团; R 1〜R 4彼此独立地是氢原子,卤素原子或一价的,取代或未取代的有机基团,至少两个基团可以是周期性的 相互联系 Y是含有至少一个氧原子的二价连接官能团; Z是含有至少一个可被光化辐射活化的基团的有机基团; 条件是至少对于n = 1,基团R和/或基团X被至少一个通式II的取代基取代:<?in-line-formula description =“In-line Formulas”end =“lead”?> ZY-(II),<?in-line-formula description =“In-line Formulas”end =“tail”?>其中变量Z和Y如上所定义; 制备它们的过程及其用途。
    • 16. 发明授权
    • Curable aqueous polyurethane dispersions
    • 可固化水性聚氨酯分散体
    • US07169841B2
    • 2007-01-30
    • US10311307
    • 2001-06-26
    • Reinhold SchwalmBernd BruchmannFrank VoellingerErich BeckWolfgang SchrofUwe Meisenburg
    • Reinhold SchwalmBernd BruchmannFrank VoellingerErich BeckWolfgang SchrofUwe Meisenburg
    • C08J3/00C08K3/20C08L75/00C08F8/30C08F283/04
    • C09D175/16C08G18/7837C08G18/8175Y10T428/31551C08G18/0823
    • A curable aqueous polyurethane dispersion substantially comprises a) at least one compound having two free isocyanate groups, at least one allophanate group and at least one C═C double bond capable of free radical polymerization, a carbonyl group or an oxygen atom in the form of an ether function being bonded directly to the double bond, b) at least one compound having at least one group reactive toward isocyanate groups and having a C═C double bond capable of free-radical polymerization, c) if required, at least one compound having at least two groups reactive towards isocyanate groups and selected from hydroxyl, mercapto, primary and/or secondary amino groups, d) at least one compound having at least one group reactive towards isocyanate groups and having at least one acid group, e) at least one basic compound for neutralizing or partially neutralizing the acid groups of the compounds d), and a thermal initiator and is used for coating substrates.
    • 可固化的水性聚氨酯分散体基本上包含a)至少一种具有两个游离异氰酸酯基团的化合物,至少一个脲基甲酸酯基团和至少一个能够自由基聚合的CC双键,羰基或乙醚形式的氧原子 b)至少一种具有至少一个对异氰酸酯基团具有反应性并具有能够进行自由基聚合的CC双键的化合物,c)如果需要,至少一种具有至少两个的化合物 对异氰酸酯基反应并且选自羟基,巯基,伯和/或仲氨基的基团,d)至少一种具有至少一个对异氰酸酯基团具有反应性并具有至少一个酸基团的化合物,e)至少一种碱性化合物 用于中和或部分中和化合物d)的酸基和热引发剂,并用于涂覆基材。
    • 20. 发明申请
    • PROCESS FOR PREPARING (METH)ACRYLATES OF C10-ALCOHOL MIXTURES
    • 制备C10-醇混合物(甲基)丙烯酸酯的方法
    • US20100317887A1
    • 2010-12-16
    • US12867511
    • 2009-02-26
    • Uwe MeisenburgFrank HoeferReinhold SchwalmNick GruberLothar Karrer
    • Uwe MeisenburgFrank HoeferReinhold SchwalmNick GruberLothar Karrer
    • C07C67/62
    • C07C67/08C07C67/54C07C69/54
    • Process for preparing (meth)acrylates of C10-alcohol mixtures, by reacting (meth)acrylic acid with an isomer mixture of C10-alcohols composed of 2-propylheptanol as the main isomer and at least one of the C10-alcohols 2-propyl-4-methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4-methylhexanol, 2-isopropyl-5-methylhexanol and/or 2-propyl-4,4-dimethylpentanol, in the presence of at least one acidic catalyst and of at least one polymerization inhibitor and in the presence of a solvent which forms an azeotrope with water, the azeotrope is distilled off and condensed, and the condensate splits into an aqueous phase and an organic phase, wherein a) the esterification is performed in a reactor with a circulation evaporator and b) in the presence of a solvent, and c) the crude product is purified by subsequent purifying distillation.
    • 通过使(甲基)丙烯酸与由2-丙基庚醇组成的C 10醇的异构体混合物作为主要异构体和至少一种C10-醇2-丙基 - 丙烯酸的至少一种来制备C10-醇混合物的(甲基)丙烯酸酯的方法, 4-甲基己醇,2-丙基-5-甲基己醇,2-异丙基庚醇,2-异丙基-4-甲基己醇,2-异丙基-5-甲基己醇和/或2-丙基-4,4-二甲基戊醇,在至少 一种酸性催化剂和至少一种聚合抑制剂,并且在与水形成共沸物的溶剂的存在下,蒸馏出共沸物并冷凝,并且冷凝物分解成水相和有机相,其中a)酯化 在具有循环蒸发器的反应器中进行,和b)在溶剂存在下进行,和c)通过随后的纯化蒸馏纯化粗产物。