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11. 发明授权

US06515037B2 Polypropylene base resin composition for foam-molding, foamed article using the same composition, production process for the same foamed article and foam-molded product using the foamed-article 失效
标题翻译：用于发泡成型的聚丙烯基树脂组合物，使用相同组成的发泡制品，使用发泡制品的相同发泡制品的生产方法和发泡成型产品
公开(公告)号：US06515037B2
公开(公告)日：2003-02-04
申请号：US09784025
申请日：2001-02-16
申请人： Mototake Tsutsui , Hiroyuki Maehara , Kouichi Hatada , Tsutomu Ushioda
发明人： Mototake Tsutsui , Hiroyuki Maehara , Kouichi Hatada , Tsutomu Ushioda
IPC分类号： C08J900
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65916 , C08F2500/12 , C08F2500/24 , C08F236/20
摘要： A polypropylene base resin composition for foam-molding which use's a propylene•&agr;,&ohgr;-diene base copolymer containing a small amount of &agr;,&ohgr;-diene and obtained by copolymerizing propylene with a specific amount of &agr;,&ohgr;-diene in the presence of a catalyst system for polymerizing olefin comprising a metallocene supported catalyst or a pre-activated metallocene supported catalyst and an organic aluminum compound and which provides a foamed article having uniform and fine foamed cells (bubbles) and a high foaming magnification, a foamable polypropylene base resin composition comprising the propylene•&agr;,&ohgr;-diene base copolymer and a specific amount of a foaming agent, a foamed article obtained by foam-molding the above composition, a production process for the above foamed article and a foam-molded product prepared by heat-molding the above foamed article.
摘要翻译：一种用于发泡成型的聚丙烯基础树脂组合物，其使用含有少量α，ω-二烯的丙烯-α，ω-二烯基共聚物，并通过在特定量的α，ω-二烯的存在下将丙烯与特定量的α，ω-二烯共聚而获得一种用于聚合烯烃的催化剂体系，其包含茂金属负载的催化剂或预活化的茂金属负载的催化剂和有机铝化合物，并且提供具有均匀和细小的泡沫泡沫（气泡）和高发泡倍率的发泡制品，可发泡聚丙烯基础树脂包含丙烯-α，ω-二烯基共聚物和特定量的发泡剂的组合物，通过泡沫成型上述组合物获得的发泡制品，用于上述发泡制品的制备方法和通过加热制备的发泡成型产品 - 模制上述发泡制品。

12. 发明授权

US06846943B2 Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst 失效
标题翻译：茂金属化合物，含有该化合物的烯烃聚合催化剂，以及使用该催化剂制造烯烃聚合物的方法
公开(公告)号：US06846943B2
公开(公告)日：2005-01-25
申请号：US09861726
申请日：2001-05-22
申请人： Masato Nakano , Tsutomu Ushioda , Hiroshi Yamazaki , Toshihiro Uwai , Masami Kimura , Yoshiyuki Ohgi , Kiyomi Yamamoto
发明人： Masato Nakano , Tsutomu Ushioda , Hiroshi Yamazaki , Toshihiro Uwai , Masami Kimura , Yoshiyuki Ohgi , Kiyomi Yamamoto
IPC分类号： C07F17/00 , C08F2/00 , C08F4/44 , C08F4/64 , C08F4/659 , C08F4/74 , C08F10/06 , C08F110/06 , C08F210/06
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/65927 , C08F2500/03 , C08F2500/15 , C08F2500/12 , C08F210/16
摘要： The present invention provides a metallocene compound which produces an olefin polymer having a high molecular weight with a high stereoregularity. The metallocene compound has the following formula (1): Q(C5H4-mR1m)(C5H4-nR2n)MXY (1) wherein (C5H4-mR1m) and (C5H4-nR2n) each independently represent a cyclopentadienyl group; C5H4-m and C5H4-n each independently represent a cyclopentadienyl ring; m represents an integer of 1-3; n represents an integer of 2 or 3; R1 and R2 are each independently a substituent bonded respectively to C5H4-m and C5H4-n, and represent a hydrocarbon group of 1-20 carbon atoms, a silicon-containing hydrocarbon group of 1-20 carbon atoms or a heteroaromatic group; each R1m and each R2n may be the same or different; one pair of R2's in the R2n are bonded to each other to form at least one ring; Q represents a divalent group for cross-linking (C5H4-mR1m) and (C5H4-nR2n); M represents a titanium atom, a zirconium atom or a hafnium atom; and X and Y are the same or different and each a hydrogen atom, a halogen atom or a hydrocarbon group.
摘要翻译：本发明提供茂金属化合物，其生产具有高立构规整性的具有高分子量的烯烃聚合物。金属茂化合物具有下式（1）：其中（C5H4-mR1m）和（C5H4-nR_2n）各自独立地表示环戊二烯基; C5H4-m和C5H4-n各自独立地表示环戊二烯基环; m表示1-3的整数; n表示2或3的整数; R 1和R 2分别独立地表示与C5H4-m和C5H4-n键合的取代基，表示烃基 1-20个碳原子的含硅烃基或杂芳基;每个R 1 m和每个R 2可以相同或不同;一对R 2 R 2相互键合形成至少一个环; Q表示用于交联的二价基团（C 5 H 4 -m R m）和（C 5 H 4 -NR 2 n） M表示钛原子，锆原子或铪原子; X和Y相同或不同，各自为氢原子，卤素原子或烃基。

13. 发明授权

US06635733B2 Elastomeric polypropylene 失效
标题翻译：弹性聚丙烯
公开(公告)号：US06635733B2
公开(公告)日：2003-10-21
申请号：US09850152
申请日：2001-05-08
申请人： Tsuyoshi Yahata , Masato Nakano , Yoshiyuki Ohgi , Tsutomu Ushioda
发明人： Tsuyoshi Yahata , Masato Nakano , Yoshiyuki Ohgi , Tsutomu Ushioda
IPC分类号： C08F21006
CPC分类号： C08F110/06 , C08F4/65912 , C08F10/00 , Y10S526/943 , C08F4/65925 , C08F2500/15 , C08F2500/12 , C08F2500/03 , C08F2500/21
摘要： An elastomeric polypropylene wherein (a) an isotactic pentad (I5) is 0.150-0.749, (b) a different bond due to a 2,1-insertion reaction is 0.11-20 mol %, (c) a different bond due to a 1,3-insertion reaction is 0-10 mol % and (d) a melting point (Tm) is 50-160° C., (a) to (c) being determined from 13C NMR spectra, which is obtainable by the polymerization of propylene using any one of a metallocene catalyst (I) comprising a metallocene compound (A), an activating compound (B) and if desired, an organoaluminum compound (C), a supported metallocene catalyst (II) prepared by supporting the metallocene catalyst (I) on a finely particulate support (D), and a supported metallocene catalyst (III) prepared by adding an organoaluminum compound (E) to the supported metallocene catalyst (II). In particular, it has excellent transparency and elastic characteristics.
摘要翻译：一种弹性体聚丙烯，其中（a）全同立构五单元组（I5）为0.150-0.749，（b）由于2,1-插入反应引起的不同键为0.11-20摩尔％，（c）由于1 ，3-插入反应为0-10摩尔％，（d）熔点（Tm）为50-160℃，（a）至（c）由13 C NMR谱确定，可通过使用包含茂金属化合物（A）的茂金属催化剂（I），活化化合物（B）和如果需要的话，使用有机铝化合物（C），负载金属茂催化剂（II）在精细颗粒载体（D）上的金属茂催化剂（I）和通过将有机铝化合物（E）加入到负载的茂金属催化剂（II）中制备的负载金属茂催化剂（III）。特别是具有优异的透明性和弹性特性。

14. 发明授权

US5874505A Polypropylene composition 失效
标题翻译：聚丙烯组成
公开(公告)号：US5874505A
公开(公告)日：1999-02-23
申请号：US980421
申请日：1997-11-28
申请人： Jun Saito , Naoshi Kawamoto , Akiko Kageyama , Kouichi Hatada , Yoshiyuki Oogi , Tsutomu Ushioda
发明人： Jun Saito , Naoshi Kawamoto , Akiko Kageyama , Kouichi Hatada , Yoshiyuki Oogi , Tsutomu Ushioda
IPC分类号： C08F4/58 , C08F4/64 , C08F110/06 , C08L23/10 , C08L23/16 , C08L23/12
CPC分类号： C08L23/10 , C08F110/06 , C08L23/16 , Y10S526/943
摘要： A polypropylene composition comprising 20 to 95% by weight of a stereoregular polypropylene characterized by the specified physical properties determined from .sup.13 C NMR spectra and 5 to 80% by weight of an .alpha.-olefin copolymer comprising 10 to 90% by weight of an .alpha.-olefin and 10 to 90% by weight of at least one of other .alpha.-olefins. The polypropylene composition demonstrates good balance of rigidity and impact resistance, high heat resistance and high toughness, when used as molding materials.
摘要翻译：一种聚丙烯组合物，其包含20至95重量％的立构规整聚丙烯，其特征在于由13 C NMR谱确定的特定物理性质和5至80重量％的包含10至90重量％的α-烯烃的α-烯烃共聚物和10至90重量％的至少一种其它α-烯烃。当用作成型材料时，聚丙烯组合物表现出良好的刚性和耐冲击性的平衡，高耐热性和高韧性。

15. 发明授权

US07906599B2 Transition metal compound, catalyst for olefin polymerization containing the same, and method for producing propylene/ethylene-α-olefin block copolymer by using the catalyst 有权
标题翻译：过渡金属化合物，含有该催化剂的烯烃聚合用催化剂，以及使用该催化剂制造丙烯/乙烯-α-烯烃嵌段共聚物的方法
公开(公告)号：US07906599B2
公开(公告)日：2011-03-15
申请号：US12297444
申请日：2007-04-17
申请人： Hisashi Ohtaki , Naoshi Iwama , Masami Kashimoto , Tomohiro Kato , Tsutomu Ushioda
发明人： Hisashi Ohtaki , Naoshi Iwama , Masami Kashimoto , Tomohiro Kato , Tsutomu Ushioda
IPC分类号： C08F4/76 , C08F4/64 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , C08F210/16 , C08F297/08 , C08F297/083 , Y10S526/901 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F210/06 , C08F2500/21 , C08F210/08 , C08F2500/17
摘要： Disclosed is a novel transition metal compound which is used for forming a metallocene catalyst for olefin polymerization. Specifically disclosed is a novel transition metal compound represented by the general formula below which enables to form a metallocene catalyst that has a balanced reactivity with ethylene and a comonomer selected from α-olefins having 3-20 carbon atoms and enables to produce an α-olefin polymer having a high molecular weight. Also specifically disclosed are a catalyst for olefin polymerization containing such a transition metal compound, and a method for producing a propylene/ethylene-α-olefin block copolymer wherein such a catalyst is used.
摘要翻译：公开了一种用于形成烯烃聚合用茂金属催化剂的新型过渡金属化合物。具体公开了一种由以下通式表示的新型过渡金属化合物，其能够形成具有与乙烯的反应性平衡的茂金属催化剂和选自具有3-20个碳原子的α-烯烃的共聚单体，并且能够生产α-烯烃具有高分子量的聚合物。还具体公开了含有这种过渡金属化合物的烯烃聚合催化剂，以及使用这种催化剂的丙烯/乙烯-α-烯烃嵌段共聚物的制造方法。

16. 发明授权

US06995279B2 Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes 有权
标题翻译：茂金属化合物，使用含有该化合物的催化剂生产烯烃聚合物的方法，以及通过该方法生产的烯烃聚合物
公开(公告)号：US06995279B2
公开(公告)日：2006-02-07
申请号：US10630666
申请日：2003-07-31
申请人： Tsutomu Ushioda , Masato Nakano , Toshihiro Uwai
发明人： Tsutomu Ushioda , Masato Nakano , Toshihiro Uwai
IPC分类号： C07F17/00 , B01J31/00 , C08F4/44
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/06 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/16 , C08F210/08 , C08F2500/07
摘要： Metallocene compounds represented by the following general formula (1): YqKLMX2 (1) wherein M, Y, q, L and X are each as defined in the Specification.
摘要翻译：茂金属化合物由以下通式表示

17. 发明申请

US20090099310A1 NOVEL TRANSITION METAL COMPOUND, CATALYST FOR OLEFIN POLYMERIZATION CONTAINING THE SAME, AND METHOD FOR PRODUCING PROPYLENE/ETHYLENE-ALPHA-OLEFIN BLOCK COPOLYMER BY USING THE CATALYST 有权
标题翻译：新型过渡金属化合物，含有烯烃聚合物的催化剂，以及通过使用催化剂生产丙烯/乙烯-α-烯烃嵌段共聚物的方法
公开(公告)号：US20090099310A1
公开(公告)日：2009-04-16
申请号：US12297444
申请日：2007-04-17
申请人： Hisashi Ohtaki , Naoshi Iwama , Masami Kashimoto , Tomohiro Kato , Tsutomu Ushioda
发明人： Hisashi Ohtaki , Naoshi Iwama , Masami Kashimoto , Tomohiro Kato , Tsutomu Ushioda
IPC分类号： C08L53/00 , C07F17/00 , C08F4/76 , B01J31/22 , C08F4/52 , C08F4/16
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , C08F210/16 , C08F297/08 , C08F297/083 , Y10S526/901 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F210/06 , C08F2500/21 , C08F210/08 , C08F2500/17
摘要： Disclosed is a novel transition metal compound which is used for forming a metallocene catalyst for olefin polymerization. Specifically disclosed is a novel transition metal compound represented by the general formula below which enables to form a metallocene catalyst that has a balanced reactivity with ethylene and a comonomer selected from α-olefins having 3-20 carbon atoms and enables to produce an α-olefin polymer having a high molecular weight. Also specifically disclosed are a catalyst for olefin polymerization containing such a transition metal compound, and a method for producing a propylene/ethylene-α-olefin block copolymer wherein such a catalyst is used.
摘要翻译：公开了一种用于形成烯烃聚合用茂金属催化剂的新型过渡金属化合物。具体公开的是由以下通式表示的新型过渡金属化合物，其能够形成与乙烯和选自具有3-20个碳原子的α-烯烃的共聚单体具有平衡的反应性的茂金属催化剂，并且能够生产α-烯烃具有高分子量的聚合物。还具体公开了含有这种过渡金属化合物的烯烃聚合催化剂，以及使用这种催化剂的丙烯/乙烯-α-烯烃嵌段共聚物的制造方法。

18. 发明授权

US07019157B2 Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process 有权
标题翻译：茂金属化合物，使用含有催化剂的烯烃聚合物的生产方法和通过生产方法生产的烯烃聚合物
公开(公告)号：US07019157B2
公开(公告)日：2006-03-28
申请号：US10210394
申请日：2002-08-02
申请人： Toshihiro Uwai , Masato Nakano , Tsutomu Ushioda , Masami Kimura , Tsuyoshi Yahata
发明人： Toshihiro Uwai , Masato Nakano , Tsutomu Ushioda , Masami Kimura , Tsuyoshi Yahata
IPC分类号： C07F17/00 , C08F4/76 , C08F4/52
CPC分类号： C08F297/08 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/06 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/12 , C08F2500/03
摘要： The present invention provides metallocene compounds which exhibit high polymerization activity for production of highly stereoregular polymers, as well as a production process for olefin polymers which employs olefin polymerization catalysts containing the compounds, and olefin polymers obtained by the production process. A metallocene compound of the present invention is represented by the following general formula (1): YKLMX2 (1) wherein M represents a titanium atom, zirconium atom or hafnium atom; K and L are fused rings coordinated to M and each independently represents a fused ring of a cyclopentadienyl ring and a 5-membered ring, a fused ring of a cyclopentadienyl ring and a 6-membered ring or a fused ring of a cyclopentadienyl ring and a 7-membered ring; Y is a bridge group crosslinking K and L; and each X is bonded to M; and K and L have a 2-furyl group, substituted 2-furyl group, 2-thienyl group, substituted 2-thienyl group, 2-furfuryl group or substituted 2-furfuryl group on at least one position among each of the 2-positions, 4-positions and 5-positions.
摘要翻译：本发明提供了表现出高聚合活性的茂金属化合物，用于生产高立体规则聚合物，以及使用含有该化合物的烯烃聚合催化剂的烯烃聚合物的制备方法，以及通过该方法得到的烯烃聚合物。本发明的茂金属化合物由以下通式（1）表示：<？in-line-formula description =“In-line formula”end =“lead”？> YKLMX＆lt; 2＆gt;（ 1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中M表示钛原子，锆原子或铪原子; K和L是与M配位的稠合环，并且各自独立地表示环戊二烯基环和5元环的稠环，环戊二烯基环的稠环和6元环或环戊二烯基环的稠环和 7元环; Y是交联K和L的桥组; 并且每个X与M键合; K和L在2-位中的至少一个位置具有2-呋喃基，取代的2-呋喃基，2-噻吩基，取代的2-噻吩基，2-糠基或取代的2-糠基 4个职位和5个职位。

19. 发明授权

US06479646B1 Metallocene compounds having indenyl ligand and catalysts for olefin polymerization containing the same 失效
标题翻译：具有茚基配体的茂金属化合物和含有它们的烯烃聚合催化剂
公开(公告)号：US06479646B1
公开(公告)日：2002-11-12
申请号：US09686619
申请日：2000-10-12
申请人： Masato Nakano , Tsutomu Ushioda , Seiki Mitani , Hiroshi Yamazaki
发明人： Masato Nakano , Tsutomu Ushioda , Seiki Mitani , Hiroshi Yamazaki
IPC分类号： B05J3100
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/06 , C08F110/06 , C08F4/65925 , C08F2500/17 , C08F2500/03
摘要： A metallocene compound having an indenyl ligand substituted by a heteroaromatic group, which is useful as an olefin polymerization catalyst. The metallocene compound has the following structure wherein M is a transition metal atom; each Ra is a monocyclic or polycyclic heteroaromatic group; each R1 is halogen, a hydrocarbon group of 1-20 carbons, a halogenated hydrocarbon group of 1-20 carbons, etc., or adjacent R1's may be joined together to form a ring of 6-8 carbons; p and q are each 1-7; n and l are each 0 or 1-6; and each X is halogen, a hydrocarbon group of 1-20 carbons, a halogenated hydrocarbon group of 1-20 carbons, etc.
摘要翻译：具有被杂芳基取代的茚基配位体的茂金属化合物，其可用作烯烃聚合催化剂。金属茂化合物具有以下结构，其中M是过渡金属原子;每个R a是单环或多环杂芳族基团;每个R 1是卤素，1-20个碳的烃基，1-20个碳的卤代烃基等，或相邻的R1可以连接在一起形成6-8个碳环; p和q各自为1-7; n和l各自为0或1-6;并且各X为卤素，1-20个碳的烃基，1-20个碳的卤代烃基等

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